which successfully passed the QA-process (i.e., met the Data Quality Objectices) were included into the TFS-central data bank. The following summary of major results obtained in TFS would not have been possible without the contribution of many experimentalists and modellers participating in this project. I would like to thank these colleagues for their support. All participants are grateful for the financial support by the BMBF and for the assistance by the Projekttragerschaft (UKF-GSF-Miinchen). Garmisch-Partenkirchen, WOLFGANG SEILER February 2002 DEVELOPMENT AND APPLICATION OF A MESOSCALE MODEL HIERARCHY FOR THE DIAGNOSIS AND FORECAST OF THE DISTRIBUTION OF POLLUTANTS OVER GERMANY AND EUROPE Journal of Atmospheric Chemistry 42: 5-22, 2002. 5 (c) 2002 Kluwer Academic Publishers. An Empirical, Receptor-Based Procedure for Assessing the Effect of Different Ozone Mitigation Strategies WOLFGANG FRICKE, WINFRIED VANDERSEE and STEFAN GILGE Deutscher Wetterdienst, Meteorologisches Observatorium, Albin-Schwaiger-Weg 10, D-82383 Hohenpeissenberg, Germany, e-mail: [email protected] (Received: 6 November 2000; in final form: 29 May 2(01) Abstract. The paper presents a new receptor-based approach for investigating the effect of differ- ent mitigation strategies on surface ozone concentrations. The empirical approach relates measured ozone concentrations to 3-D back trajectories and European precursor emission data (NOx, VOC, isoprene). These are the only parameters used as input. Following a description of the method, results for two German stations, an urban and a rural mountain site, are described, and discussed in detail.

Atmospheric-pressure plasmas continue to attract considerable research interest due to their diverse applications, including high power lasers, opening switches, novel plasma processing applications and sputtering, EM absorbers and reflectors, remediation of gaseous pollutants, excimer lamps, and other noncoherent light sources. Atmospheric-pressure plasmas in air are of particular importance as they can be generated and maintained without vacuum enclosure and without any additional feed gases. Non-Equilibrium Air Plasmas at Atmospheric Pressure reviews recent advances and applications in the generation and maintenance of atmospheric-pressure plasmas. With contributions from leading international researchers, the coverage includes advances in atmospheric-pressure plasma source development, diagnostics and characterization, air plasma chemistry, modeling and computational techniques, and an assessment of the status and prospects of atmospheric-pressure air plasma applications. The extensive application sections make this book attractive for practitioners in many fields where technologies based on atmospheric-pressure air plasmas are emerging.

Atmospheric-pressure plasmas continue to attract considerable research interest due to their diverse applications, including high power lasers, opening switches, novel plasma processing applications and sputtering, EM absorbers and reflectors, remediation of gaseous pollutants, excimer lamps, and other noncoherent light sources. Atmospheric-pressure plasmas in air are of particular importance as they can be generated and maintained without vacuum enclosure and without any additional feed gases.

Non-Equilibrium Air Plasmas at Atmospheric Pressure reviews recent advances and applications in the generation and maintenance of atmospheric-pressure plasmas. With contributions from leading international researchers, the coverage includes advances in atmospheric-pressure plasma source development, diagnostics and characterization, air plasma chemistry, modeling and computational techniques, and an assessment of the status and prospects of atmospheric-pressure air plasma applications. The extensive application sections make this book attractive for practitioners in many fields where technologies based on atmospheric-pressure air plasmas are emerging.

The Arctic troposphere (0 to ca. 8 km) plays an important role in environmental concerns for global change. It is a unique chemical reactor influenced by human activity and the Arctic ocean. It is surrounded by industrialized continents that in winter contribute gaseous and particulate pollution (Arctic haze). It is underlain by the flat Arctic ocean from which it is separated by a crack-ridden ice membrane 3 to 4 m thick. Ocean to atmosphere exchange of heat, water vapor and marine biogenic gases influence the composition of the reactor. From September 21 to December 21 to March 21, the region north of the Arctic circle goes from a completely sunlit situation to a completely dark one and then back to light. At the same time the lower troposphere is stably stratified. This hinders vertical mixing. During this light period, surface temperature reaches as low as -40 DegreesC. In this environment, chemical reactions involving sunlight are generally much slower than further south. Thus, the abundance of photochemically reactive compounds in the atmosphere can be high prior to polar sunrise. Between complete dark in February and complete light in April, a number of chemical changes in the lower troposphere take place.

Photochemical oxidants are secondary air pollutants formed under the influence of sunlight by complex photochemical reactions in air which contains nitrogen oxides and reactive hydrocarbons as precursors. The most adverse components formed by photochemical reactions in polluted air are ozone (0 ) 3 and peroxyacetyl nitrate (PAN), among many other products such as aldehydes, ketones, organic and inorganic acids, nitrates, sulfates etc. An analysis and evaluation of the available knowledge has been used to characterize the relationships among emissions, ambient air concentrations, and effects, and to identify the important controlling influences on the formation and effects of photochemical oxidants. The biological activity of photochemical oxidants was first clearly manifested during the early 1940's, when vegetation injury was observed in the Los Angeles Basin in the United States. Since that time, as a consequence of the increasing emissions of photochemical oxidant precursors, the photochemical oxidants have become the most important air pollutants in North America. In other parts of the world, for example South and Central America, Asia, and Australia, photo chemical oxidants threaten vegetation, particularly the economic and ecological performance of plant life. According to my knowledge, the first observations of ozone and PAN injury to vegetation in Europe were made by Dr. Ellis F. Darley (Statewide Air Pollution Research Center, University of California, Riverside, California) during a study visit (1963/64) to the Federal Republic of Germany."

which successfully passed the QA-process (i.e., met the Data Quality Objectices) were included into the TFS-central data bank. The following summary of major results obtained in TFS would not have been possible without the contribution of many experimentalists and modellers participating in this project. I would like to thank these colleagues for their support. All participants are grateful for the financial support by the BMBF and for the assistance by the Projekttragerschaft (UKF-GSF-Miinchen). Garmisch-Partenkirchen, WOLFGANG SEILER February 2002 DEVELOPMENT AND APPLICATION OF A MESOSCALE MODEL HIERARCHY FOR THE DIAGNOSIS AND FORECAST OF THE DISTRIBUTION OF POLLUTANTS OVER GERMANY AND EUROPE Journal of Atmospheric Chemistry 42: 5-22, 2002. 5 (c) 2002 Kluwer Academic Publishers. An Empirical, Receptor-Based Procedure for Assessing the Effect of Different Ozone Mitigation Strategies WOLFGANG FRICKE, WINFRIED VANDERSEE and STEFAN GILGE Deutscher Wetterdienst, Meteorologisches Observatorium, Albin-Schwaiger-Weg 10, D-82383 Hohenpeissenberg, Germany, e-mail: [email protected] (Received: 6 November 2000; in final form: 29 May 2(01) Abstract. The paper presents a new receptor-based approach for investigating the effect of differ- ent mitigation strategies on surface ozone concentrations. The empirical approach relates measured ozone concentrations to 3-D back trajectories and European precursor emission data (NOx, VOC, isoprene). These are the only parameters used as input. Following a description of the method, results for two German stations, an urban and a rural mountain site, are described, and discussed in detail.