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While basic features of polarons were well recognized a long time
ago and have been described in a number of review papers and
textbooks, interest in the role of electron-phonon interactions and
polaron dynamics in di?- ent materials has recently gone through a
vigorous revival. Electron-phonon interactions have been shown to
be relevant in many inorganic and organic semiconductors and
polymers, colossal magnetoresistance oxides, and tra- port through
nanowires and quantum dots also often depends on vibronic
displacements of ions. These interactions presumably play a role in
hi- temperature superconductors as well. The continued interest in
polarons extends beyond the physical description of advanced
materials. The ?eld has been a testing ground for analytical,
semi-analytical, and numerical techniques, such as path integrals,
strong-coupling perturbation expansion, advanced variational
methods, exact diagonalization, Quantum Monte Carlo, and other
techniques. This book reviews some recent developments in the ?eld
of polarons, starting with the basics and covering a number of
active directions of research. Single- and multipolaron theories
have o?ered more insight into colossal magnetoresistance and in a
broad spectrum of ph- ical properties of structures with reduced
dimension and dimensionality such as transport, optical absorption,
Raman scattering, photoluminescence, magneto-optics, etc. While
nobody - at present - has a ?nal theory of hi- temperature
superconductivity, we discuss one alternative (polaronic) route. We
have bene?ted from discussions with many experts in the ?eld.
The Advanced Study Institute on 'Elementary Excitations in Solids,
Molecules, and Atoms' was held at the University of Antwerp
(U.I.A.) from June 18th till June 30th 1973. The In stitute was
sponsored by NATO. Co-sponsors were: Agfa-Gevaert N.V. (Mortsel -
Belgium), Bell Telephone Mfg. Co. (Antwerp Belgium), the National
Science Foundation (Washington D.C. - U.S.A.) and the University of
Antwerp (U.I.A.). A total of 120 lecturers and participants
attended the Institute. Over the last few years, substantial
progress has been made in the description of the elementary
excitations of the elec tronic and vibrational systems and their
interactions. Parallel with this, the experimentalists have
obtained outstanding re sults, partly as a result of availability
of coherent light sour ces from the far infrared through the
visible region, and partly because of the availability of
synchrotron radiation sources in the soft X-ray region. The results
of today will lead to fur ther progress over the next years. It was
the purpose of this NATO Advanced Study Institute to present astate
of the art, namely a survey of experiment and theory."
The 1984 Advanced Study Institute on "Electronic Structure,
Dynamics and Quantum Structural Properties of Condensed Matter"
took place at the Corsendonk Conference Center, close to the City
of Antwerpen, from July 16 till 27, 1984. This NATO Advanced Study
Institute was motivated by the research in my Institute, where, in
1971, a project was started on "ab-initio" phonon calculations in
Silicon. I~ is my pleasure to thank several instances and people
who made this ASI possible. First of all, the sponsor of the
Institute, the NATO Scientific Committee. Next, the co-sponsors:
Agfa-Gevaert, Bell Telephone Mfg. Co. N.V., C & A, Esso
Belgium*, CDC Belgium, Janssens Pharmaceutica, Kredietbank and the
Scientific Office of the U.S. Army. Special thanks are due to Dr.
P. Van Camp and Drs. H. Nachtegaele, who, over several months,
prepared the practical aspects of the ASI with the secretarial help
of Mrs. R.-M. Vandekerkhof. I also like to. thank Mrs. M. Cuyvers
who prepared and organized the subject and material index and Mrs.
H. Evans for typing-assist ance. I express particular gratitude to
Mrs. F. Nedee, who, like in 1981 and 1982, has put the magnificent
Corsendonk Conference Center at our disposal and to Mr. D. Van Der
Brempt, Director of the Corsendonk Conference Center, for the
efficient way in which he and his staff took care of the practical
organization at the Conference Center.
From July 20 till 31, 1981, the Advanced Study Institute on
"Electron Correlations in Solids, Molecules and Atoms," sponsored
by NATO, was held at the University of Antwerpen (U.I.A.), in the
Conference Center Corsendonk. In the last few years, the problem of
many-electron correlations has gained renewed attention, due to
recent experimental and theoretic al developments. From the
theoretical point of view, more sophisticated treatments of the
homogeneous electron gas model evolved, including dynamical aspects
of the electron correlation in the dielectric response.
Furthermore, the homogeneous electron gas, which served as a model
for simple metals, was extended to include spin- and charge-density
waves and phasons. The concept of elementary excitations too was
introduced not only in perfectly ordered metallic crystals, but
also in magnetic alloys, in liquid metals and alloys, in
semiconductors, and even in molecules and atoms. Fairly accurate
quantitative calculations of these effects recently became
possible, ranging from plasmon frequencies in atoms, over
dielectric response of semiconduc tors and resistivity in magnetic
alloys to electron-hole liquids and their phase separation. The
recent technological evolution allowed for more accurate
measurements in previously unaccessible domains, e.g. X-ray scatter
ing and fast electron energy loss at large wavevector. Moreover,
these new developments opened new perspectives in physics,
accompany ing or even introducing the new concepts which also
evolved in the theory."
The International Workshop on "The Use of Super computers in
Theoretical Science" took place from July 30 till August 1, 1984,
at the Conference Center of the "Priorij Corsendonk", close to the
city of Antwerpen, Belgium. During the past decade computational
science has developed itself to a third methodology besides the
experimental and theoretical sciences. This remarkable evolution
was only possible due to a drastic increase of the computational
power of present day computers. Indeed, computational physics and
chemistry as such is certainly not new, but it was only during the
past ten years or so that realistic problems could be solved
numerically to a sufficient degree of accuracy. During this
workshop the state-of-the-art in high speed computation was
presented by a team of lecturers who are well known for their
competence in this field. It is a pleasure to thank several
organizations and companies who made this workshop possible. First
of all, the main sponsors: the Belgian National Science Found ation
(NFWO-FNRS) and the "Universitaire Instelling Ant werpen". Next,
the co-sponsors: Agfa-Gevaert N. V., Control Data Belgium and the
Belgian Ministry of Education. Special thanks are due to Dr. P.E.
Van Camp and Drs. H. Nachtegaele for the practical organization of
this workshop. I would also like to thank Mrs. H. Evans for typing
the manuscripts and for preparing the author and subject index. v
Last but not least I express my gratitude to Mr.
While basic features of polarons were well recognized a long time
ago and have been described in a number of review papers and
textbooks, interest in the role of electron-phonon interactions and
polaron dynamics in di?- ent materials has recently gone through a
vigorous revival. Electron-phonon interactions have been shown to
be relevant in many inorganic and organic semiconductors and
polymers, colossal magnetoresistance oxides, and tra- port through
nanowires and quantum dots also often depends on vibronic
displacements of ions. These interactions presumably play a role in
hi- temperature superconductors as well. The continued interest in
polarons extends beyond the physical description of advanced
materials. The ?eld has been a testing ground for analytical,
semi-analytical, and numerical techniques, such as path integrals,
strong-coupling perturbation expansion, advanced variational
methods, exact diagonalization, Quantum Monte Carlo, and other
techniques. This book reviews some recent developments in the ?eld
of polarons, starting with the basics and covering a number of
active directions of research. Single- and multipolaron theories
have o?ered more insight into colossal magnetoresistance and in a
broad spectrum of ph- ical properties of structures with reduced
dimension and dimensionality such as transport, optical absorption,
Raman scattering, photoluminescence, magneto-optics, etc. While
nobody - at present - has a ?nal theory of hi- temperature
superconductivity, we discuss one alternative (polaronic) route. We
have bene?ted from discussions with many experts in the ?eld.
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