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Studies on the First World War are plentiful but most tend to focus
on the combatants. This volume offers a new and highly original
perspective that shows the reader the civilian side of this
protracted and destructive war through a succession of "snapshots":
130 excerpts from leading American and Canadian newspapers provide
a collective portrait of life behind the battle lines, what is
often called the "second" front. Written principally by Paris-based
journalists, and intended for popular reading audiences, these
articles depict ordinary people in a way that still touches the
reader of today. They record eye-witness testimony of Paris under
aerial bombardment, the gutted cathedrals at Reims and Arras, the
cemeteries around Compiegne, the subterranean living quarters at
Cambrai, and the heart-breaking orphanages at Chambly. Introduced
and concluded by the editor, the volume also offers biographical
notes on some of the leadingjournalist contributors, maps to
familiarize readers with the geography of northern France, and
detailed subject and geographical indices. The volume ends with a
select bibliography of works on the subject of French civilian life
during the Great War.
France's drift into war and subsequent collapse often have been
attributed to her level of confidence. Either she had too much, or
too little. This work contends that these two moods were not
mutually exclusive, that they coexisted throughout the interwar
years, sustained by competing visions of the Republic and of the
best way to ensure national security. Early chapters describe the
tensions within French interwar foreign policy, as well as the
ensuing historiographical tensions among scholars intent on
interpreting the French experience. Subsequent chapters explore
tensions in defence and economic policies, domestic politics and
ideological allegiance, public attitudes and opinion.
Thoroughly updated, Introduction to Polymers, Third Edition
presents the science underpinning the synthesis, characterization
and properties of polymers. The material has been completely
reorganized and expanded to include important new topics and
provide a coherent platform for teaching and learning the
fundamental aspects of contemporary polymer science. New to the
Third EditionPart IThis first part covers newer developments in
polymer synthesis, includingliving radical polymerization,
catalytic chain transfer and free-radical ring-opening
polymerization, along with strategies for the synthesis of
conducting polymers, dendrimers, hyperbranched polymers and block
copolymers. Polymerization mechanisms have been made more explicit
by showing electron movements. Part IIIn this part, the authors
have added new topics on diffusion, solution behaviour of
polyelectrolytes and field-flow fractionation methods. They also
greatly expand coverage of spectroscopy, including UV visible,
Raman, infrared, NMR and mass spectroscopy. In addition, the Flory
Huggins theory for polymer solutions and their phase separation is
treated more rigorously. Part IIIA completely new, major topic in
this section is multicomponent polymer systems. The book also
incorporates new material on macromolecular dynamics and reptation,
liquid crystalline polymers and thermal analysis. Many of the
diagrams and micrographs have been updated to more clearly
highlight features of polymer morphology. Part IVThe last part of
the book contains major new sections on polymer composites, such as
nanocomposites, and electrical properties of polymers. Other new
topics include effects of chain entanglements, swelling of
elastomers, polymer fibres, impact behaviour and ductile fracture.
Coverage of rubber-toughening of brittle plastics has also been
revised and expanded.
Studies on the First World War are plentiful but most tend to focus
on the combatants. This volume offers a new and highly original
perspective that shows the reader the civilian side of this
protracted and destructive war through a succession of "snapshots":
130 excerpts from leading American and Canadian newspapers provide
a collective portrait of life behind the battle lines, what is
often called the "second" front. Written principally by Paris-based
journalists, and intended for popular reading audiences, these
articles depict ordinary people in a way that still touches the
reader of today. They record eye-witness testimony of Paris under
aerial bombardment, the gutted cathedrals at Reims and Arras, the
cemeteries around Compiegne, the subterranean living quarters at
Cambrai, and the heart-breaking orphanages at Chambly. Introduced
and concluded by the editor, the volume also offers biographical
notes on some of the leadingjournalist contributors, maps to
familiarize readers with the geography of northern France, and
detailed subject and geographical indices. The volume ends with a
select bibliography of works on the subject of French civilian life
during the Great War.
