Both experimental and theoretical investigations make it clear that mesoscale materials, that is, materials at scales intermediate between atomic and bulk matter, do not always behave in ways predicted by conventional theories of shock compression. At these scales, shock waves interact with local material properties and microstructure to produce a hierarchy of dissipative structures such as inelastic deformation fields, randomly distributed lattice defects, and residual stresses. A macroscopically steady planar shock wave is neither plane nor steady at the mesoscale. The chapters in this book examine the assumptions underlying our understanding of shock phenomena and present new measurements, calculations, and theories that challenge these assumptions. They address such questions as: - What are the experimental data on mesoscale effects of shocks, and what are the implications? - Can one formulate new mesoscale theories of shock dynamics? - How would new mesoscale theories affect our understanding of shock-induced phase transitions or fracture? - What new computational models will be needed for investigating mesoscale shocks?

This volume is concerned primarily with the chemical and physical effects of shock waves on typical materials. It compares naturally occurring materials with similar materials produced by shock compression in the laboratory, providing clues about the environment and events that produced the natural materials.

This volume concerns the fracture and fragmentation of solid materials that occurs when they are subjected to extremes of stress applied at the highest possible rates. The plan for the volume is to address experimental, theoretical, and com putational aspects of high-rate dynamic fracture and fragmentation, with emphasis on recent work. We begin with several chapters in which the emphasis falls on experimental methods and observations. These chapters address both macroscopic responses and the microscopic cause of these re sponses. This is followed by several chapters emphasizing modeling-the physical explanation and mathematical representation of the observations. Some of the models are deterministic, while others focus on the stochastic aspects of the observations. Often, the ov\ rall objective of investigation of dynamic fracture and fragmentation phenomena is provision of a means for predicting the entire course of an event that begins with a stimulus such as an impact and proceeds through a complicated deformation and fracture pro cess that results in disintegration of the body and formation of a rapidly expanding cloud of debris fragments. Analysis of this event usually involves development of a continuum theory and computer code that captures the experimental observations by incorporating models of the important pheno mena into a comprehensive description of the deformation and fracture pro cess. It is to this task that the work of the last few chapters is devoted."

Developments in experimental methods are providing an increasingly detailed understanding of shock compression phenomena on the bulk, intermediate, and molecular scales. This third volume in a series of reviews of the curent state of knowledge covers several diverse areas. The first group of chapters addresses fundamental physical and chemical aspects of the response of condensed matter to shock comression: equations of state, molecular-dynamic analysis, deformation of materials, spectroscopic methods. Two further chapters focus on a particular group of materials: ceramics. Another chapter discusses shock-induced reaction of condensed-phase explosives. And a final pair of chapters considers shock phenomena at low stresses from the point of view of continuum mechanics.

Research in the field of shock physics and ballistic impact has always been intimately tied to progress in development of facilities for accelerating projectiles to high velocity and instrumentation for recording impact phenomena. The chapters of this book, written by leading US and European experts, cover a broad range of topics and address researchers concerned with questions of material behaviour under impulsive loading and the equations of state of matter, as well as the design of suitable instrumentation such as gas guns and high-speed diagnostics. Applications include high-speed impact dynamics, the inner composition of planets, syntheses of new materials and materials processing. Among the more technologically oriented applications treated is the testing of the flight characteristics of aeroballistic models and the assessment of impacts in the aerospace industry.

My intent in writing this book is to present an introduction to the thermo- chanical theory required to conduct research and pursue applications of shock physics in solid materials. Emphasis is on the range of moderate compression that can be produced by high-velocity impact or detonation of chemical exp- sives and in which elastoplastic responses are observed and simple equations of state are applicable. In the interest of simplicity, the presentation is restricted to plane waves producing uniaxial deformation. Although applications often - volve complex multidimensional deformation fields it is necessary to begin with the simpler case. This is also the most important case because it is the usual setting of experimental research. The presentation is also restricted to theories of material response that are simple enough to permit illustrative problems to be solved with minimal recourse to numerical analysis. The discussions are set in the context of established continuum-mechanical principles. I have endeavored to define the quantities encountered with some care and to provide equations in several convenient forms and in a way that lends itself to easy reference. Thermodynamic analysis plays an important role in continuum mechanics, and I have included a presentation of aspects of this subject that are particularly relevant to shock physics. The notation adopted is that conventional in expositions of modern continuum mechanics, insofar as possible, and variables are explained as they are encountered. Those experienced in shock physics may find some of the notation unconventional.

