Heat equation asymptotics of a generalized Ahlfors Laplacian on a manifold with boundary.- Recurrent versus diffusive quantum behavior for time-dependent Hamiltonians.- Perturbations of spectral measures for Feller operators.- A global approach to the location of quantum resonances.- On estimates for the eigen-values in some elliptic problems.- Quantum scattering with long-range magnetic fields.- Spectral invariance and submultiplicativity for Frechet algebras with applications to pseudo-differential operators and ?* -quantization.- Decroissance exponentielle des fonctions propres pour l'operateur de Kac: le cas de la dimension > 1.- Second order perturbations of divergence type operators with a spectral gap.- On the Weyl quantized relativistic Hamiltonian.- Spectral asymptotics for the family of commuting operators.- Pseudo differential operators with negative definite functions as symbol: Applications in probability theory and mathematical physics.- One-dimensional Schroedinger operators with high potential barriers.- General boundary value problems in regions with corners.- Some results for nonlinear equations in cylindrical domains.- Global representation of Langrangian distributions.- Stable asymptotics of the solution to the Dirichlet problem for elliptic equations of second order in domains with angular points or edges.- Maslov operator calculus and non-commutative analysis.- Relative time delay and trace formula for long range perturbations of Laplace operators.- Functional calculus and Fredholm criteria for boundary value problems on noncompact manifolds.- The variable discrete asymptotics of solutions of singular boundary value problems.- Schroedinger operators with arbitrary non-negative potentials.- Abel summability of the series of eigen- and associated functions of the integral and differential operators.- The relativistic oscillator.- On the ratio of odd and even spectral counting functions.- A trace class property of singularly perturbed generalized Schroedinger semi-groups.- Radiation conditions and scattering theory for N-particle Hamiltonians (main ideas of the approach).

This book contains the proceedings of the International Conference on Mathematical Results in Quantum Mechanics held in Blossin, Germany, May 17-21, 1993. Its purpose is to draw attention to the recent developments in quantum mechanics and related mathematical problems. The book is addressed to the wide audience of mathematicians and physicists interested in contemporary quantum physics and associated mathematical problems. The reader will find sections not only on traditional subjects such as SchrAdinger and Dirac operators and generalized SchrAdinger generators, but also on stochastic spectral analysis, many-body problems and statistical physics, chaos, and operator theory and its applications. Contributors: SchrAdinger and Dirac operators: M.Sh. Birman, V. Grecchi, R. Hempel, M. Hoffmann-Ostenhof, Y. Saito, G. Stolz, M. Znojil a Generalized SchrAdinger operators: J.-P. Antoine, J.F. Brasche, P. Duclos, R. Hempel, M. Klein, P. Stovicek a Stochastic spectral analysis: M. Demuth, V.A. Liskevich, E.M. Ouhabaz, P. Stollmann a Many-body problems and statistical physics: M. Fannes, R. Gielerak, M. HA1/4bner, A.M. Khorunzhy, H. Lange, N. Macris, Yu.A. Petrina, K.B. Sinha, A. Verbeure a Chaos: J. Dittrich, P. Seba, K. Zyczkowski a Operator theory and its application: F. Bentosela, V. Buslaev, A.N. Kochubei, A.Yu. Konstantinov, V. Koshmanenko, H. Neidhardt, G. Nenciu, D. Robert

The intention of the international conference PDE2000 was to bring together specialists from different areas of modern analysis, mathematical physics and geometry, to discuss not only the recent progress in their own fields but also the interaction between these fields. The special topics of the conference were spectral and scattering theory, semiclassical and asymptotic analysis, pseudodifferential operators and their relation to geometry, as well as partial differential operators and their connection to stochastic analysis and to the theory of semigroups. The scientific advisory board of the conference in Clausthal consisted of M. Ben-Artzi (Jerusalem), Chen Hua (Peking), M. Demuth (Clausthal), T. Ichinose (Kanazawa), L. Rodino (Turin), B.-W. Schulze (Potsdam) and J. SjAstrand (Paris). The book is aimed at researchers in mathematics and mathematical physics with interests in partial differential equations and all its related fields.

