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The first stage of the physics of long, flexible chains was
pioneered by eminent scientists such as Debye, Kuhn, Kramers, and
Flory, who formulated the basic ideas. In recent years, because of
the availability of new experimental and theoretical tools, a
second stage of the physics of polymers has evolved. In this book,
a noted physicist explains the radical changes that have taken
place in this exciting and rapidly developing field.Pierre-Gilles
de Gennes points out the three developments that have been
essential for recent advances in the study of large-scale
conformations and motions of flexible polymers in solutions and
melts. They are the advent of neutron-scattering experiments on
selectively deuterated molecules; the availability of inelastic
scattering of laser light, which allows us to study the cooperative
motions of the chains; and the discovery of an important
relationship between polymer statistics and critical phenomena,
leading to many simple scaling laws.Until now, information relating
to these advances has not been readily accessible to physical
chemists and polymer scientists because of the difficulties in the
new theoretical language that has come into use. Professor de
Gennes bridges this gap by presenting scaling concepts in terms
that will be understandable to students in chemistry and
engineering as well as in physics.
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