Ce anomalies track changes in oxygen availability due to the anomalous redox-sensitivity of Ce compared with the other rare earth elements. The proxy systematics have been calibrated experimentally as well as in modern anoxic water bodies. Ce anomalies are unique because they track intermediate manganous conditions, rather than fully anoxic conditions. In addition, they are sensitive to local-regional redox conditions, and can be analysed in chemical sediments such as carbonate rocks. This makes them especially useful as a tool to track local oxygen distribution in shallow shelf environments, where biodiversity is highest. This review focusses on the systematics of the Ce anomaly proxy, the preservation and extraction of the signal in sedimentary rocks, and the potential applications of the proxy.

Paleosols formed in direct contact with the Earth's atmosphere, so they can record the composition of the atmosphere through weathering processes and products. Herein we critically review a variety of different approaches for reconstructing atmospheric O2 and CO2 over the past three billion years. Paleosols indicate relatively low CO2 over that time, requiring additional greenhouse forcing to overcome the 'faint young Sun' paradox in the Archean and Mesoproterozoic, as well as low O2 levels until the Neoproterozoic. Emerging techniques will revise the history of Earth's atmosphere further and may provide a window into atmospheric evolution on other planets.

Based on a university course, this book provides an exposition of a large spectrum of geological, geochemical and geophysical problems that are amenable to thermodynamic analysis. It also includes selected problems in planetary sciences, relationships between thermodynamics and microscopic properties, particle size effects, methods of approximation of thermodynamic properties of minerals, and some kinetic ramifications of entropy production. The textbook will enable graduate students and researchers alike to develop an appreciation of the fundamental principles of thermodynamics, and their wide ranging applications to natural processes and systems.

This second edition is fully updated to include new developments in the study of metamorphism as well as enhanced features to facilitate course teaching. It integrates a systematic account of the mineralogical changes accompanying metamorphism of the major rock types with discussion of the conditions and settings in which they formed. The use of textures to understand metamorphic history and links to rock deformation are also explored. Specific chapters are devoted to rates and timescales of metamorphism and to the tectonic settings in which metamorphic belts develop. These provide a strong connection to other parts of the geology curriculum. Key thermodynamic and chemical concepts are introduced through examples which demonstrate their application and relevance. Richly illustrated in colour and featuring end-of-chapter and online exercises, this textbook is a comprehensive introduction to metamorphic rocks and processes for undergraduate students of petrology, and provides a solid basis for advanced study and research.

Vanadium isotope ratios (51V/50V) have potential to provide information about changes in past ocean oxygen contents. In particular, V isotopes may find utility in tracing variations at non-zero oxygen concentrations because the redox couple that controls V elemental and isotopic abundances in seawater (vanadate-vanadyl) appears to operate around 10M O2. This characteristic sets V isotopes apart from many other metal isotope redox proxies that require more reducing conditions to register significant changes in their isotope budgets. The oxygen abundance sensitivity range of V isotopes suggests that this paleoproxy could be particularly useful in tracing marine oxygenation changes throughout the Phanerozoic and potentially beyond.

The use of the trace element content of sedimentary pyrite as a proxy for the trace element composition of past oceans has recently emerged. The pyrite proxy has several potential advantages over bulk sample analysis: preservation through metamorphism; little dilution during analysis (samples are ablated not dissolved, allowing for the less abundant elements commonly held in the sulfide fraction to be investigated as proxies); accurate measurement of several elements simultaneously; the ability to screen sediments for hydrothermal overprint; and the technique can give information regarding trace element availably at multiple stages of diagenesis. Because of these multiple strengths, the pyrite trace element proxy is a valuable potential addition to the paleo-ocean chemistry tool kit.

The TEX86 paleothermometer is based upon the distribution of archaeal membrane lipids ('GDGTs') in marine sediments. GDGTs are ubiquitous, abundant and relatively resistant to degradation; as such, the TEX86 paleothermometer has been used to reconstruct sea surface temperature (SST) during the Cenozoic and early Mesozoic. We review the principles of the TEX86 proxy and developments made over the last two decades. We also discuss its application as a paleotemperature proxy and explore existing challenges and limitations.

