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Showing 1 - 15 of 15 matches in All Departments
Featuring contributions from leading experts, Organic Photochemistry and Photophysics is a unique resource that addresses the organic photochemistry and photophysical behavior in aromatic molecules, thiocarbonyls, selected porphyrins, and metalloporphyrins. The book presents theories pertaining to radiative and radiationless transitions. It describes excited-state proton-transfer reactions of aromatic compounds and the physical, energetic, and environmental effects of atom transfer reactions. The text discusses the role of the carbonyl and azo groups in ketones and azoalkanes in the development of photochemistry, followed by a review of nucleophilic substitution reactions in the photochemistry of aromatics (also called photosubstitution) and the various atomic bonds that result from these reactions. The book presents studies that explain the factors that govern the nature and efficiencies of SET-promoted photochemical reactions. It then focuses on photoamination as a convenient, powerful, and environmentally friendly synthetic process for transforming a variety of substrates into the corresponding aminated compounds. The final chapter explores how dye structure affects the sequence-dependence of DNA binding, which has potential applications in nonlinear optics and DNA detection as well as incorporating DNA into various nanostructures and devices. With an emphasis on the current uses of light in both materials chemistry and medicinal chemistry, this book serves as a comprehensive resource on photochemical reactions and discusses topics that are useful for researchers as well as newcomers in the fields of photochemistry, photobiology, photomedicine, and photophysics
Features surveys of all areas of organic, inorganic, physical and biological photochemistry. The text serves as a source of scientific findings pertinent to chemistry and biochemistry. It addresses the state of developments in the field, employing reviews of active research, including recent innovations, techniques and applications.
This text discusses di-p-methane rearrangements via radical-cation intermediates, the photo-Fries rearrangement in organized media and of biologically active compounds, electron transfer leading to fragmentation, dimerization, and nucleophilic capture, and the characterization and reactivity of photochemically generated phenylene bis(diradical) species. The authors reveal experimental and computational techniques for the study of phenylene-linked carbenes and nitrenes. Brimming with over 900 references, Photochemistry of Organic Molecules in Isotropic and Anisotropic Media is crucial for professionals and students in photochemistry; chemical engineering; materials and semiconductor science; and organic, inorganic, and physical chemistry.
Answering the need for information that could revolutionize the development of alternate solar energy sources and the reduction of atmospheric contaminants, Semiconductor Photochemistry and Photophysics reflects renewed interest inspired by the unique properties of nanocrystalline semiconductor particles. It provides a thorough overview and describes fundamental research aimed at understanding the underlying mechanisms of the cells and looks at the application of nanocrystalline TiO2 as a photocatalyst for environmental remediation. Key topics include semiconductor photoelectrochemistry, dye-sensitized solar cells, and photocatalytic treatment of chemical waste.
This text discusses di-p-methane rearrangements via radical-cation intermediates, the photo-Fries rearrangement in organized media and of biologically active compounds, electron transfer leading to fragmentation, dimerization, and nucleophilic capture, and the characterization and reactivity of photochemically generated phenylene bis(diradical) species. The authors reveal experimental and computational techniques for the study of phenylene-linked carbenes and nitrenes. Brimming with over 900 references, Photochemistry of Organic Molecules in Isotropic and Anisotropic Media is crucial for professionals and students in photochemistry; chemical engineering; materials and semiconductor science; and organic, inorganic, and physical chemistry.
This text examines organic, physical and materials photochemistry. It reports the first example of a TiO2 sensitization with a fullerene-based donor-acceptor dyad, and covers halophenols, diflusinal photochemistry, hydroxystyrenes, acetylenes, and other related compounds. The volume also investigates whether c, d-alkenes influence the efficiency and course of light-induced reactions, and more
Focuses on complex naturally occurring and synthetic supramolecular arrays. The text describes applications of photochemistry in cystalline organic matrices; covers two-component crystals - crystalline molecular compounds, mixed crystals and simple mechanical mixtures - in solid and liquid phases; assesses photoinduced fragmentation of carbon-heteroatom bonds; and more.