Research in the field of shock physics and ballistic impact has always been intimately tied to progress in development of facilities for accelerating projectiles to high velocity and instrumentation for recording impact phenomena. The chapters of this book, written by leading US and European experts, cover a broad range of topics and address researchers concerned with questions of material behaviour under impulsive loading and the equations of state of matter, as well as the design of suitable instrumentation such as gas guns and high-speed diagnostics. Applications include high-speed impact dynamics, the inner composition of planets, syntheses of new materials and materials processing. Among the more technologically oriented applications treated is the testing of the flight characteristics of aeroballistic models and the assessment of impacts in the aerospace industry.

The shock waves produced by meteorite impacts give rise not only to the obvious craters seen on planets and their satellites but also to subtle effects seen only with chemical and petrographic examination of the shocked material. Shock waves in the interplanetary and interstellar medium play an important role in the formation of stars and planets, including the solar system. They also produce important chemical effects in interstellar clouds of dust and gas, --- including the production of rather complex organic molecules. This volume is concerned primarily with the chemical and physical effects of shock waves on typical Earth and planetary solid materials. The emphasis is on comparing naturally occurring materials with similar materials produced by shock compression in the laboratory. Such comparisons can provide clues about the environment and events that produced the natural materials. The chapters in the book deal with three main topics: * methods used to investigate the effects of shock on recovered minerals and rocks * effects of shock on carbon and hydrocarbons * subtle effects of shocks on geochemistry, such as shock induced redistribution of lead isotopes, the effect of the great impact at the end of the Cretaceous on atmospheric SO2 and CO2, and effect of shocks on ices.

My intent in writing this book is to present an introduction to the thermo- chanical theory required to conduct research and pursue applications of shock physics in solid materials. Emphasis is on the range of moderate compression that can be produced by high-velocity impact or detonation of chemical exp- sives and in which elastoplastic responses are observed and simple equations of state are applicable. In the interest of simplicity, the presentation is restricted to plane waves producing uniaxial deformation. Although applications often - volve complex multidimensional deformation fields it is necessary to begin with the simpler case. This is also the most important case because it is the usual setting of experimental research. The presentation is also restricted to theories of material response that are simple enough to permit illustrative problems to be solved with minimal recourse to numerical analysis. The discussions are set in the context of established continuum-mechanical principles. I have endeavored to define the quantities encountered with some care and to provide equations in several convenient forms and in a way that lends itself to easy reference. Thermodynamic analysis plays an important role in continuum mechanics, and I have included a presentation of aspects of this subject that are particularly relevant to shock physics. The notation adopted is that conventional in expositions of modern continuum mechanics, insofar as possible, and variables are explained as they are encountered. Those experienced in shock physics may find some of the notation unconventional.

Both experimental and theoretical investigations make it clear that mesoscale materials, that is, materials at scales intermediate between atomic and bulk matter, do not always behave in ways predicted by conventional theories of shock compression. At these scales, shock waves interact with local material properties and microstructure to produce a hierarchy of dissipative structures, such as inelastic deformation fields, randomly distributed lattice defects, and residual stresses. A macroscopically steady planar shock wave is neither plane nor steady at the mesoscale. The chapters in this book examine the assumptions underlying our understanding of shock phenomena and present new measurements, calculations, and theories that challenge these assumptions. They address such questions as: - What are the experimental data on mesoscale effects of shocks, and what are the implications? - Can one formulate new mesoscale theories of shock dynamics? - How would new mesoscale theories affect our understanding of shock-induced phase transitions or fracture? - What new computational models will be needed for investigating mesoscale shocks?