Thoroughly updated, Introduction to Polymers, Third Edition presents the science underpinning the synthesis, characterization and properties of polymers. The material has been completely reorganized and expanded to include important new topics and provide a coherent platform for teaching and learning the fundamental aspects of contemporary polymer science.
New to the Third Edition
Part I
This first part covers newer developments in polymer synthesis, including ‘living’ radical polymerization, catalytic chain transfer and free-radical ring-opening polymerization, along with strategies for the synthesis of conducting polymers, dendrimers, hyperbranched polymers and block copolymers. Polymerization mechanisms have been made more explicit by showing electron movements.
Part II
In this part, the authors have added new topics on diffusion, solution behaviour of polyelectrolytes and field-flow fractionation methods. They also greatly expand coverage of spectroscopy, including UV visible, Raman, infrared, NMR and mass spectroscopy. In addition, the Flory–Huggins theory for polymer solutions and their phase separation is treated more rigorously.
Part III
A completely new, major topic in this section is multicomponent polymer systems. The book also incorporates new material on macromolecular dynamics and reptation, liquid crystalline polymers and thermal analysis. Many of the diagrams and micrographs have been updated to more clearly highlight features of polymer morphology.
Part IV
The last part of the book contains major new sections on polymer composites, such as nanocomposites, and electrical properties of polymers. Other new topics include effects of chain entanglements, swelling of elastomers, polymer fibres, impact behaviour and ductile fracture. Coverage of rubber-toughening of brittle plastics has also been revised and expanded.
While this edition adds many new concepts, the philosophy of the book remains unchanged. Largely self-contained, the text fully derives most equations and cross-references topics between chapters where appropriate. Each chapter not only includes a list of further reading to help readers expand their knowledge of the subject but also provides problem sets to test understanding, particularly of numerical aspects.
Table of Contents
CONCEPTS, NOMENCLATURE AND SYNTHESIS OF POLYMERS
Concepts and Nomenclature
The Origins of Polymer Science and the Polymer Industry
Basic Definitions and Nomenclature
Molar Mass and Degree of Polymerization
Principles of Polymerization
Introduction
Classification of Polymerization Reactions
Monomer Functionality and Polymer Skeletal Structure
Functional Group Reactivity and Molecular Size: The Principle of Equal Reactivity
Step Polymerization
Introduction
Linear Step Polymerization
Non-Linear Step Polymerization
Radical Polymerization
Introduction to Radical Polymerization
The Chemistry of Conventional Free-Radical Polymerization
Kinetics of Conventional Free-Radical Polymerization
Free-Radical Polymerization Processes
Reversible-Deactivation (‘Living’) Radical Polymerizations
Non-Linear Radical Polymerizations
Ionic Polymerization
Introduction to Ionic Polymerization
Cationic Polymerization
Anionic Polymerization
Group-Transfer Polymerization
Stereochemistry and Coordination Polymerization
Introduction to Stereochemistry of Polymerization
Tacticity of Polymers
Geometric Isomerism in Polymers Prepared from Conjugated Dienes
Ziegler–Natta Coordination Polymerization
Metallocene Coordination Polymerization
Ring-Opening Polymerization
Introduction to Ring-Opening Polymerization
Cationic Ring-Opening Polymerization
Anionic Ring-Opening Polymerization
Free-Radical Ring-Opening Polymerization
Ring-Opening Metathesis Polymerization
Specialized Methods of Polymer Synthesis
Introduction
Solid-State Topochemical Polymerization
Polymerization by Oxidative Coupling
Precursor Routes to Intractable Polymers
Supramolecular Polymerization (Polyassociation)
Copolymerization
Introduction
Step Copolymerization
Chain Copolymerization
Block Copolymer Synthesis
