Die 2. uberarbeitete und erweiterte Auflage der Hydrogeologischen Methoden basiert auf einer grundlichen Uberarbeitung. Dies betrifft insbesondere die Darstellung von Durchlassigkeit und Transmissivitat, Speicherkoeffizient und Porenraum sowie die Pumpversuche. Das von vielen Benutzern geschatzte Kapitel uber statistische Verfahren in der Hydrogeologie wurde nicht ubernommen. Dafur liegen im Schrifttum seit 1980 moderne, auf die elektronische Datenverarbeitung abgestimmte Bucher vor. Neue Darstellungen gibt es auch fur solche hydrogeologische Methoden, die manche Fachkollegen und Praktiker vermissen werden. Neu hinzu gekommen sind Kapitel uber die "Hydrogeochemie fur die Praxis," den Transport von Wasserinhaltsstoffen, Kontamination des Grundwassers und Sanierung von Grundwasserleitern, Grundwassermonitoring, Brunnenalterung und Regenerierung sowie Grundwasserwiedererganzung und -bilanz. Hydrogeologische Systemzusammenhange werden schlussig dargestellt und durch sehr viele anschauliche Abbildungen illustriert. Dies trifft auch auf die Definition und Ableitung der wichtigsten hydrogeologischen Kennwerte zu. In den Text eingefugte Beispiele erlauben es dem Benutzer, Losungsweg und Berechnung nachzuvollziehen."

An isotope is a variant form of a chemical element, containing a different number of neutrons in its nucleus. Most elements exist as several isotopes. Many are stable while others are radioactive, and some may only exist fleetingly before decaying into other elements. In this Very Short Introduction, Rob Ellam explains how isotopes have proved enormously important across all the sciences and in archaeology. Radioactive isotopes may be familiar from their use in nuclear weapons, nuclear power, and in medicine, as well as in carbon dating. They have been central to establishing the age of the Earth and the origins of the solar system. Combining previous and new research, Ellam provides an overview of the nature of stable and radioactive isotopes, and considers their wide range of modern applications. ABOUT THE SERIES: The Very Short Introductions series from Oxford University Press contains hundreds of titles in almost every subject area. These pocket-sized books are the perfect way to get ahead in a new subject quickly. Our expert authors combine facts, analysis, perspective, new ideas, and enthusiasm to make interesting and challenging topics highly readable.

Uniting the conceptual foundations of the physical sciences and biology, this groundbreaking multidisciplinary book explores the origin of life as a planetary process. Combining geology, geochemistry, biochemistry, microbiology, evolution and statistical physics to create an inclusive picture of the living state, the authors develop the argument that the emergence of life was a necessary cascade of non-equilibrium phase transitions that opened new channels for chemical energy flow on Earth. This full colour and logically structured book introduces the main areas of significance and provides a well-ordered and accessible introduction to multiple literatures outside the confines of disciplinary specializations, as well as including an extensive bibliography to provide context and further reading. For researchers, professionals entering the field or specialists looking for a coherent overview, this text brings together diverse perspectives to form a unified picture of the origin of life and the ongoing organization of the biosphere.

Fluid-aided mass transfer and subsequent mineral re-equilibration are the two defining features of metasomatism and must be present in order for metamorphism to occur. Coupled with igneous and tectonic processes, metasomatism has played a major role in the formation of the Earth's continental and oceanic crust and lithospheric mantle as well as in their evolution and subsequent stabilization. Metasomatic processes can include ore mineralization, metasomatically induced alteration of oceanic lithosphere, mass transport in and alteration of subducted oceanic crust and overlying mantle wedge, which has subsequent implications regarding mass transport, fluid flow, and volatile storage in the lithospheric mantle overall, as well as both regional and localized crustal metamorphism. Metasomatic alteration of accessory minerals such as zircon or monazite can allow for the dating of metasomatic events as well as give additional information regarding the chemistry of the fluids responsible. Lastly present day movement of fluids in both the lithospheric mantle and deep to mid crust can be observed utilizing geophysical resources such as electrical resistivity and seismic data. Such observations help to further clarify the picture of actual metasomatic processes as inferred from basic petrographic, mineralogical, and geochemical data. The goal of this volume is to bring together a diverse group of geologists, each of whose specialities and long range experience regarding one or more aspects of metasomatism during geologic processes, should allow them to contribute to a series of review chapters, which outline the basis of our current understanding of how metasomatism influences and helps to control both the evolution and stability of the crust and lithospheric mantle.

