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This book has its origins in courses taught by the author to various und- graduate and graduate students at the Indian Institute of Technology, K- pur, India. The diversity of inorganic chemistry and its impact on polymer chemistry has been profound. This subject matter has grown considerably in the last decade and the need to present it in a coherent manner to young minds is a pedagogic challenge. The aim of this book is to present to the students an introduction to the developments in Inorganic and - ganometallic polymers. This book is divided into eight chapters. Chapter 1 provides a general overview on the challenges of Inorganic polymer synthesis. This is f- lowed by a survey of organic polymers and also includes some basic f- tures of polymers. Chapters 3-8 deal with prominent families of inorganic and organometallic polymers. Although the target group of this book is the undergraduate and graduate students of chemistry, chemical engineering and materials science it is also hoped that chemists and related scientists in industry would find this book useful. I am extremely thankful to my wife Sudha who not only encouraged me throughout but also drew all the Figures and Schemes of this book. I also thank my children Adithya and Aarathi for their constant concern on the progress of this book. I express my acknowledgment to the editorial team of Springer-Verlag for their cooperation.
This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.
This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.
This book has its origins in courses taught by the author to various und- graduate and graduate students at the Indian Institute of Technology, K- pur, India. The diversity of inorganic chemistry and its impact on polymer chemistry has been profound. This subject matter has grown considerably in the last decade and the need to present it in a coherent manner to young minds is a pedagogic challenge. The aim of this book is to present to the students an introduction to the developments in Inorganic and - ganometallic polymers. This book is divided into eight chapters. Chapter 1 provides a general overview on the challenges of Inorganic polymer synthesis. This is f- lowed by a survey of organic polymers and also includes some basic f- tures of polymers. Chapters 3-8 deal with prominent families of inorganic and organometallic polymers. Although the target group of this book is the undergraduate and graduate students of chemistry, chemical engineering and materials science it is also hoped that chemists and related scientists in industry would find this book useful. I am extremely thankful to my wife Sudha who not only encouraged me throughout but also drew all the Figures and Schemes of this book. I also thank my children Adithya and Aarathi for their constant concern on the progress of this book. I express my acknowledgment to the editorial team of Springer-Verlag for their cooperation.
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