concentrates on teaching techniques using as much theory as needed. application of the techniques to many problems of materials characterization. Moessbauer spectroscopy is a profound analytical method which has nevertheless continued to develop. The authors now present a state-of-the art book which consists of two parts. The first part details the fundamentals of Moessbauer spectroscopy and is based on a book published in 1978 in the Springer series 'Inorganic Chemistry Concepts' by P. Gutlich, R. Link and A.X. Trautwein. The second part covers useful practical aspects of measurements, and the application of the techniques to many problems of materials characterization. The update includes the use of synchroton radiation and many instructive and illustrative examples in fields such as solid state chemistry, biology and physics, materials and the geosciences, as well as industrial applications. Special chapters on magnetic relaxation phenomena (S. Morup) and computation of hyperfine interaction parameters (F. Neese) are also included. The book concentrates on teaching the technique using theory as much as needed and as little as possible. The reader will learn the fundamentals of the technique and how to apply it to many problems of materials characterization. Transition metal chemistry, studied on the basis of the most widely used Moessbauer isotopes, will be in the foreground.

The twelve chapters of this volume aim to provide a complete manual for using noble gases in terrestrial geochemistry, covering applications which range from high temperature processes deep in the Earth's interior to tracing climatic variations using noble gases trapped in ice cores, groundwaters and modern sediments. Other chapters cover noble gases in crustal (aqueous, CO2 and hydrocarbon) fluids and laboratory techniques for determining noble gas solubilities and diffusivities under geologically relevant conditions. Each chapter deals with the fundamentals of the analysis and interpretation of the data, detailing sampling and sampling strategies, techniques for analysis, sources of error and their estimation, including data treatment and data interpretation using recent case studies.

Uranium is an element to be found ubiquitous in rock, soil, and water. Uranium concentrations in natural ground water can be more than several hundreds g/l without impact from mining, nuclear industry, and fertilizers. Considering the WHO recommendation for drinking water of 15 g/l (has been as low as 2 g/l before) due to the chemical toxicity of uranium the element uranium has become an important issue in environmental research. Besides natural enrichment of uranium in aquifers uranium mining and milling activities, further uranium processing to nuclear fuel, emissions form burning coal and oil, and the application of uranium containing phosphate fertilizers may enrich the natural uranium concentrations in soil and water by far. In October 1995 the first international conference on Uranium Mining and Hydrogeology (UMH I) was held in Freiberg being organized by the Department of Geology at the Technical University Bergakademie Freiberg by the support of the Saxon State Ministry of Geology and Environment. Due to the large scientific interest in the topic of uranium a second conference (UMH II) took place in Freiberg in September 1998. Furthermore, in September 2002 scientists working on the topic of uranium mining and hydrogeology attended the third conference (UMH III) which was jointly held together with the International Mine Water - sociation (IMWA) Symposium 2002. The reviewed papers and posters of the 2002 conference have been published by Springer entitled Uranium in the aquatic en- ronment (edited by Merkel, Planer-Friedrich and Wolkersdorfer).

Fluid-aided mass transfer and subsequent mineral re-equilibration are the two defining features of metasomatism and must be present in order for metamorphism to occur. Coupled with igneous and tectonic processes, metasomatism has played a major role in the formation of the Earth's continental and oceanic crust and lithospheric mantle as well as in their evolution and subsequent stabilization. Metasomatic processes can include ore mineralization, metasomatically induced alteration of oceanic lithosphere, mass transport in and alteration of subducted oceanic crust and overlying mantle wedge, which has subsequent implications regarding mass transport, fluid flow, and volatile storage in the lithospheric mantle overall, as well as both regional and localized crustal metamorphism. Metasomatic alteration of accessory minerals such as zircon or monazite can allow for the dating of metasomatic events as well as give additional information regarding the chemistry of the fluids responsible. Lastly present day movement of fluids in both the lithospheric mantle and deep to mid crust can be observed utilizing geophysical resources such as electrical resistivity and seismic data. Such observations help to further clarify the picture of actual metasomatic processes as inferred from basic petrographic, mineralogical, and geochemical data. The goal of this volume is to bring together a diverse group of geologists, each of whose specialities and long range experience regarding one or more aspects of metasomatism during geologic processes, should allow them to contribute to a series of review chapters, which outline the basis of our current understanding of how metasomatism influences and helps to control both the evolution and stability of the crust and lithospheric mantle.