Weathering involves important processes that alter the original structure, texture and chemical components of a granitic rock. The changes in mineralogical and chemicals properties of the rocks as a result of weathering can be studied by means of a number of chemical and petrographic techniques. This paper evaluates some chemical indexes as indicators of the weathering state of granites used in ashlars and to establish the correlation between these indices and the index physical properties of the rocks such as rock density and porosity. Additionally, numerical modeling of mineral deposition from hydrothermal solutions and fluid-rock interaction is used to outline the main regularities of the formation of hydrothermal veins and related metasomatic alteration of wall rocks. This book examines the conditions of fluid flow evolution and geological environment during hydrothermal system activity derived from the data on mineral assemblages in the veins and altered rocks. Furthermore, this book focuses on the tectonic and geological settings, analytical methods, petrographical characteristics, geochemical features, mineralogy and mineral chemistry of the volcanic rocks in the Central Anatolia. Other chapters explain the hydraulic evolution of Tinos, Panormos Bay ore fluid associated with Au-Ag-Te mineralisation and the biological and ecological aspects of the littoral system, composed by bedrock, boulders and cobbles. Furthermore, two types of degradation processes that are affecting some pictographs have been discovered and are described in this book. The information obtained is fundamental to undertake appropriately the conservation of these fragile works of art.

Quantifying the timescales of current geological processes is critical for constraining the physical mechanisms operating on the Earth today. Since the Earth's origin 4.55 billion years ago magmatic processes have continued to shape the Earth, producing the major reservoirs that exist today (core, mantle, crust, oceans and atmosphere) and promoting their continued evolution. But key questions remain. When did the core form and how quickly? How are magmas produced in the mantle, and how rapidly do they travel towards the surface? How long do magmas reside in the crust, differentiating and interacting with the host rocks to yield the diverse set of igneous rocks we see today? How fast are volcanic gases such as carbon dioxide released into the atmosphere?

This book addresses these and other questions by reviewing the latest advances in a wide range of Earth Science disciplines: from the measurement of short-lived radionuclides to the study of element diffusion in crystals and numerical modelling of magma behaviour. It will be invaluable reading for advanced undergraduate and graduate students, as well as igneous petrologists, mineralogists and geochemists involved in the study of igneous rocks and processes.

Building upon the award-winning second edition, this comprehensive textbook provides a fundamental understanding of the formative processes of igneous and metamorphic rocks. Encouraging a deeper comprehension of the subject by explaining the petrologic principles, and assuming knowledge of only introductory college-level courses in physics, chemistry, and calculus, it lucidly outlines mathematical derivations fully and at an elementary level, making this the ideal resource for intermediate and advanced courses in igneous and metamorphic petrology. With over 500 illustrations, many in color, this revised edition contains valuable new material and strengthened pedagogy, including boxed mathematical derivations allowing for a more accessible explanation of concepts, and more qualitative end-of-chapter questions to encourage discussion. With a new introductory chapter outlining the "bigger picture," this fully updated resource will guide students to an even greater mastery of petrology.

This book provides thorough knowledge and detailed information of oil shales using a range of conventional and unconventional techniques and methodologies combined to elucidate the composition of oil shale deposits. As these rocks are mined for energy production their composition and mineral constituents are of special interests to individuals and communities that are likely to be effected by these resources when mined and processed. The book highlights the environmental and health hazards of the spent shales after processing. These are significantly greater in volume than the rocks originally mined before processing. Toxic metals tend to double and triple their concentrations in the spent shales and will be leached into water sources and soils.Since oil shales as an energy resource are totally uneconomical; all oil shales, their mining and processing are heavily subsidised by governments and institutions using taxpayers money.