This book describes the latest advances, innovations and applications in the field of waste management and environmental geomechanics as presented by leading researchers, engineers and practitioners at the International Conference on Sustainable Waste Management through Design (IC_SWMD), held in Ludhiana (Punjab), India on November 2-3, 2018. Providing a unique overview of new directions, and opportunities for sustainable and resilient design approaches to protect infrastructure and the environment, it discusses diverse topics related to civil engineering and construction aspects of the resource management cycle, from the minimization of waste, through the eco-friendly re-use and processing of waste materials, the management and disposal of residual wastes, to water treatments and technologies. It also encompasses strategies for reducing construction waste through better design, improved recovery, re-use, more efficient resource management and the performance of materials recovered from wastes. The contributions were selected by means of a rigorous peer-review process and highlight many exciting ideas that will spur novel research directions and foster multidisciplinary collaboration among different waste management specialists.

The attraction of selenium isotopes as a paleoenvironmental tracer lies in the high redox potential of selenium oxyanions (SeIV and SeVI), the dominant species in the modern ocean. The largest isotopic fractionations occur during oxyanion reduction, which makes selenium isotopes a sensitive proxy for the redox evolution of our planet. As a case study we review existing data from the Neoarchean and Paleoproterozoic, which show that significant isotopic fractionations are absent until 2.5 Ga, and prolonged isotopic deviations only appear around 2.3 Ga. Selenium isotopes have thus begun to reveal complex spatiotemporal redox patterns not reflected in other proxies.

Shipping is responsible for transporting 90% of the world's trade. This book provides a comprehensive review of the impact shipping has on the environment. Topics covered include pollutant discharges such as atmospheric emissions, oil, chemical waste, sewage and biocides; as well as non-pollutant impacts including invasive species, wildlife collisions, noise, physical damage, and the environmental effects associated with shipwrecks and shipbreaking. The history of relevant international legislation is also covered. With chapters written by eminent international authors, this book provides a global perspective on the environmental impact of ships, making it a useful reference for advanced students and researchers of environmental science, as well as practitioners of maritime law and policy, and marine business.

This book includes the proceedings of the conference "Problems of the Geocosmos" held by the Earth Physics Department, St. Petersburg State University, Russia, every two years since 1996. Covering a broad range of topics in solid Earth physics and solar-terrestrial physics, as well as more applied subjects such as engineering geology and ecology, the book reviews the latest research in planetary geophysics, focusing on the interaction between the Earth's shells and the near-Earth space in a unified system. This book is divided into four sections: * Exploration and Environmental Geophysics (EG), which covers two broad areas of environmental and engineering geophysics - near-surface research and deep geoelectric studies; * Paleomagnetism and Rock Magnetism (P), which includes research on magnetostratigraphy, paleomagnetism applied to tectonics, environmental magnetism, and marine magnetic anomalies; * Seismology (S), which covers the theory of seismic wave propagation, Earth's structure from seismic data, global and regional seismicity and sources of earthquakes, and novel seismic instruments and data processing methods; and * Physics of Solar-Terrestrial Connections (STP), which includes magnetospheric phenomena, space weather, and the interrelationship between solar activity and climate.

Introducing the essentials of modern geochemistry for students across the Earth and environmental sciences, this new edition emphasises the general principles of this central discipline. Focusing on inorganic chemistry, Francis Albarede's refreshing approach is brought to topics that range from measuring geological time to the understanding of climate change. The author leads the student through the necessary mathematics to understand the quantitative aspects of the subject in an easily understandable manner. The early chapters cover the principles and methods of physics and chemistry that underlie geochemistry, to build the students' understanding of concepts such as isotopes, fractionation, and mixing. These are then applied across many of the environments on Earth, including the solid Earth, rivers, and climate, and then extended to processes on other planets. Three new chapters have been added - on stable isotopes, biogeochemistry, and environmental geochemistry. End-of-chapter student exercises, with solutions available online, are also included.

