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This book covers whole aspects of the sulfur isologues of amides.
Starting from the synthetic methods of thioamides, a range of
synthetic applications to the construction of carbon-sulfur and
carbon-carbon bonds, to asymmetric reactions, to formation of
heterocycles are described. Among the array of thiocarbonyl
compounds, thioamides are readily handled in room temperature air.
Some of their characteristic features are that the polarity of C=S
bonds in thioamides is much smaller than C=O bonds in ordinary
amides, that thioamides possess higher HOMO and lower LUMO when
compared with those of ordinary amides, and that carbon atoms alpha
to the C=S and nitrogen atoms in thioamides are more acidic than
those in ordinary amides. Theoretical studies further disclose
their features. Thioamides are also used as ligands to a wide
variety of metals. Their unique photophysical properties and
catalytic activities are described here. Characteristic features of
biologically relevant thioamides, e.g., thiopeptides and related
compounds, are the final focus of the book.
This book covers whole aspects of the sulfur isologues of amides.
Starting from the synthetic methods of thioamides, a range of
synthetic applications to the construction of carbon-sulfur and
carbon-carbon bonds, to asymmetric reactions, to formation of
heterocycles are described. Among the array of thiocarbonyl
compounds, thioamides are readily handled in room temperature air.
Some of their characteristic features are that the polarity of C=S
bonds in thioamides is much smaller than C=O bonds in ordinary
amides, that thioamides possess higher HOMO and lower LUMO when
compared with those of ordinary amides, and that carbon atoms alpha
to the C=S and nitrogen atoms in thioamides are more acidic than
those in ordinary amides. Theoretical studies further disclose
their features. Thioamides are also used as ligands to a wide
variety of metals. Their unique photophysical properties and
catalytic activities are described here. Characteristic features of
biologically relevant thioamides, e.g., thiopeptides and related
compounds, are the final focus of the book.
The Science of Synthesis Editorial Board, together with the volume
editors and authors, is constantly reviewing the whole field of
synthetic organic chemistry as presented in Science of Synthesis
and evaluating significant developments in synthetic methodology.
Several annual volumes updating content across all categories
ensure that you always have access to state-of-the-art synthetic
methodology.
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