Fully updated and expanded, this new edition provides students with an accessible introduction to marine chemistry. It highlights geochemical interactions between the ocean, solid earth, atmosphere and climate, enabling students to appreciate the interconnectedness of Earth's processes and systems and elucidates the huge variations in the oceans' chemical environment, from surface waters to deep water. Written in a clear, engaging way, the book provides students in oceanography, marine chemistry and biogeochemistry with the fundamental tools they need for a strong understanding of ocean chemistry. Appendices present information on seawater properties, key equations and constants for calculating oceanographic processes. New to this edition are end-of-chapter problems for students to put theory into practice, summaries to allow easy review of material and a comprehensive glossary. Supporting online resources include solutions to problems and figures from the book.

Chemical processes shape the world we live in; the air we breathe, the water we drink, the weather we experience. Environmental Chemistry: a global perspective describes those chemical principles which underpin the natural processes occurring within and between the air, water, and soil, and explores how human activities impact on these processes, giving rise to environmental issues of global concern. Guiding us through the chemical composition of the three key environmental systems - the atmosphere, hydrosphere, and terrestrial environment - the authors explain the chemical processes which occur within and between each system. Focusing on general principles, we are introduced to the essential chemical concepts which allow better understanding of air, water, and soil and how they behave; careful explanations ensure that clarity is not sacrificed at the expense of thorough coverage of the underlying chemistry. We then see how human activity continues to affect the chemical behaviour of these environmental systems, and what the consequences of these natural processes being disturbed can be. Environmental Chemistry: a global perspective takes chemistry out of the laboratory, and shows us its importance in the world around us. With illuminating examples from around the globe, its rich pedagogy, and broad, carefully structured coverage, this book is the perfect resource for any environmental chemistry student wishing to develop a thorough understanding of their subject.

The second edition of The Biomarker Guide is a fully updated and expanded version of this essential reference. Now in two volumes, it provides a comprehensive account of the role that biomarker technology plays both in petroleum exploration and in understanding Earth history and processes. Biomarkers and Isotopes in Petroleum Exploration and Earth History itemizes parameters used to genetically correlate petroleum and interpret thermal maturity and extent of biodegradation. It documents most known petroleum systems by geologic age throughout Earth history. The Biomarker Guide is an invaluable resource for geologists, petroleum geochemists, biogeochemists, and environmental scientists.

Freshwater Ecosystems and Climate Change in North America brings together a group of experts from the fields of geochemistry, climatology, hydrology and aquatic ecology to address the central question, ‘What would be the impact to and response of freshwater ecosystems in your region as a result of a hypothetical doubling of CO₂ in the atmosphere?’ These regional papers and syntheses will provide a solid foundation upon which scientists can proceed and build in their efforts to provide other scientists, regulators, and decision-makers with meaningful information concerning the important phenomena associated with climate change.

Studies of Sr isotopic composition of thousands of samples of marine sediments and fossils have yielded a curve of 87Sr/86Sr versus age for seawater Sr that extends back to 1 billion years. The ratio has fluctuated with large amplitude during this time period, and because the ratio is always uniform in the oceans globally at any one time, it is useful as a stratigraphic correlation and age-dating tool. The ratio also appears to reflect major tectonic and climatic events in Earth history and hence provides clues as to the causes, timing, and consequences of those events. The seawater 87Sr/86Sr ratio is generally high during periods marked by continent-continent collisions, and lower when continental topography is subdued, and seafloor generation rates are high. There is evidence that major shifts in the seawater ratio can be ascribed to specific orogenic events and correlate with large shifts in global climate.

