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This succinct text presents an accessible account of the main classes of transition metal organometallic complexes and introduces the reader to the chemistry of compounds with metal carbon O bonds: metal carbonyls, metal alkyls, and metal alkylidenes and alkylidynes. The synthetic methods leading to each class of comounds are illustrated with pertinent examples, followed by the discussion of characterisitic structures and reactivity patterns. The systematic approach will provide undergraduate readers with a concise overview of this area of inorganic chemistry.
The interaction of transition metals with unsaturated molecules has led to fundamental insights in the nature of the chemical bond which, in turn, has provided the basis of important present-day applications such as transition metal mediated synthesis or homogeneous and heterogeneous catalysis. This slim volume outlines the chemistry and discusses the bonding in of some of the most important classes of organometallic compounds: the complexes of transition metals with Pi-ligands such as alkenes, alkynes, arenes, and cyclopentadienyl and allyl ligands. The material covered follows on from Organometallics I which covers the chemistry of complexes with metal-carbon delta-bonds. Synthetic and reactivity aspects of each class of compounds are illustrated with pertinent examples from the recent chemical literature. Highlighted excursions relate the fundamental chemistry to current synthetic or catalytic applications.
Organometallic chemistry explores the chemistry of the often
bewildering variety of compounds featuring metal-carbon bonds. A
field that has underpinned the development of new synthetic methods
and materials, it is also central to our understanding of
catalysis. In his text, Manfred Bochmann distils the extensive
knowledge of the field into a succinct overview of essential
concepts. The book is enriched throughout with examples that
demonstrate how our understanding of organometallic chemistry has
led to new applications in research and industry - not least in
relation to catalysis - and an extensive reaction schemes and
structures give added clarity to the concepts being explained.
Striking just the right balance between breadth and depth - and
with features throughout to support the learning process -
Organometallics and Catalysis is the perfect introduction for
undergraduate and graduate students who need a thorough grounding
on the subject or are embarking on new research areas. Online
Resource Centre: The Online Resource Centre to accompany
Organometallics and Catalysis: An Introduction features: For
registered adopters of the text: - Figures from the book in
electronic format For everyone: - Curated links to relevant video
materials on YouTube
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