There have been numerous computer-based simulation studies carried out on the subject of CO2 geo-sequestration. However, the amount of experimental data available in the literature on this topic, especially with regards to multiphase flow characteristics of fluid-rock systems during such processes, is very limited. This research was carried out with the aim of providing a better understanding of the multiphase fluid flow characteristics of fluid-rock systems during the geo-sequestration process. The ultimate goal of this research was to experimentally evaluate the change in a number of multiphase flow characteristics of the system over time caused by the potential chemical and physical/mechanical processes occurring during deep CO2 disposal. In order to achieve this goal the effects of cyclic/alternating CO2-brine flooding, flow direction, existence of residual hydrocarbon (natural gas) and change in the reservoir stress field on the system's multiphase flow behaviour were investigated. Until completion of this study there were no experimental data published in the literature addressing the above mentioned issues and the results obtained, and published within this thesis were the first of their kind.

This book will broaden readers' understanding of pegmatites in a special geodynamic setting, dealing with the emplacement of the Hagendorf-Pleystein Pegmatite Province (HPPP) in the Central European Variscides. This treatise illustrates the complex processes leading to the formation and partial destruction of the pegmatites, documenting the geochronological, chemical, mineralogical, geological and geomorphological / sedimentological data set. The book starts with a detailed account of the economic geology of the various pegmatites, explaining why these deposits are a major resource of ceramic raw materials. In its concluding section, a model of the pegmatite evolution in an ensialic orogen provides meaningful insights into the genetic aspects of pegmatite generation. The Late Paleozoic rare-element pegmatites of the HPPP, Oberpfalz-SE, Germany, rank among the largest concentrations in Europe. The biggest pegmatite of this mining district totals 4.4 million tons of ore (Hagendorf-South). The mining history of the HPPP is restricted to the 20th century, when local entrepreneurs started mining operations in search of ceramic raw materials, feldspar and quartz. Today the "Silbergrube Aplite" is still worked for feldspar. The traditional mining of pegmatitic and aplitic rocks in Central Europe, such as the Bohemian Massif, which is shared by Germany, the Czech Republic, Poland and Austria, has been focused on these industrial minerals. In addition to these major commodities, lithium was mined for a period of time. But even today many of these pegmatites of calc-alkaline affiliation have not lost their appeal to mineralogists and mineral enthusiasts for their wealth of minerals that contain P, Nb, Ta, Li, Be, B, U, Th, Sc, Ti and Sn. The most favorable crustal section to bring about pegmatitic rocks of this type, encompassing pegmatoids, metapegmatites, reactivated pseudopegmatites and pegmatites sensu stricto is the ensialic orogen, exemplified by the Variscan (Hercynian) Orogen, which geodynamically connects the Paleozoic pegmatite provinces in North America and Europe. The geological history of the HPPP, however, goes much further than the Carboniferous-Permian magmatic activity, when the last structural disturbances of the Variscan orogeny affected the NE-Bavarian Basement between 450 and 330 Ma. During this time mafic magmatic rocks together with calcareous and arenaceous sediments were converted into paragneisses, calcsilicate rocks, and amphibolites. It is the period of time when tectonic shortening led to over thrusting and when the emplacement of nappes and the architectural elements of the ensialic orogen began taking shape. During the Late Permian, the Mesozoic and the Cenozoic, the HPPP did not lie idle in geological terms; hypogene and supergene alteration continued and found its most recent expression in alluvial-fluvial "nigrine" placer deposits, which resulted from the unroofing of the pegmatites and aplites in the HPPP and can be used even outside HPPP as an ore guide to pegmatites.

This volume provides a comprehensive overview of advanced research in the field of efficient, clean and renewable energy production, conversion and storage. The ten chapters, written by internationally respected experts, address the following topics: (1) solar and wind energy; (2) energy storage in batteries; (3) biomass; and (4) socio-economic aspects of energy. Given its multidisciplinary approach, which combines environmental analysis and an engineering perspective, the book offers a valuable resource for all researchers and students interested in environmentally sustainable energy production, conversion, storage and its engineering.