Over million-year timescales, the geologic cycling of carbon controls long-term climate and the oxidation of Earth's surface. Inferences about the carbon cycle can be made from time series of carbon isotopic ratios measured from sedimentary rocks. The foundational assumption for carbon isotope chemostratigraphy is that carbon isotope values reflect dissolved inorganic carbon in a well-mixed ocean in equilibrium with the atmosphere. However, when applied to shallow-water platform environments, where most ancient carbonates preserved in the geological record formed, recent research has documented the importance of considering both local variability in surface water chemistry and diagenesis. These findings demonstrate that carbon isotope chemostratigraphy of platform carbonate rarely represent the average carbonate sink or directly records changes in the composition of global seawater. Understanding what causes local variability in shallow-water settings, and what this variability might reveal about global boundary conditions, are vital questions for the next generation of carbon isotope chemostratigraphers.

Energy and water have been fundamental to powering the global economy and building modern society. This cross-disciplinary book provides an integrated assessment of the different scientific and policy tools around the energy-water nexus. It focuses on how water use, and wastewater and waste solids produced from fossil fuel energy production affect water quality and quantity. Summarizing cutting edge research, it describes the scientific methods for detecting contamination sources in the context of policy and regulations. The authors highlight the growing evidence that fossil fuel production, from both conventional and unconventional sources, leads to water quality degradation, while regulations for the water and energy sector remain fractured and highly variable across and within countries. This volume will be a key reference for scholars, industry professionals, environmental consultants and policy makers seeking information on the risks associated with the energy cycle and its impact on the environment, particularly water resources.

Ancient iron formations - iron and silica-rich chemical sedimentary rocks that formed throughout the Precambrian eons - provide a significant part of the evidence for the modern scientific understanding of palaeoenvironmental conditions in Archaean (4.0-2.5 billion years ago) and Proterozoic (2.5-0.539 billion years ago) times. Despite controversies regarding their formation mechanisms, iron formations are a testament to the influence of the Precambrian biosphere on early ocean chemistry. As many iron formations are pure chemical sediments that reflect the composition of the waters from which they precipitated, they can also serve as nuanced geochemical archives for the study of ancient marine temperatures, redox states, and elemental cycling, if proper care is taken to understand their sedimentological context.

Molybdenum (Mo) is a widely used trace metal for investigating redox conditions. However, unanswered questions remain that concentration and bulk isotopic analysis cannot specially answer. Improvements can be made by combining new geochemical techniques to traditional methods of Mo analysis. In this Element, we propose a refinement of Mo geochemistry within aquatic systems, ancient rocks, and modern sediments through molecular geochemistry (systematically combining concentration, isotope ratio, elemental mapping, and speciation analyses). Specifically, to intermediate sulfide concentrations governing Mo behavior below the 'switch-point' and dominant sequestration pathways in low oxygen conditions. The aim of this work is to 1) aid and improve the breadth of Mo paleoproxy interpretations by considering Mo speciation and 2) address outstanding research gaps concerning Mo systematics (cycling, partitioning, sequestration, etc.). The Mo paleoproxy has potential to solve ever complex research questions. By using molecular geochemical recommendations, improved Mo paleoproxy interpretations and reconstruction can be achieved.

Natural radiation arises from many sources, from the unstable atoms within our own bodies and in the materials around us, from the Sun, and even from beyond the Solar System. Additional sources include the legacy of testing nuclear weapons, nuclear waste, and nuclear accidents. All these sources have provided means of dating environmental materials and tracing the movements of substances through land, sea, and air. But ionising radiation also interacts with DNA, which has led to a remarkable range of studies to examine how and how quickly these unstable atoms are accumulated by both humans and biota, and their various effects on both. Providing an overview of the sources, uses and impacts of ionising radiation in the environment, and the frameworks developed to manage exposures to them, this is a valuable reference for graduate students and researchers interested in radioecology, environmental science and radiological protection.

