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This volume C 1 is the first supplement volume to "Phosphor" C
which was published in 1965 and covers the compounds of phosphorus.
Starting with the binary species formed between phosphorus and
hydrogen, the present volume deals with the neutral mononuclear
compounds PH through PH; the ions featuring the same stoichiometric
composition are s covered in separate sections. PH and PH are the
major initial gaseous decomposition products of PH and, thus, also
2 J intermediates in many of its gas-phase reactions. Both
molecules and their ions have been thoroughly investigated by a
variety of modern, high-resolution spectroscopic methods during the
last three decades. The coverage of their physical, and mostly
molecular, properties re presents the largest part of the first two
chapters (PH and ions pp. 2 to 47; PH and ions pp. 47 2 to 111). PH
is the only compound described in this volume which is thermally
stable under normal J conditions. It is the phosphorus analog of
ammonia, but exhibits, however, a quite different chemical behavior
towards most elements and compounds. The majority of its physical,
and in particular spectroscopic, properties have been determined in
great detail since the sixties, partially in regard to
spectroscopic investigations of the atmospheres of the outer
planets."
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