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This title provides an overview of the innovative use of
electro-kinetic phenomena in experimentally exploring
non-equilibrium regions of chemically non-reacting systems.
Transport phenomena mediated by charged liquid-liquid interfaces
and solid-liquid interfaces are also covered. Transport phenomena
mediated by electrified interfaces are discussed in the context of
a number of important areas, including, soil/water systems, phase
transfer catalysis, animal/plant physiology and mimicking
taste/smell sensing mechanisms.
- Provides an overview of the innovative use of electro-kinetic
phenomena
- Discusses conventional electro-kinetics and other transport
phenomena mediated by charged interfaces
- Of special interest to those working in the area of interface
science
The book presents a critical and comprehensive account of
Non-equilibrium Physical Chemistry from theoretical and
experimental angle. It covers a wide spectrum of non-equilibrium
phenomena from steady state close to equilibrium to non-linear
region involving transition to bistability, temporal oscillations,
spatio-temporal oscillations and finally to far from equilibrium
phenomena such as complex pattern formation, dynamic instability at
interfaces, Chaos and complex growth phenomena (fractals) in
Physico-chemical systems.
Part I of the book deals with theory and experimental studies
concerning transport phenomena in membranes (Thermo-osmosis,
Electroosmotic ) and in continuous systems (Thermal diffusion,
Soret effect) close to equilibrium Experimental tests provide
insight into the domain of validity of Non-equilibrium
Thermodynamics, which is the major theoretical tool for this
region. Later developments in Extended Irreversible Thermodynamics
and Non-equilibrium Molecular dynamics have been discussed in the
Appendix.
Part II deals with non-linear steady states and bifurcation to
multistability, temporal and spatio- temporal oscillations
(Chemical waves). Similarly Part II deals with more complex
phenomena such as Chaos and fractal growth occurring in very far
from equilibrium region. Newer mathematical techniques for
investigating such phenomena along with available experimental
studies.
Part IV deals with analogous non-equilibrium phenomena occurring in
the real systems (Socio-political, Finance and Living systems etc.)
for which physico-chemical systems discussed in earlier chapters
provide a useful model for development of theories based on
non-linear science and science of complexity.
Key Features:
- The book provides a critical account of theoretical studies on
non-equilibrium phenomenon from region close to equilibrium to far
equilibrium.
- Experimental studies have been reported which provide test of the
theories and their limitations.
- Impacts of the concepts developed in non-equilibrium Physical
Chemistry in sociology, economics and other social science and
living systems has been discussed.
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