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Showing 1 - 2 of 2 matches in All Departments
The book entitled with "Determination of Stability Constants of Binary and Mixed Complexes" deals with the stability constants of metal complexes can be very easily calculated by this technique, therefore the present method is advantageous over other methods ( viz, polarographic, potentiometric, solubility etc) which usually suffers from a number of vitiating factors (e.g. diffusion, ionic strength and temperature ). The Electrophoretic technique is almost free from these vitiating factors and results are fairly reliable. Its further extension that these studies can be used to reduced the level of these metal ions in biological system. These studies may also be used for the resolution of racemic mixture of penicillamine and other amino acids.
The book entitled with "Solution Ionophoretic Technique in Study of Metal-Ligand Equilibria" deals with solution ionophoretic technique, which is used for the determination of the stability constants of metal complexes is better than other physiochemical methods but it has some vitiating factors (e.g. diffusion, ionic strength and temperature). This technique is free from these vitiating factors and results are fairly reliable. The technique used in these studies proved to be very useful in studying the stepwise complextion in solution. The special electrophoretic tube which has been designed for this work, yields better results after standardization. This technique provides vivid picturization of complex formation whose stability constant can be determined easily. Its further extension in the study of mixed complexation reactions is obviously a unique advancement in the realm of coordination chemistry.
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