Graft Copolymer Synthesis
CHARACTERIZATION OF POLYMERS
Theoretical Description of Polymers in Solution
Introduction
Thermodynamics of Polymer Solutions
Chain Dimensions
Frictional Properties of Polymer Molecules in Dilute Solution
Number-Average Molar Mass
Introduction to Measurements of Number-Average Molar Mass
Membrane Osmometry
Vapour Pressure Osmometry
Ebulliometry and Cryoscopy
End-Group Analysis
Effects of Low Molar Mass Impurities upon Mn
Scattering Methods
Introduction
Static Light Scattering
Dynamic Light Scattering
Small-Angle X-Ray and Neutron Scattering
Frictional Properties of Polymers in Solution
Introduction
Dilute Solution Viscometry
Ultracentrifugation
Molar Mass Distribution
Introduction
Fractionation
Gel Permeation Chromatography
Field-Flow Fractionation
Mass Spectroscopy
Chemical Composition and Molecular Microstructure
Introduction
Principles of Spectroscopy
Ultraviolet and Visible Light Absorption Spectroscopy
Infrared Spectroscopy
Raman Spectroscopy
Nuclear Magnetic Resonance Spectroscopy
Mass Spectroscopy
PHASE STRUCTURE AND MORPHOLOGY OF BULK POLYMERS
The Amorphous State
Introduction
The Glass Transition
Factors Controlling the Tg
Macromolecular Dynamics
The Crystalline State
Introduction
Determination of Crystal Structure
Polymer Single Crystals
Semi-Crystalline Polymers
Liquid Crystalline Polymers
Defects in Crystalline Polymers
Crystallization
Melting
Multicomponent Polymer Systems
Introduction
Polymer Blends
Block Copolymers
PROPERTIES OF BULK POLYMERS
Elastic Deformation
Introduction
Elastic Deformation
Elastic Deformation of Polymers
Viscoelasticity
Introduction
Viscoelastic Mechanical Models
Boltzmann Superposition Principle
Dynamic Mechanical Testing
Frequency Dependence of Viscoelastic Behaviour
Transitions and Polymer Structure
Time–Temperature Superposition
Effect of Entanglements
Non-Linear Viscoelasticity
Elastomers
Introduction
Thermodynamics of Elastomer Deformation
Statistical Theory of Elastomer Deformation
Stress–Strain Behaviour of Elastomers
Factors Affecting Mechanical Behaviour
Yield and Crazing
Introduction
Phenomenology of Yield
Yield Criteria
Deformation Mechanisms
Crazing
Fracture and Toughening
Introduction
Fundamentals of Fracture
Mechanics of Fracture
Fracture Phenomena
Toughened Polymers
Polymer Composites
Introduction to Composite Materials
Matrix Materials
Types of Reinforcement
Composite Composition
Particulate Reinforcement
Fibre Reinforcement
Nanocomposites
Electrical Properties
Introduction to Electrical Properties
Dielectric Properties
Conduction in Polymers
Polymer Electronics
Answers to Problems
Index
Problems and Further Reading appear at the end of each chapter.
"Sartre is a true post-colonial pioneer. His ethical and political
struggle against all forms of oppression and exploitation speak to
the problems of our own times with a rare courage and
cogency."
Homi K. Bhabha, Anne F. Rothenberg Professor of English and
American Literature Harvard University
Nearly forty years after its first publication in French, this
collection of Sartre's writings on colonialism remains a supremely
powerful, and relevant, polemical work. Over a series of thirteen
essays Sartre brings the full force of his remarkable intellect
relentlessly to bear on his own country's conduct in Algeria, and
by extension, the West's conduct in the Third World in general. The
tussle is not equal, and the western imperialists emerge at the
end, bloody, bruised and thoroughly chastened. Most startling of
all is Sartre's advocacy of violence as a legitimate response to
repression, motivated by his belief that freedom was the central
characteristic of being human. Whether one agrees with his every
conclusion or not, "Colonialism and Neo-Colonialism" shows a
philosopher passionately engaged in using philosophy as a force for
change in the world. An important influence on postcolonial thought
ever since, this book takes on added resonance in the light of the
West's most recent bout of interference in the non-Western world.
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