This undergraduate teaching text and accompanying Periodic Table DVD, provides an introduction to the transition metals. The first two chapters introduce the reader to the chemistry of the first-row transition elements in different oxidation states, in particular +2 and +3 and their relative stability, largely using interactive activities and video on the DVD. This is followed by a study of coordination chemistry and the stability of complexes. Later chapters look at theories of metal-ligand bonding, in particular the way models can be used to rationalise many of the properties of transition metals and their compounds, such as colour, magnetism and stereochemistry. Starting with the simple, yet powerful crystal field approach, the book finishes with a largely pictorial treatment of molecular orbital theory. The text also includes interactive activities on the accompanying Periodic Table DVD, in-text questions with answers, full colour diagrams and revision exercises on an associated website www.rsc.org/metalsandlife

To appreciate the chemistry and physical properties of complexes of the transition series, an understanding of metal-ligand interactions applied to complexes of the d-block is needed. Metal Ligand Bonding aims to provide this through an accessible, detailed, non-mathematical approach. Initial chapters detail the crystal-field model, using it to describe the use of magnetic measurements to distinguish complexes with different electronic configurations and geometries. Subsequent chapters look at the molecular orbital theory of transition metal complexes using a pictorial approach. Bonding in octahedral complexes is explored and electronic spectra and magnetic properties are given extensive coverage. The material addressed in this book forms the foundation of undergraduate lecture courses on d-block chemistry and facilitates learning through various key features, including: full colour diagrams; in-text questions with answers; revision exercises and clearly defined learning outcomes to encourage a reflective approach to study; an associated website; and experimental data and observations from everyday life. A basic knowledge of atomic and molecular orbitals as applied to main group elements is assumed.