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This book underscores the essential principles of photocatalysis
and provides an update on its scientific foundations, research
advances, and current opinions, and interpretations. It consists of
an introduction to the concepts that form the backbone of
photocatalysis, from the principles of solid-state chemistry and
physics to the role of reactive oxidizing species. Having
recognised the organic link with chemical kinetics, part of the
book describes kinetic concepts as they apply to photocatalysis.
The dependence of rate on the reaction conditions and parameters is
detailed, the retrospective and prospective aspects of the
mechanism of photocatalysis are highlighted, and the adsorption
models, photocatalytic rate expressions, and kinetic disguises are
examined. This book also discusses the structure, property, and
activity relationship of prototypical semiconductor photocatalysts
and reviews how to extend their spectral absorption to the visible
region to enable the effective use of visible solar spectrum.
Lastly, it presents strategies for deriving substantially improved
photoactivity from semiconductor materials to support the latest
applications and potential trends.
This book underscores the essential principles of photocatalysis
and provides an update on its scientific foundations, research
advances, and current opinions, and interpretations. It consists of
an introduction to the concepts that form the backbone of
photocatalysis, from the principles of solid-state chemistry and
physics to the role of reactive oxidizing species. Having
recognised the organic link with chemical kinetics, part of the
book describes kinetic concepts as they apply to photocatalysis.
The dependence of rate on the reaction conditions and parameters is
detailed, the retrospective and prospective aspects of the
mechanism of photocatalysis are highlighted, and the adsorption
models, photocatalytic rate expressions, and kinetic disguises are
examined. This book also discusses the structure, property, and
activity relationship of prototypical semiconductor photocatalysts
and reviews how to extend their spectral absorption to the
visible region to enable the effective use of visible solar
spectrum. Lastly, it presents strategies for deriving substantially
improved photoactivity from semiconductor materials to support the
latest applications and potential trends.
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