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The aim of this book is to provide the reader with a modern
presentation of ionic solutions at interfaces, for physical
chemists, chemists and theoretically oriented experimentalists in
this field. The discussion is mainly on the structural and
thermodynamic properties, in relation to presently available
statistical mechanical models. Some dynamic properties are also
presented, at a more phenomenological level. The initial chapters
are devoted to the presentation of some basic concepts for bulk
properties: hydrodynamic interactions, electrostatics, van der
Waals forces and thermodynamics of ionic solutions in the framework
of a particular model: the mean spherical approximation (MSA).
Specific features of interfaces are then discussed: experimental
techniques such as in-situ X-ray diffraction, STM and AFM
microscopy are described. Ions at liquid/air, liquid/metal and
liquid/liquid interfaces are considered from the experimental and
theoretical viewpoint. Lastly some dynamic (transport) properties
are included, namely the self-diffusion and conductance of small
colloids (polyelectrolytes and micelles) and the kinetics of solute
transfer at free liquid/liquid interfaces.
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