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Polymer Thermodynamics: Blends, Copolymers and Reversible
Polymerization describes the thermodynamic basis for miscibility as
well as the mathematical models used to predict the compositional
window of miscibility and construct temperature versus
volume-fraction phase diagrams. The book covers the binary
interaction model, the solubility parameter approach, and the
entropic difference model. Using equation of state (EOS) theories,
thermodynamic models, and information from physical properties, it
illustrates the construction of phase envelopes. The book presents
nine EOS theories, including some that take into account molecular
weight effects. Characteristic values are given in tables. It uses
the binary interaction model to predict the compositional window of
miscibility for copolymer/homopolymer blends and blends of
copolymers and terpolymers with common monomers. It discusses
Hansen fractional solubility parameter values, six phase diagram
types, the role of polymer architecture in phase behavior, and the
mathematical framework for multiple glass transition temperatures
found in partially miscible polymer blends. The author also
illustrates biomedical and commercial applications of
nanocomposites, the properties of various polymer alloys, Fick's
laws of diffusion and their implications during transient events,
and the use of the dynamic programming method in the sequence
alignment of DNA and proteins. The final chapter reviews the
thermodynamics of reversible polymerization and copolymerization.
Polymer blends offer improved performance/cost ratios and the
flexibility to tailor products to suit customers' needs. Exploring
physical phenomena, such as phase separation, this book provides
readers with methods to design polymer blends and predict the phase
behavior of binary polymer blends using desktop computers.
This is a modern first course on process control, instruments,
process dynamics and stability. MS Excel spreadsheets are used in
order to obtain solutions to non-linear equations when needed and
closed form analytical solutions are obtained using Laplace
transforms and other methods. The solutions are presented in 210
figures and the book has 1319 equations. With an industrial
controls market size of about 150 billion dollars and a chemical
process industry market size of three trillion dollars, the
practioners can use this book to master techniques of P,
proportional, PI, Proportional Integral, PD, Proportional
Derivative feedback control, feedforword control, hybrid control,
adaptive control, internal model control, ratio control, filtered
real proportional integral derivative control, ANNs, artificial
neural networks, SPC, and statistical process control. Control
block diagrams are developed using MS Paint. Flavor for what is a
continuous process is given using 18 process flow diagrams. Be it a
feedback control of temperature in a mixing tank or a neural
network design for a distillation column, the details and the big
picture are both given. Pioneers who made this area possible
include people such as Maxwell, Galileo, Sherwood, Levenspiel,
Kalman, Laplace, Fermat, Damkholer, Newton, Fourier, Fick,
Michaelis, Menten, Monod, Staudinger, Ziegler, Natta, Flory,
Peclect, Bode, Nyquist, Biot, Bessel, Bernoulli (both father and
son!) , Euler, Stokes, Mach, Reynolds, Prandtl, Nusselt, Weiner,
Hopf, Clapeyron, Clausius, Lorenz, and Kreb, who are mentioned
where their theories were used in the analysis.
This is a modern first course on process control, instruments,
process dynamics and stability. MS Excel spreadsheets are used in
order to obtain solutions to non-linear equations when needed and
closed form analytical solutions are obtained using Laplace
transforms and other methods. The solutions are presented in 210
figures and the book has 1319 equations. With an industrial
controls market size of about 150 billion dollars and a chemical
process industry market size of three trillion dollars, the
practioners can use this book to master techniques of P,
proportional, PI, Proportional Integral, PD, Proportional
Derivative feedback control, feedforword control, hybrid control,
adaptive control, internal model control, ratio control, filtered
real proportional integral derivative control, ANNs, artificial
neural networks, SPC, and statistical process control. Control
block diagrams are developed using MS Paint. Flavor for what is a
continuous process is given using 18 process flow diagrams. Be it a
feedback control of temperature in a mixing tank or a neural
network design for a distillation column, the details and the big
picture are both given. Pioneers who made this area possible
include people such as Maxwell, Galileo, Sherwood, Levenspiel,
Kalman, Laplace, Fermat, Damkholer, Newton, Fourier, Fick,
Michaelis, Menten, Monod, Staudinger, Ziegler, Natta, Flory,
Peclect, Bode, Nyquist, Biot, Bessel, Bernoulli (both father and
son!), Euler, Stokes, Mach, Reynolds, Prandtl, Nusselt, Weiner,
Hopf, Clapeyron, Clausius, Lorenz, and Kreb, who are mentioned
where their theories were used in the analysis.
In today's rapidly changing global economy, business managers must
have the tools and know-how to quickly evaluate the economic
viability of potential solutions to engineering problems. An entire
field of study has evolved to meet this need, yet there are few
straightforward texts that outline the basics of engineering
economics.
"Fundamentals of Engineering Economics" is an accessible,
comprehensive guide to the fundamental principles, concepts, and
methods of engineering economics. Utilizing detailed case studies
and exercises reflecting current trends and issues in economics,
this book introduces students to a variety of key concepts,
including estimation of the time value of money, evaluation of a
single project, decision analysis, depreciation and taxes. This is
an ideal textbook for Economic Analysis and Technical Applications
students, or anyone seeking to gain an understanding of the core
concepts of engineering economics.
"Fundamentals of Engineering Economics" is organized into the
following topical chapters:
- Overview of Engineering Economy
- Fixed and Variable Costs
- Time Worth of Money
- Five Methods for Evaluation of Capital Project
- Comparison of Alternates and Decision Analysis
- Depreciation and Replacement Analysis
- Taxes, Tariffs, and Duties
- Public Sector Initiatives and Benefit-to-Cost Ratio
- Break-Even Analysis and Spider Plots
Kal Renganathan Sharma serves as Adjunct Professor of Chemical
Engineering at the Roy G. Perry College of Engineering at Prairie
View A&M University. He received his B.Tech. from the Indian
Institute of Technology (1985, Chennai, India) and his MS and Ph.D
degrees from West Virginia University (1987, 1990, Morgantown, WV).