This book provides an introductory understanding of fluvial geomorphic principles and how these principles can be integrated with geochemical data to cost-effectively characterize, assess and remediate contaminated rivers. The book stresses the importance of needing to understand both geomorphic and geochemical processes. Thus, the overall presentation is first an analysis of physical and chemical processes and, second, a discussion of how an understanding of these processes can be applied to specific aspects of site assessment and remediation. Such analyses provide the basis for a realistic prediction of the kinds of environmental responses that might be expected, for example, during future changes in climate or land-use.

This book provides a comprehensive description of groundwater resources in Ethiopia and its various dimensions (groundwater as resource, environmental functions, and socioeconomics). The prevailing knowledge of groundwater resources in Ethiopia (or elsewhere in Sub Saharan Africa) was based on geological and stratigraphic framework known nearly four decades ago (mainly 1960's and 70's). Thanks to the substantial geoscientific research since the 70's a new set of relevant geological/stratigrahpic data has been created that helps to re-define our understanding of groundwater resources in Africa as a whole and in Ethiopia in particular: a) For the first time the basement aquifer of Ethiopia has been described hydrogeologically based on genesis of regoliths (deep weathering and striping history); clear regional difference in groundwater potential is shown for the first time; comparative accounty has been given regarding groundwater occurrence in the generally low grade basement rocks of Ethiopia (Arabian Nubian shield) and high grade basement rocks of the rest of Africa. b) For the first time groundwater occurrence in multilayred sedimentary rocks account for spatial variation in degree of karstification; deformation history, and stratigraphy. c) The vast volcanic aquifers of Ethiopia which have previously classified based on their ages are now reclassified based on age, morphology (eg. groundwater in plateau volcanics, groundwater in shield volcanics) and aquifer structure. d) The loose alluvio lacustrine sediments which were known as least extensive in previous works based on areal cover are in fact shown to host the most voluminous groundwater resources in Ethiopia. These aquifers have now been described based on their geomorphology, extent, and genesis. The aim of this book is to use these newly created knowledge to redefine the understanding of groundwater resources in Ethiopia.

This textbook details basic principles of planetary science that help to unify the study of the solar system. It is organized in a hierarchical manner so that every chapter builds upon preceding ones. Starting with historical perspectives on space exploration and the development of the scientific method, the book leads the reader through the solar system. Coverage explains that the origin and subsequent evolution of planets and their satellites can be explained by applications of certain basic principles of physics, chemistry, and celestial mechanics and that surface features of the solid bodies can be interpreted by principles of geology.

Petrogenesis of Metamorphic Rocks presents a large number of diagrams showing the stability relations among minerals and groups of minerals found in metamorphic rocks. The diagrams help to determine the pressure and temperature conditions under which a given set of metamorphic rocks may have formed. Other parameters that control metamorphic mineral assemblages are also discussed and pitfalls resulting from simplifications and generalizations are highlighted. The book discusses the most common metamorphic rock types, their nomenclature, structure and graphical representation of their mineral assemblages. Part I defines basic principles of metamorphism, introduces metamorphic processes, geologic thermometry and barometry and defines metamorphic grade. Part II presents in a systematic way mineralogical changes and assemblages found in the most common types of metamorphic rocks. The computation of diagrams is based on recent advances in quantitative petrology and geochemistry. An extensive bibliography, including the key contributions and classic papers in the field, make it an invaluable source book for graduate students and professional geologists.

Chemical additives are used to enhance the properties of many industrial products. Since their release into the environment is a potential risk for man and nature, their fate and behavior have been investigated in the framework of the European Union-funded project RISKCYCLE. The results are presented in two volumes, Global Risk-Based Management of Chemical Additives I: Production, Usage and Environmental Occurrence and Global Risk-Based Management of Chemical Additives II: Risk-Based Assessment and Management Strategies. This book is the second of the two volumes and features two main parts. In the first part, experts in the field discuss different models related to the assessment of the potential risks posed by chemical additives and analyze their benefits and drawbacks. In the second part, specific case studies in which the models have been applied are presented and the reliability of the models is evaluated. This volume is an invaluable source of information for scientists and governmental agencies dealing with the risk assessment of chemicals on a global scale.