This is the most updated, comprehensive collection of monographs on all aspects of photochemistry and photophysics related to natural and synthetic, inorganic, organic, and biological supramolecular systems. "Supramolecular Photochemistry: Controlling Photochemical Processes" addresses reactions in crystals, organized assemblies, monolayers, zeolites, clays, silica, micelles, polymers, dendrimers, organic hosts, supramolecular structures, organic glass, proteins and DNA, and applications of photosystems in confined media. This landmark publication describes the past, present, and future of this growing interdisciplinary area.
This text examines organic, physical and materials photochemistry. It reports the first example of a TiO2 sensitization with a fullerene-based donor-acceptor dyad, and covers halophenols, diflusinal photochemistry, hydroxystyrenes, acetylenes, and other related compounds. The volume also investigates whether c,d-alkenes influence the efficiency and course of light-induced reactions, and more.
A consideration of the development of photochemical systems with functions as optical sensors or switches, discussing materials and chemical systems, technology, and applications for target molecules and optical signal multiplexing. It contains novel applications in electrogenerated chemiluminescence and supramolecular photophysics for sensing chemical and biological analytes.
Control of molecular chirality is central to contemporary chemistry, biology, and materials-related areas. Chiral photochemistry employs molecular and supramolecular chiral interactions in the electronically excited state to induce molecular chirality, providing new and versatile strategies and surprising results unattainable by conventional thermal asymmetric synthesis. Chiral Photochemistry is the first book devoted solely to this rapidly growing area. This comprehensive and authoritative book covers all aspects of the subject, from circularly polarized light to supramolecular chiral source and from the origin of homochirality in the biosphere to chiral devices and materials.
Principles of Molecular Photochemistry: An Introduction develops photochemical and photophysical concepts from a small set of familiar principles. Developed from Nick Turro's best-selling text for three decades - Modern Molecular Photochemistry - this updated primer introduces an initial paradigm that relates the photon and a reactant molecular structure to photochemistry through the structure and dynamics of electronically excited states, reactive intermediates and products. The same paradigm is readily adapted to incorporate the photon and a reactant molecular structure to photophysics. The book provides brilliantly clear descriptions in pictorial terms that can be readily understood by the student and applied to systems of interest. This text will be of interest to not only practicing photochemists and their students, but also to biological scientists, polymer scientists, material scientists and nanoscientists who use photochemistry and photophysics in their research and teaching.
Modern Molecular Photochemistry of Organic Molecules is a comprehensive revision of Turro's classic text, Modern Molecular Photochemistry, which has been the standard of the field for three decades. For a crystal-clear introduction to organic photochemistry in pictorial terms, this book comprises all of the same introductory chapters that make up Principles of Molecular Photochemistry, but then goes on to provide additional chapters that cover the methods for determining the mechanisms of organic photoreactions, and describe comprehensively the photochemistry of the basic functional groups of organic chemistry. The text also includes special topic chapters on supramolecule organic photochemistry, the first of its kind, and the role of triplet and singlet molecular oxygen in organic photochemistry.This text will be of interest to not only practicing photochemists and their students, but also to biological scientists, polymer scientists, material scientists and nanoscientists who use photochemistry and photophysics in their research and teaching. For adopting professors, an art CD of figures from the book is also available.
A description of applications to electrical conductors, nonlinear optical devices, polymer light-omitting diodes (LEDs), electronic devices, batteries, antistatic coatings, and transistors. It reviews cases of metal-organic polymers incorporated with traditional organic polymers; assesses key properties of conjugated polymers; discusses features of d10 complexes and their interactions with DNA; and more.
Answering the need for information that could revolutionize the development of alternate solar energy sources and the reduction of atmospheric contaminants, Semiconductor Photochemistry and Photophysics reflects renewed interest inspired by the unique properties of nanocrystalline semiconductor particles. It provides a thorough overview and describes fundamental research aimed at understanding the underlying mechanisms of the cells and looks at the application of nanocrystalline TiO2 as a photocatalyst for environmental remediation. Key topics include semiconductor photoelectrochemistry, dye-sensitized solar cells, and photocatalytic treatment of chemical waste.
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