This monograph develops a unified microscopic basis for phases and phase changes of bulk matter and small systems, based on classical physics. It describes the thermodynamics of ensembles of particles and explains phase transition in gaseous and liquid systems. The origins are derived from simple but physically relevant models of how transitions occur between rigid and fluid states, of how phase equilibria arise, and how they differ for small and large systems.

A vivid and revealing portrait of shipboard life as experienced by eighteenth-century migrants from Europe to the New World In October 1735, James Oglethorpe's Georgia Expedition set sail from London, bound for Georgia. Two hundred and twenty-seven passengers boarded two merchant ships accompanied by a British naval vessel and began a transformative voyage across the Atlantic that would last nearly five months. Chronicling their passage in journals, letters, and other accounts, the migrants described the challenges of physical confinement, the experiences of living closely with people from different regions, religions, and classes, and the multi-faceted character of the ocean itself. Using their specific journey as his narrative arc, Stephen Berry's A Path in the Mighty Waters tells the broader and heretofore underexplored story of how people experienced their crossings to the New World in the eighteenth century. During this time, hundreds of thousands of Europeans-mainly Irish and German-crossed the Atlantic as part of their martial, mercantile, political, or religious calling. Histories of these migrations, however, have often erased the ocean itself, giving priority to activities performed on solid ground. Reframing these histories, Berry shows how the ocean was more than a backdrop for human events; it actively shaped historical experiences by furnishing a dissociative break from normal patterns of life and a formative stage in travelers' processes of collective identification. Shipboard life, serving as a profound conversion experience for travelers both spiritually and culturally, resembled the conditions of a frontier or border zone where the chaos of pure possibility encountered an inner need for stability and continuity, producing permutations on existing beliefs. Drawing on an impressive array of archival collections, Berry's vivid and rich account reveals the crucial role the Atlantic played in history and how it has lingered in American memory as a defining experience.

This book deals with the formulation of the thermodynamics of chemical and other systems far from equilibrium. It contains applications to non-equilibrium stationary states and approaches to such states, systems with multiple stationary states, stability and equi-stability conditions, reaction diffusion systems, transport properties, and electrochemical systems. The theoretical treatment is complemented by experimental results to substantiate the formulation.

This book deals with the formulation of the thermodynamics of chemical and other systems far from equilibrium. It contains applications to non-equilibrium stationary states and approaches to such states, systems with multiple stationary states, stability and equi-stability conditions, reaction diffusion systems, transport properties, and electrochemical systems. The theoretical treatment is complemented by experimental results to substantiate the formulation.

This monograph develops a unified microscopic basis for phases and phase changes of bulk matter and small systems, based on classical physics. It describes the thermodynamics of ensembles of particles and explains phase transition in gaseous and liquid systems. The origins are derived from simple but physically relevant models of how transitions occur between rigid and fluid states, of how phase equilibria arise, and how they differ for small and large systems.