This book takes an in-depth look at the theory and methods inherent in the tracing of riverine sediments. Examined tracers include multi-elemental concentration data, fallout radionuclides (e.g., 210Pb, 137Cs, 7Be), radiogenic isotopes (particularly those of Pb, Sr, and Nd), and novel ("non-traditional") stable isotopes (e.g., Cd, Cu, Hg, and Zn), the latter of which owe their application to recent advances in analytical chemistry. The intended goal is not to replace more 'traditional' analyses of the riverine sediment system, but to show how tracer/fingerprinting studies can be used to gain insights into system functions that would not otherwise be possible. The text, then, provides researchers and catchment managers with a summary of the strengths and limitations of the examined techniques in terms of their temporal and spatial resolution, data requirements, and the uncertainties in the generated results. The use of environmental tracers has increased significantly during the past decade because it has become clear that documentation of sediment and sediment-associated contaminant provenance and dispersal is essential to mitigate their potentially harmful effects on aquatic ecosystems. Moreover, the use of monitoring programs to determine the source of sediments to a water body has proven to be a costly, labor intensive, long-term process with a spatial resolution that is limited by the number of monitoring sites that can be effectively maintained. Alternative approaches, including the identification and analysis of eroded upland areas and the use of distributed modeling routines also have proven problematic. The application of tracers within riverine environments has evolved such that they focus on sediments from two general sources: upland areas and specific, localized, anthropogenic point sources. Of particular importance to the former is the development of geochemical fingerprinting methods that quantify sediment provenance (and to a much lesser degree, sediment-associated contaminants) at the catchment scale. These methods have largely developed independently of the use of tracers to document the source and dispersal pathways of contaminated particles from point-sources of anthropogenic pollution at the reach- to river corridor-scale. Future studies are likely to begin merging the strengths of both approaches while relying on multiple tracer types to address management and regulatory issues, particularly within the context of the rapidly developing field of environmental forensics.

This compilation of techniques, methodologies and scientific data arises from a four-year Italian research project, which took place at university research stations in Turin, Piacenza, Naples and Potenza. Soil Organic Matter (SOM) represents an active and essential pool of the total organic carbon on the planet. Consequently, even small changes in this SOM carbon pool may have a significant impact on the concentration of atmospheric CO2. Recent new understanding of the chemical nature of SOM indicates that innovative and sustainable technologies may be applied to sequester carbon in agricultural soils. Overall results of the project have been applied to develop an innovative model for the prediction and description, both quantitatively and qualitatively, of carbon sequestration in agricultural soils. This book provides experts in different areas of soil science with a complete picture of the effects of new soil management methods and their potentials for practical application in farm management.

Based on an American Chemical Society Symposium organized by Professors Glenn Seaborg and Oliver Manuel, this volume provides a comprehensive record of different views on this important subject at the end of the 20th century. They have assembled a blend of highly respected experimentalists and theorists from astronomy, geology, meteoritics, planetology and nuclear chemistry and physics to discuss the origin of elements in the solar system. The intent was to include all points of view and let history judge their validity.

The Qattara Depression is part of the Northwestern Desert in Egypt and is home to the second lowest point in Africa at -133 meters below sea level. Therefore, before any projects can be carried out in this area, we must first understand the geology of the land. The present study deals with the high-resolution sequence stratigraphic analysis of the Lower Miocene Moghra Formation outcrops in the Qattara Depression Region. The literature on the sedimentology and sequence stratigraphy of the Moghra Formation has been sparse to date, despite some excellent work over the years by academic and petroleum workers. Moreover, the area studied is within what was once a front-line of World War II, where mine fields and war relics are scattered and cover wide reaches. This has resulted in limited geologic mapping in the past. Thus, great attention is paid in this study to establishing a robust sedimentology and high-resolution sequence stratigraphic framework for the Lower Miocene Moghra Formation. Included are works based on outcrops and, most importantly, new sedimentological and chronostratigraphic information not previously available.

