This book discusses current techniques and instrumentation for cluster chemistry. It addresses both the experimental and theoretical aspects of gas-phase metal cluster reactivities, especially those pertaining to pollution removal, energetic reactions and corrosion and anticorrosion. These metal cluster systems have attracted enormous interest as they display a completely new class of physical, chemical, electronic, magnetic and catalytic properties. As these properties change with size and composition, it can thus be understood how their nature evolves from atoms to bulk solids. The book offers readers a basic understanding of the structural chemistry and reactivity of metal clusters in both gas-phase and wet chemistry. Further, the lessons they learn here regarding metal cluster chemistry will prepare researchers for the study of condensed phase dynamics that pertain to wet chemical synthesis, soft-landing deposition and cluster assembly.

Clusters and nanoscale materials give rise to properties and behaviour that are governed by size restrictions, and hence display features directly attributable to quantum confinement. Thus they represent ideal media for observing and studying quantum phenomena. This book presents and evaluates some of the latest developments in this area of basic research. Each of the chapters focuses on selected aspects of the field, and the authors endeavour to display the breadth of the subject by presenting some of the important recent advances that have been made through the use of new experimental techniques and theoretical approaches.

This book discusses current techniques and instrumentation for cluster chemistry. It addresses both the experimental and theoretical aspects of gas-phase metal cluster reactivities, especially those pertaining to pollution removal, energetic reactions and corrosion and anticorrosion. These metal cluster systems have attracted enormous interest as they display a completely new class of physical, chemical, electronic, magnetic and catalytic properties. As these properties change with size and composition, it can thus be understood how their nature evolves from atoms to bulk solids. The book offers readers a basic understanding of the structural chemistry and reactivity of metal clusters in both gas-phase and wet chemistry. Further, the lessons they learn here regarding metal cluster chemistry will prepare researchers for the study of condensed phase dynamics that pertain to wet chemical synthesis, soft-landing deposition and cluster assembly.

Clusters represent a new class of materials with totally new applications. This broad-ranging book presents and evaluates some of the latest developments in this area. The authors present some of the important recent advances made through the use of new experimental techniques and theoretical approaches.