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Of system-number "Manganese," Part B, which de- scribes the Element
Manganese, has been completed. Also completed is Part C, describing
the compounds, with 10 volumes. Part A will present the history and
occurence of manganese. Volume A 1 on the history has already been
published, the other volumes dealing with occurence of manganese
are in preparation. Part D is devoted to the coordination
compounds. Part D 1, D 2, D 3, D 4, D 5 and D 6 thereof are already
available. The present volume "Manganese D 7" continues the
description of the coordination compounds. Complexes with nitriles,
with nitro-hydrocarbons, and with ligands containing sulfur,
selenium or tellurium are described. Many of the coordination
compounds containing sulfur are of analytical or biological
interest. A formula index lists the ligands and the empirical
formulas.
The present volume "Manganese" D 6 continues the description of the
manganese com- plexes. The introduction on p. 1 shows the classes
of complexes that have already been described in Chapters 1 through
29 in Volumes D1 to D 5. Complexes with Schiff bases and related
compounds (e.g., hydrazones, semicarbazones, or thiosemicarbazones)
are now described in Chapters 30 and 31 of this volume and
complexes with carbazones, thiocarba- zones and formazans in
Chapter 32. Complexes with Schiff bases play a central role in the
development of coordination chemistry. The publications range from
synthetic aspects to modern physicochemically or biochemically
relevant investigations on these compounds. The huge number of
studies results from the fact that these ligands may contain
various donor atoms, in addition to the azomethine group, and thus
can occur with variable denticities. About 1700 compounds derived
from 808 different ligands are described in the present volume.
Their arrangement is by ligand type and number of azomethine
groups.
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