This classic textbook is an introduction to the systematics and the use of stable isotopes in geosciences. It is subdivided into three parts: i) theoretical and experimental principles, ii) fractionation processes of light and heavy elements, iii) the natural variations of geologically important reservoirs. Since the publication of the previous edition improvements in multi-collector ICP mass-spectrometry have increased the ability to measure isotope ratios with very high precision for many elements of the periodic table. The amount of published data has increased tremendously in the last years; thus, conclusions based on a limited database are now better constrained. In this new edition, therefore, 47 elements with resolvable natural variations in isotope composition are discussed. This increase of elements, together with advances in the calculation of equilibrium isotope fractionation using ab initio methods, has led to an unbelievable rise of publications, making substantial major revisions and extensions of the last edition necessary. Many new references have been added, which enable quick access to recent literature.

This book is a collection of all the lectures by the professors attending the 3rd "Interna tional School on Marine Chemistry" held in Ustica (Palermo, Italy, September 2000), under the auspices of the United Nations and the Italian Chemical Society. The School was organized by the University of Palermo in co-operation with the Natural Marine Reserve of Ustica Island. The Organising Committee of the School wishes to thank the University of Messina, the University of Roma "La Sapienza: ' the Italian University Consortium of Environ mental Chemistry, and the Marine Reserve of Ustica Island for their financial support to the School. This book has been printed with the financial support of the Environmental Re search Centre CIRITA of the University of Palermo. thank all the professors whose outstanding scientific contributions have The editors made it possible to publish this book. Professor Antonio Gianguzza Professor Ezio Pelizzetti Professor Silvio Sammartano Contents Part I Biogeochemical Processes at the Air-Water and Water-Sediment Interface .............................................. ."

The application of surface geochemical methods to finding petroleum is based on the detection of hydrocarbons in the soil that have leaked from a petroleum reservoir at depth. While the seal over the deposit was once considered impermeable, surface geochemistry data now show that such leakage is a common occurrence. Despite its simplicity and low costs, surface geochemistry remains controversial because, until now, there was no objective and in-depth treatment of the various methods of surface geochemistry for oil exploration. Written by a successful oil finder, this practical guide: * surveys a broad array of surface geochemistry techniques, from soil gases to microbiology, and provides clear strategies for applying them to the high-stakes art of petroleum exploration * offers numerous case studies, both successes and failures, to show the strengths and weaknesses of different approaches * examines statistical and spatial variation, surveys and models in surface geochemistry, demonstrating how each analytical tool can be used to optimize accuracy * integrates surface geochemistry data interpretation with data from conventional methods of oil exploration, and considers the economics of surface geochemical approaches * discusses key topics that have been neglected in the literature, such as grid design and the effects of soils. Geologists, geophysicists, geological engineers and exploration managers involved in petroleum exploration will gain valuable insights from this volume. By presenting and evaluating each method of surface geochemistry in a neutral tone, this book enables the reader to select and employ these methods with greater confidence.

Die 2. uberarbeitete und erweiterte Auflage der Hydrogeologischen Methoden basiert auf einer grundlichen Uberarbeitung. Dies betrifft insbesondere die Darstellung von Durchlassigkeit und Transmissivitat, Speicherkoeffizient und Porenraum sowie die Pumpversuche. Das von vielen Benutzern geschatzte Kapitel uber statistische Verfahren in der Hydrogeologie wurde nicht ubernommen. Dafur liegen im Schrifttum seit 1980 moderne, auf die elektronische Datenverarbeitung abgestimmte Bucher vor. Neue Darstellungen gibt es auch fur solche hydrogeologische Methoden, die manche Fachkollegen und Praktiker vermissen werden. Neu hinzu gekommen sind Kapitel uber die "Hydrogeochemie fur die Praxis," den Transport von Wasserinhaltsstoffen, Kontamination des Grundwassers und Sanierung von Grundwasserleitern, Grundwassermonitoring, Brunnenalterung und Regenerierung sowie Grundwasserwiedererganzung und -bilanz. Hydrogeologische Systemzusammenhange werden schlussig dargestellt und durch sehr viele anschauliche Abbildungen illustriert. Dies trifft auch auf die Definition und Ableitung der wichtigsten hydrogeologischen Kennwerte zu. In den Text eingefugte Beispiele erlauben es dem Benutzer, Losungsweg und Berechnung nachzuvollziehen."

