This book provides introductory, comprehensive, and concise descriptions of amorphous chalcogenide semiconductors and related materials. It includes comparative portraits of the chalcogenide and related materials including amorphous hydrogenated Si, oxide and halide glasses, and organic polymers. It also describes effects of non-equilibrium disorder, in comparison with those in crystalline semiconductors.

Understanding the structural unit of crystalline solids is vital in determining their optical and electronic properties. However, the disordered nature of amorphous semiconductors, where no long-range order is retained, makes it difficult to determine their structure using traditional methods. This book shows how computer modelling can be used to overcome the difficulties that arise in the atomic scale identification of amorphous semiconductors. The book explains how to generate a random structure using computer modelling, providing readers with the techniques to construct realistic material structures. It shows how the optical and electronic properties are related to random structures. Readers will be able to understand the characteristic features of disordered semiconductors. The structural and electronic modifications by photon irradiation are also discussed in detail. This book is ideal for both physicists and engineers working in solid state physics, semiconductor engineering and electrical engineering.

This book provides introductory, comprehensive, and concise descriptions of amorphous chalcogenide semiconductors and related materials. It includes comparative portraits of the chalcogenide and related materials including amorphous hydrogenated Si, oxide and halide glasses, and organic polymers. It also describes effects of non-equilibrium disorder, in comparison with those in crystalline semiconductors.

"Amorphous Chalcogenide Semiconductors and Glasses" describes developments in the science and technology of this class of materials. This book offers an up-to-date treatment of chalcogenide glasses and amorphous semiconductors from basic principles to applications while providing the reader with the necessary theoretical background to understanding the material properties technology of this class of materials. This book offers an up-to-date treatment of chalcogenide glasses and amorphous semiconductors from basic principles to applications while providing the reader with the necessary theoretical background to understanding the material properties. Chalcogenides form a special class of materials, which have one or more of the elements from the chalcogen group, Group VI in the Periodic Table (S, Se. or Te) as a constituent; the chalcogen is mixed with other elements to form various "new" compounds and alloys. Chalcogenides are noncrystalline solids because their structure is "amorphous" or "glassy". Such structures have totally different properties than crystalline solids. Chalcogenide glasses have a number of very interesting and useful properties, which have been already exploited in the commercialization of new devices.

This book presents the current level of understanding of the structural, electronic and optical properties of amorphous semiconductors. As amorphous materials depart significantly from the crystalline counterparts, some of the basic problems associated with the validity of the effective mass approximation, whether K is a good quantum number, and concepts of phonons and excitons will be addressed in detail. A significant part of the book is devoted to present recent progress made in the understanding of light-induced degradations in amorphous semiconductors, which is regarded as the most limiting problem in device applications. The monograph presents a comprehensive review of both experimental and theoretical studies on amorphous semiconductors.