All three degrees are in chemical engineering. Dr. Sharma is the
author of 10 books, 4 book chapters, 21 journal articles, 528
conference papers and 108 other presentations. He is the recipient
of several prestigious honors and awards, including the Outstanding
Student of the Penultimate Year from the Rev. Brothers of St.
Gabriel at RSK Higher Secondary School (Trichy, India) and an
Honorary Fellowship from the Australian Institute of High Energetic
Materials (Melbourne, Australia).
Nuclear fuel materials are those that are capable of undergoing
fission reactions along with the liberation of enormous quantity of
energy. The fuel cycle costs are 20% of nuclear electricity
generation cost. This new book evaluates the use of the damped wave
diffusion and relaxation equation to nuclear fuels processes.
Simultaneous diffusion and auto-catalytic reactions and the wave
diffusion phenomena may have a combined effect of sub-critical
damped oscillations in concentration under certain conditions.
Closed form analytical solutions are developed from the hyperbolic
partial differential equations that govern the phenomena.
Transient problems in transport phenomena have a variety of
applications, ranging from drug delivery systems in chemotherapy in
bioengineering to heat transfer to surfaces in fluidized bed
combustion (FBC) boilers in mechanical engineering. However, the
attention given to transient problems is disproportionate with its
occurrence in the industry. Damped Wave Transport and Relaxation
looks at transient problems in heat, mass and momentum transfer:
including non-Fourier effects of conduction and relaxation;
non-Fick effects of mass diffusion and relaxation; and
non-Newtonian effects of viscous momentum transfer and relaxation.
The author also reviews applications to current problems of
interest and uses worked examples and illustrations to describe the
manifestations of using generalized transport equations. This book
is intended for graduate students in transport phenomena and is an
ideal reference source for industrial engineers.
* Provides a connection with molecular phenomena
* Separate sections are devoted to heat, mass and momentum transfer
* Includes exercises and examples of applications
In this day and age, the chemical process engineer strives to make
products at a lower cost, with less pollution, while using a
variety of raw materials. When a new product or process is found to
be successful, more plants are built either by retrofit or existing
similar plants, or by construction of large plants. Engineers
involved in the scaling of new plants will need a solid
understanding of the issues involved in multiple reactions, which
can happen in a series, in parallel, and can be reversible.
Computer software can be used provide detailed treatments of these
reactions and readers of Multiple Reactions Galore will learn how
to treat intermediate products during a complex reaction scheme.
This two-volume set discusses the engineering design issues
involved when multiple reactions occur in the considered process.
Design issues such as product distribution, economic analysis and
profitability as well as the sensitivity of important quantities
such as yield, selectivity to rate constant ratios, will be
presented in detail. The author explains how to use Excel
spreadsheets to seek numerical solutions when closed form
analytical solutions are not possible. The author also explores the
importance of by-product and by-product yield, which is often
overlooked in traditional reaction engineering textbooks.
In this day and age, the chemical process engineer strives to make
products at a lower cost, with less pollution, while using a
variety of raw materials. When a new product or process is found to
be successful, more plants are built either by retrofit or existing
similar plants, or by construction of large plants. Engineers
involved in the scaling of new plants will need a solid
understanding of the issues involved in multiple reactions, which
can happen in a series, in parallel, and can be reversible.
Computer software can be used provide detailed treatments of these
reactions and readers of Multiple Reactions Galore will learn how
to treat intermediate products during a complex reaction scheme.
This two-volume set discusses the engineering design issues
involved when multiple reactions occur in the considered process.
Design issues such as product distribution, economic analysis and
profitability as well as the sensitivity of important quantities
such as yield, selectivity to rate constant ratios, will be
presented in detail. The author explains how to use Excel
spreadsheets to seek numerical solutions when closed form
analytical solutions are not possible. The author also explores the
importance of by-product and by-product yield, which is often
overlooked in traditional reaction engineering textbooks.
Polymer Thermodynamics: Blends, Copolymers and Reversible
Polymerization describes the thermodynamic basis for miscibility as
well as the mathematical models used to predict the compositional
window of miscibility and construct temperature versus
volume-fraction phase diagrams. The book covers the binary
interaction model, the solubility parameter approach, and the
entropic difference model. Using equation of state (EOS) theories,
thermodynamic models, and information from physical properties, it
illustrates the construction of phase envelopes. The book presents
nine EOS theories, including some that take into account molecular
weight effects. Characteristic values are given in tables. It uses
the binary interaction model to predict the compositional window of
miscibility for copolymer/homopolymer blends and blends of
copolymers and terpolymers with common monomers. It discusses
Hansen fractional solubility parameter values, six phase diagram
types, the role of polymer architecture in phase behavior, and the
mathematical framework for multiple glass transition temperatures
found in partially miscible polymer blends. The author also
illustrates biomedical and commercial applications of
nanocomposites, the properties of various polymer alloys, Fick's
laws of diffusion and their implications during transient events,
and the use of the dynamic programming method in the sequence
alignment of DNA and proteins. The final chapter reviews the
thermodynamics of reversible polymerization and copolymerization.
Polymer blends offer improved performance/cost ratios and the
flexibility to tailor products to suit customers' needs. Exploring
physical phenomena, such as phase separation, this book provides
readers with methods to design polymer blends and predict the phase
behavior of binary polymer blends using desktop computers.
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