This volume contains the proceedings of the international conference on " Operator Calculus and Spectral Theory" in Lambrecht, Germany, Decem- ber 9. - 14. , 1991, sponsored by the Deutsche Forschungsgemeinschaft, and by the Karl-Weierstrass-Institute of Mathematics, Berlin. The idea was to bring together specialists from different areas of modern analysis, geometry and mathematical physics, in a similar spirit as in the earlier series of conferences of the Karl-Weierstrass- Institute (Ludwigsfelde, 1976; Reinhardsbrunn, 1985; Holzhau, 1988; Breitenbrunn,1990). Berlin, Mainz M. Demuth B. Gramsch B. -W. Schulze List of talks given in La. brecht. 8. - 14. December 91 Name Title S. Albeverio Some recent deveiopments in Dirichlet forms and associated processes U. Bunke On the spectral flow of Dirac operators with negative definite functions as symbols - applications in probability theory and mathematical physics M. Combescure Recurrent versus diffusive behaviour for time-dependent quantum Hamiltonian E. B. Davies Analysis on graphs and noncommutative geometry M. Demuth On stochastic spectral analysis and asymptotics for Schrodinger operators P. Duclos A global approach to the location of quantum resonances v. v. Egorov On negative spectrum of elliptic operators V. EnB Non-threshold states of long-range N-body problems B. Gramsch -algebras and microlocal analysis P. B. Gilkey On the index of geometrical operators for Riemannian manifolds with boundary B. Helffer Spectral problems in statistical mechanics R. Hempe I Second order pertubations of elliptic operators with periodic principal part T. Ichinose On the Weyl quantized relativistic Hamiltonian V. V.

The last decades have demonstrated that quantum mechanics is an inexhaustible source of inspiration for contemporary mathematical physics. Of course, it seems to be hardly surprising if one casts a glance toward the history of the subject; recall the pioneering works of von Neumann, Weyl, Kato and their followers which pushed forward some of the classical mathematical disciplines: functional analysis, differential equations, group theory, etc. On the other hand, the evident powerful feedback changed the face of the "naive" quantum physics. It created a contem porary quantum mechanics, the mathematical problems of which now constitute the backbone of mathematical physics. The mathematical and physical aspects of these problems cannot be separated, even if one may not share the opinion of Hilbert who rigorously denied differences between pure and applied mathemat ics, and the fruitful oscilllation between the two creates a powerful stimulus for development of mathematical physics. The International Conference on Mathematical Results in Quantum Mechan ics, held in Blossin (near Berlin), May 17-21, 1993, was the fifth in the series of meetings started in Dubna (in the former USSR) in 1987, which were dedicated to mathematical problems of quantum mechanics. A primary motivation of any meeting is certainly to facilitate an exchange of ideas, but there also other goals. The first meeting and those that followed (Dubna, 1988; Dubna, 1989; Liblice (in the Czech Republic), 1990) were aimed, in particular, at paving ways to East-West contacts."

In the tricyclooctanone approach to polyquinane syntheses[ll the photochemical rearrangement of bicyclo[2.2.2]octenone, 1a 2a,[2J has been the initial key reaction providing tricyclo- 2 [3.3.0.0 ' S]octan-3-one as a chiral building block.[3-SJ This reaction - an oxadi-n-methane (ODPM) process - and the 1,3-acyl shift (AS) forming the cyclobutanone 3 are quite generally the characteristic re- arrangement paths undergone by ~,~-unsaturated ketones (~,~-UKs) upon triplet sensitization and direct excitation with ultraviolet light, respectively. R' R' hv hv R~O ~ ~ (sens) WO ~ R ONR R 1a-c 2a-c 3a-c a R=R'=H b R = CH , R'= H 3 c R = R'= CH 3 As a polyvalent building block, the enantiomers of which are readily accessible from cheap bulk chemicals such as benzene and its derivatives, the parent system 1a and three younger generations of its class (Sections 3.1. - 3.4.) have no equal among synthetically useful photochemical rearrangements. 2. THE PHOTOCHEMISTRY OF ~,~-UNSATURATED KETONES The literature dealing with the spectroscopy and photo- chemistry of ~,~-UKs has been exhaustively and critically reviewed around 1975 by Dauben et al.[6l and Houk,[7J and in 1980 by Schuster.[ SlI1 The 1,3-AS was first observed on direct excitation of 1) For more recent papers on i3,~-UK photochemistry see [9-24]. 64 ~ R' hv ~o hv .,.