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By delivering concentrated information in three different volumes,
the editors of the Practical Aspects of Ion Trap Mass Spectrometry
mini-series present in-depth reviews on mainstream developments in
each active and popular area. Contributing authors provide concise
reports illustrating successful approaches to difficult analytical
problems across the basic scientific disciplines.
Ion Trap Instrumentation, the second volume in the series, conveys
an appreciation of the ion trap as a versatile instrument which is
used successfully in research and in applications, often in tandem
with other instruments or components, such as external ion sources
and lasers.
The book begins with a discussion of high resolution mass
spectrometry and mass measurement accuracy. It then demonstrates
that trajectories of high kinetic energy ions can be controlled so
that such ions are confined. It provides applications of lasers to
the study of trapped ions the laser photodissociation of gaseous
ions confined within the ion trap. The book concludes with physics
applications of the ion trap, in particular, the Penning trap and
the Paul trap.
Fundamentals of Ion Trap Mass Spectrometry presents an account of
the development and theory of the quadrupole ion trap and its
utilization as an ion storage device, a reactor for ion/molecular
reactions, and a mass spectrometer. It also expands the
appreciation of ion traps from that of a unique arrangement of
electrodes of hyperbolic form (and having a pure quadrupole field)
to a series of ion traps having fields with hexapole and octopole
components and introduces the practical ion trapping device in
which electrode spacing has been increased.
The fundamentals of ion trap are covered in four chapters,
beginning with the origin of the ion trap, its development and
operating principles, and improvements in performance. The second
part focuses on the environment within the ion trap -- the movement
of ions within the trap -- and how this movement is modified by
repeated collisions of the ions with buffer gas atoms of helium,
and on the collisions of ions with molecules that lead to chemical
change. The critical role of collisions in focusing the ion cloud
for subsequent operations is emphasized.
This important reference presents a coherent picture of the present
status of research in the ion trapping field to facilitate the
entree of potential ion trappers and provide a backdrop for ion
trap research and development in the future.
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