In 2002, the Swedish Metal Information Task Force (MITF) engaged the Environmental Research Group (MFG) to update previous monographs on copper, zinc and major alloying metals (such as chromium, nickel and molybdenum) in society and in the environment. This book presents new results on metal fluxes from society to the environment, on metal speciation in water, soil and sediment, and its interpretation in terms of mobility, biological uptake and toxicity. The scientific fundamentals of new approaches, like the Acid Volatile Sulphide (AVS) concept to predict metal bioavailability in sediments, and the Biotic Ligand Model (BLM) to calculate the toxicity of metals to aquatic organisms, are critically evaluated, with a focus on copper, nickel, zinc, and, in part, chromium.

Recent scientific advances now offer an improved understanding of the mechanisms and factors controlling the intricate behaviour of trace metals, their interactions, uptake and effect in natural systems. Traditional risk assessment methods usually built on quite crude toxicity tests done in unrealistic "laboratory waters," and did not consider natural conditions. In contrast, modern approaches now increasingly involve the full utilisation of site-specific factors, which are decisive for the formation of bioavailable and toxic metal forms.

Audience: This book provides excellent guidance not only to scientists focusing on the assessment of the ecological risk of metals, but also to authorities, decision makers in industry, educational staff and the interested public concerned with the occurrence and fate of trace metals.

It is not long ago that scientists realized, our study and understanding of most environmental problems call for a cross-sectional, more holistic view. In fact, environmental geochemistry became one of the legs to stand on for such a required interdisciplinary approach. Geochemists do not only describe the elemental composition and pro cesses of natural systems, such as soils, ground or surface waters, but they also establish the methodology to quantify material rates and turnover. Today, geochemical expertise has become indispensable when monitoring the fate of noxious chemicals, like-metallic pollu tants released to the environment. To know how trace metals will be have and react in complex systems under changing conditions, might provide us with a more realistic estimate of what is really acceptable in terms of quality standards. This would ease the formulation of ade quate environmental objectives, strategies and criteria to handle emerging pollution situations. Moreover, to take notice of geochemi cal principles will support our endeavor to improve the way we deal with limited and nonrenewable resources. It is exactly here, i. e. at the interface between natural elemental processes and the way we use them, that geochemical approaches meet the demand of technical at tempts to minimize the impact of environmentally relevant activities, like mining, waste handling, or manufacturing. The consideration to include geochemically derived concepts into the search for technical solutions is not really new, but has a long tradition during the evolution of modern societies."