This book is focused on recent progress in the dynamically developing field of controlled/living radical polymerization. It is a sequel to ACS Symposium Series 685, 768, 854, and 944. The volume contains 24 chapters on other controlled/living radical polymerization techniques including kinetics and mechanism of RAFT, DT, NMP, and OMRP, macromolecular architecture by RAFT, DT, and NMP, materials prepared by RAFT and NMP, and industriral aspects of RAFT and NMP.

This book is focused on recent progress in the dynamically developing field of controlled/living radical polymerization. It is a sequel to ACS Symposium Series 685, 768, 854, and 944. Volume 1023 contains 26 chapters on mechanistic, synthetic and materials aspects of ATRP. Volume 1024 contains 24 chapters on other controlled/living radical polymerization techniques.

This book is the first volume in a two-volume compilation on controlled/living radical polymerization. It combines all important aspects of controlled radical polymerization: from synthetic procedures, to rational selection of reaction components, to understanding of the reaction mechanisms, to materials and applications.
This book is focused on recent progress in the rapidly developing field of controlled/living radical polymerization. It is a sequel to ACS Symposium Series 685, 768, 854, 944, 1023, and 1024. Volume 1100 deals with the mechanistic aspects of controlled radical polymerization and describes the recent advances in the most important techniques, whereas Volume 1101 contains chapters on new materials prepared by controlled radical polymerization as well as applications of these materials.

This review is focused on controlled/living radical polymerization methods for the preparation of various copolymers. A brief introduction to the subject of radical polymerization, and early attempts to control it, is followed by a detailed examination of the literautre on controlled/living radical copolymerizations from the mid-90's until 2001. The topics covered include statistical/gradient, block, graft, and star copolymers and the polymerization methods used to produce them. These copolymers were prepared using three major controlled radical methods (either nitroxide mediated polymerization, atom transfer radical polymerization or degenerative transfer) and a combination of polymerization techniques, including transformation chemistry or the simultaneous/dual living polymerizations, to achieve the desired chain architecture or topology. An evaluation of the current state of the field is also presented.

The progress in polymer science is revealed in the chapters of "Polymer Science: A Comprehensive Reference." In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources.
Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymersProvides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference workElectronic version has complete cross-referencing and multi-media componentsVolume editors are world experts in their field (including a Nobel Prize winner)

This unified presentation of cationic polymerization discusses initiation, propagation, transfer, and termination in cationic polymerizations of alkenes and heterocycles. It also elucidates the mechanisms of the reactions involved in all carbocationic and ring-opening polymerizations. It is written by internationally acclaimed experts in their respective fields.

The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.

Awarded the Literature Prize of the VCI This comprehensive textbook describes the synthesis, characterization and technical and engineering applications of polymers. Polymers are unique molecules and have properties different from any other class of materials.  We encounter them in everyday life, not only in the form of the well-known, large-volume plastics such as PE or PP or the many other special polymers, some of which are very specifically modified but also in nature as polymeric biomolecules, such as DNA. Our life, as we know it, would not only be completely different without macromolecules but it would also be biologically impossible. This textbook provides a broad knowledge of the basic concepts of macromolecular chemistry and the unique properties of this class of materials. Environmentally relevant topics, such as biopolymers and microplastic, which should not be missing in a contemporary textbook are also covered. Building on basic knowledge of organic chemistry and thermodynamics, the book presents an easy-to-understand yet in-depth picture of this very dynamic and increasingly important interdisciplinary science that involves elements of chemistry, physics, engineering, and the life sciences. Readers of this work can confirm their understanding of the text at the end of each chapter by working through a selection of exercises. In writing the book, great importance was attached to good readability despite the necessary depth of detail. It is a book that is just as suitable for students of chemistry and related courses as it is for the applied scientist in an industrial environment. The first edition of this work is so far the only textbook on polymer chemistry to be awarded the Literature Prize of the Fund of the German Chemical Industry Association in 2015.