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Ideals are simple and able to be easily understood, but never exist
in reality. In this book a theory based on the second law of
thermodynamics and its applications are described. In
thermodynamics there is a concept of an ideal gas which satisfies a
mathematical formula PV = RT. This formula can appro- mately be
applied to the real gas, so far as the gas has not an especially
high pressure and low temperature. In connection with the second
law of thermo- namics there is also a concept of reversible and
irreversible processes. The reversible process is a phenomenon
proceeding at an infinitely low velocity, while the irreversible
process is that proceeding with a finite velocity. Such a process
with an infinitely slow velocity can really never take place, and
all processes observed are always irreversible, therefore, the
reversible process is an ideal process, while the irreversible
process is a real process. According to the first law of
thermodynamics the energy increase dU of the thermodynamic system
is a sum of the heat dQ added to the system and work dW done in the
system. Practically, however, the mathematical formula of the law
is often expressed by the equation , or some similar equations
derived from this formula, is applied to many phenomena. Such
formulae are, however, th- retically only applicable to phenomena
proceeding at an infinitely low velocity, that is, reversible
processes or ideal processes.
Ideals are simple and able to be easily understood, but never exist
in reality. In this book a theory based on the second law of
thermodynamics and its applications are described. In
thermodynamics there is a concept of an ideal gas which satisfies a
mathematical formula PV = RT. This formula can appro- mately be
applied to the real gas, so far as the gas has not an especially
high pressure and low temperature. In connection with the second
law of thermo- namics there is also a concept of reversible and
irreversible processes. The reversible process is a phenomenon
proceeding at an infinitely low velocity, while the irreversible
process is that proceeding with a finite velocity. Such a process
with an infinitely slow velocity can really never take place, and
all processes observed are always irreversible, therefore, the
reversible process is an ideal process, while the irreversible
process is a real process. According to the first law of
thermodynamics the energy increase dU of the thermodynamic system
is a sum of the heat dQ added to the system and work dW done in the
system. Practically, however, the mathematical formula of the law
is often expressed by the equation , or some similar equations
derived from this formula, is applied to many phenomena. Such
formulae are, however, th- retically only applicable to phenomena
proceeding at an infinitely low velocity, that is, reversible
processes or ideal processes.
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