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This book describes in 2 parts experimental data with simple
explanations (Part I) and itinerant electron theories (Part II)
about magnetism and its related properties of 3d-intermetallic
compounds. Unlike 3d-metal alloys and oxides, theoretical as well
as experimental studies on 3d-intermetallic compounds such as
3d-pnictides and chalcogenides, on which we focus in this book,
seem unfortunately delayed. The objective of this book is to
motivate active studies in this ?eld in the future. We discuss in
detail magnetic and related properties of the 3d-transition-metal
pnictides and chalcogenides, which include the intermetallic
compounds expressed as MX and M X, and their mixed compoundsM M X,
MX X and M M X, 2 1?x x 1?y 2?x y x where M (M)isa3d element and X
(X ) a pnicogen (P, As, Sb, and Bi) or a chalcogen (S, Se, and Te).
Most of the MX-type compounds crystallize either in the
hexagonalNiAs-type structure or in the orthorhombicMnP-type
structure which is regarded as a distorted NiAs-type structure.
Crystallographic phase transition b- ween the NiAs- and the
MnP-typesoccursin some of MX-typecompoundswhen the
temperaturechanges. The M X-type compoundscrystallize in the
tetragonalCu Sb- 2 2 typestructure.Asdescribedin
detailinthisbook,manyofthecompoundsmentioned
aboveexhibitveryinterestingmagneticandcrystallographicphasetransitionscaused
by various means such as change of temperature, applications of
external magnetic ?eld or pressure, and change of the composition x
in the case of mixed compounds.
This book describes in 2 parts experimental data with simple
explanations (Part I) and itinerant electron theories (Part II)
about magnetism and its related properties of 3d-intermetallic
compounds. Unlike 3d-metal alloys and oxides, theoretical as well
as experimental studies on 3d-intermetallic compounds such as
3d-pnictides and chalcogenides, on which we focus in this book,
seem unfortunately delayed. The objective of this book is to
motivate active studies in this ?eld in the future. We discuss in
detail magnetic and related properties of the 3d-transition-metal
pnictides and chalcogenides, which include the intermetallic
compounds expressed as MX and M X, and their mixed compoundsM M X,
MX X and M M X, 2 1?x x 1?y 2?x y x where M (M)isa3d element and X
(X ) a pnicogen (P, As, Sb, and Bi) or a chalcogen (S, Se, and Te).
Most of the MX-type compounds crystallize either in the
hexagonalNiAs-type structure or in the orthorhombicMnP-type
structure which is regarded as a distorted NiAs-type structure.
Crystallographic phase transition b- ween the NiAs- and the
MnP-typesoccursin some of MX-typecompoundswhen the
temperaturechanges. The M X-type compoundscrystallize in the
tetragonalCu Sb- 2 2 typestructure.Asdescribedin
detailinthisbook,manyofthecompoundsmentioned
aboveexhibitveryinterestingmagneticandcrystallographicphasetransitionscaused
by various means such as change of temperature, applications of
external magnetic ?eld or pressure, and change of the composition x
in the case of mixed compounds.
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