Soil and Water Contamination, Second Edition gives a structured overview of transport and fate processes of environmental contaminants. Dealing with all topics essential for understanding and predicting contaminant patterns in soil, groundwater and surface water, it contributes to the formation of a solid basis for adequate soil and water pollution control and integrated catchment management. A unique feature of this work is that it does not treat water and soil pollution as independent processes, but as components of an integrated whole. The core of this geoscientific approach is divided into four parts: * Introduction to the basics of soil and water contamination, such as the fundamentals of environmental pollution and chemistry and the basic properties of soil, groundwater and surface water. * Source, role, and behaviour of substances in soil and water, treating natural and anthropogenic sources of nutrients, heavy metals, radionuclides and organic pollutants as well as emerging substances of concern, their physico-chemical characteristics, behaviour, and toxicity. * Transport and fate of substances in soil and water, focusing on processes of transport, exchange and transformations like advection, dispersion, adsorption kinetics and biochemical decay. Special attention is paid to the mathematical description and modelling of these processes. * Patterns of substances in soil and water, explaining spatial and temporal patterns of pollutants in soil, groundwater, and surface water, illustrated by recent case studies from fundamental and applied research. This comprehensive, successful textbook, now in its second edition, has been conscientiously updated and extended and includes many case studies, examples and exercises sections, providing undergraduate and graduate students in the Earth and Environmental Sciences with all the material necessary for the study of soil and water contamination. In addition, it can serve as a useful source of information for professionals.

The Working Group M.O. (Interactions of soil minerals with organic components and microorganisms) (WGMO) of the International Soil Science Society (ISSS) was founded in 1990 at the 14th World Congress of Soil Science (Kyoto, Japan), with Professor P.M. Huang being the Chairman. Since then, the Working Group M.O. has served as a forum to bring together soil chemists, soil mineralogists, soil microbiologists, soil biochemists, soil physi cists and environmental, ecological, and health scientists. The objective of the Working Group M.O. is to promote research, teaching, and also the exchange of technology concerning the knowledge and the impact of the interactions between minerals-organics and microorganisms on environmental quality, agricultural sustainability, and ecosystem "health". This group is first a scientific group as defined just previously, but it also intends to develop exchange and transfer between scientists and engineers. The first International Meeting organized by Professor P. M. Huang, was held in Edmonton, Canada, in August 1992, where 87 papers were presented by scientists from 20 countries. Following this meeting, a two volume book was edited by P. M. Huang, J. Berthelin, J.-M. Bollag, W. B. McGill, and A. L. Page, entitled "Environmental impact of soil component interaction" : Volume I "Natural and anthropogenic organic-volume II "Metals, other inorganic and microbial activities", and published by c.R.C. Lewis Pub lishers (1995).

A significant advance in climatological scholarship, Tectonic Uplift and Climate Change is a multidisciplinary effort to summarize the current status of a new theory steadily gaining acceptance in geoscience circles: that long-term cooling and glaciation are controlled by plateau and mountain uplift. Researchers in many diverse fields, from geology to paleobotany, present data that substantiate this hypothesis. The volume covers most of the key, dramatic transformations of the Earth's surface.

John E. Mylroie and Ira D. Sasowsky' Caves occupy incongruous positions in both our culture and our science. The oldest records of modem human culture are the vivid cave paintings from southern France and northern Spain, which are in some cases more than 30,000 years old (Chauvet, et ai, 1996). Yet, to call someone a "caveman" is to declare them primitive and ignorant. Caves, being cryptic and mysterious, occupied important roles in many cultures. For example, Greece, a country with abundant karst, had the oracle at Delphi and Hades the god of death working from caves. People are both drawn to and mortified by caves. Written records ofcave exploration exist from as early as 852 BC (Shaw, 1992). In the decade of the 1920's, which was rich in news events, the second biggest story (as measured by column inches of newsprint) was the entrapment of Floyd Collins in Sand Cave, Kentucky, USA. This was surpassed only by Lindbergh's flight across the Atlantic (Murray and Brucker, 1979).