In the modern marine environment, barium isotope ( 138Ba) variations are primarily driven by barite cycling-barite incorporates 'light' Ba isotopes from solution, rendering the residual Ba reservoir enriched in 'heavy' Ba isotopes by a complementary amount. Since the processes of barite precipitation and dissolution are vertically segregated and spatially heterogeneous, barite cycling drives systematic variations in the barium isotope composition of seawater and sediments. This Element examines these variations; evaluates their global, regional, local, and geological controls; and, explores how 138Ba can be exploited to constrain the origin of enigmatic sedimentary sulfates and to study marine biogeochemistry over Earth's history.

Diverse and abundant lipid biomarker assemblages have been reported from a variety of Proterozoic marine environments from the careful analysis of well-preserved rocks and oils. These molecular biosignatures have provided unique insights into the communities and the environmental conditions which characterized the Proterozoic marine biosphere. We summarize some of the major temporal patterns evident in Proterozoic lipid biomarkers found to date, whilst emphasizing the scale of local heterogeneity found within Neoproterozoic oceans from region to region, and their relationship with the evolving ecological, climatic and ocean/atmospheric redox conditions. Short commentaries on a selection of papers published from the last 15 years of biomarker literature are given. The focus here is on key studies, highlighted for further reading, which have helped to better constrain the timing of the ecological expansion of eukaryotes in Proterozoic oceans or which have impacted on our knowledge of the biological sources of Proterozoic biomarkers.

In one form or another, iron speciation has had a long history as a paleoredox proxy. The technique has been refined considerably over the years, and the most recent scheme is unique in its potential to distinguish three major oceanic redox states - oxygenated, ferruginous and euxinic. This Element covers the theory behind the proxy, methods involved in applying the technique, and potential complications in interpreting Fe speciation data. A series of case studies are also provided, which highlight how more advanced consideration of the data, often in concert with other techniques, can provide unprecedented insight into the redox state of ancient oceans.

Paleosols formed in direct contact with the Earth's atmosphere, so they can record the composition of the atmosphere through weathering processes and products. Herein we critically review a variety of different approaches for reconstructing atmospheric O2 and CO2 over the past three billion years. Paleosols indicate relatively low CO2 over that time, requiring additional greenhouse forcing to overcome the 'faint young Sun' paradox in the Archean and Mesoproterozoic, as well as low O2 levels until the Neoproterozoic. Emerging techniques will revise the history of Earth's atmosphere further and may provide a window into atmospheric evolution on other planets.

The stable chromium (Cr) isotope system has emerged over the past decade as a new tool to track changes in the amount of oxygen in earth's ocean-atmosphere system. Much of the initial foundation for using Cr isotopes ( 53Cr) as a paleoredox proxy has required recent revision. However, the basic idea behind using Cr isotopes as redox tracers is straightforward-the largest isotope fractionations are redox-dependent and occur during partial reduction of Cr(VI). As such, Cr isotopic signatures can provide novel insights into Cr redox cycling in both marine and terrestrial settings. Critically, the Cr isotope system-unlike many other trace metal proxies-can respond to short-term redox perturbations (e.g., on timescales characteristic of Pleistocene glacial-interglacial cycles). The Cr isotope system can also be used to probe the earth's long-term atmospheric oxygenation, pointing towards low but likely dynamic oxygen levels for the majority of Earth's history.

Ce anomalies track changes in oxygen availability due to the anomalous redox-sensitivity of Ce compared with the other rare earth elements. The proxy systematics have been calibrated experimentally as well as in modern anoxic water bodies. Ce anomalies are unique because they track intermediate manganous conditions, rather than fully anoxic conditions. In addition, they are sensitive to local-regional redox conditions, and can be analysed in chemical sediments such as carbonate rocks. This makes them especially useful as a tool to track local oxygen distribution in shallow shelf environments, where biodiversity is highest. This review focusses on the systematics of the Ce anomaly proxy, the preservation and extraction of the signal in sedimentary rocks, and the potential applications of the proxy.