This book examines picroilmenites and their ferromagnetic behavior in the kimberlites from the Yakut diamondiferous province. Picroilmenites are minerals used to identify the location of diamonds. The author shows a solid interpretation of the magnetic-mineralogical analysis of ferromagnetic minerals based on a large number of experimental data and modeling of the magnetic state. He also presents the problems of the variability of the composition of picroilmenites from various kimberlite pipes. Furthermore, this book proposes a method to estimate the distribution of the decay structures dimensions, according to the thermomagnetic analysis and coercive spectra of titanomagnetites with the magnetite-ulvospinel decomposition structures. This book will be useful for students and researchers working in the field of rock magnetism, as well as geologists and geophysicists.

This book is focused on the basics of applying thermochronology to geological and tectonic problems, with the emphasis on fission-track thermochronology. It is conceived for relatively new practitioners to thermochronology, as well as scientists experienced in the various methods. The book is structured in two parts. Part I is devoted to the fundamentals of the fission-track method, to its integration with other geochronologic methods, and to the basic principles of statistics for fission-track dating and sedimentology applied to detrital thermochronology. Part I also includes the historical development of the technique and thoughts on future directions. Part II is devoted to the geological interpretation of the thermochronologic record. The thermal frame of reference and the different approaches for the interpretation of fission-track data within a geological framework of both basement and detrital studies are discussed in detail. Separate chapters demonstrate the application of fission-track thermochronology from various perspectives (e.g., tectonics, petrology, stratigraphy, hydrocarbon exploration, geomorphology), with other chapters on the application to basement rocks in orogens, passive continental margins and cratonic interiors, as well as various applications of detrital thermochronology.

This book presents findings from research into the Precambrian history of the Indian shield obtained using state-of-the-art technology. It demonstrates a paradigm shift towards studying the Precambrian shield regions using petrological, geochemical, structural, metallogenic, sedimentological and paleobiological data from the rocks in the Precambrian shield area, and presents a collection of contributions on these diverse topics that help to reconstruct the Precambrian evolution of the Indian Shield.

This book sheds valuable new light on the genetic mineralogy of lower-mantle diamonds and syngenetic minerals. It presents groundbreaking experimental results revealing the melting relations of ultrabasic and basic associations and a physicochemical peritectic mechanism of their evolution. The experimental investigations included here reveal the key multicomponent, multiphase oxide-silicate-carbonate-carbon parental media for lower-mantle diamonds and syngenetic minerals. Consequently, readers will find extensive information on the diamond-parental oxide-silicate-carbonate-carbon melts-solutions that supplement the general features of lower-mantle diamond genesis and the most efficient ultrabasic-basic evolution. The experimental results on physicochemical aspects, combined with analytical mineralogy data, make it possible to create a generalized composition diagram of the diamond-parental melts-solutions, there by completing the mantle-carbonatite concept for the genesis of lower-mantle diamonds and syngenetic minerals. This book addresses the needs of all researchers studying the Earth's deepest structure, super-deep mineral formation including diamonds, and magmatic evolution.

Uranium isotopes (238U/235U) have emerged as a proxy to reconstruct the redox conditions of the Earth's oceans and atmosphere based upon the large isotopic fractionation between reduced U(IV) and oxidized U(VI). Variations in 238U/235U, particularly when recorded in carbonate sediments, can track global trends in marine oxygenation and de-oxygenation. It is unique from other proxies because reduction primarily occurs at the sediment-water interface, and this sensitivity makes U isotopes especially relevant for the habitability of benthic animals. This Element covers the background, methods, and case studies of this promising tool for understanding Earth's environmental transitions, as rapid development continues to refine the accuracy of interpretations of 238U/235U records.

This book reviews the geochemical and petrological characteristics of potassic igneous rock complexes, and investigates the various tectonic settings in which these rocks occur. The authors provide an overview and classification of these rocks and elucidate the geochemical differences between barren and mineralized potassic igneous complexes. High-K rocks are genetically associated with a number of epithermal gold and porphyry copper-gold deposits. In recent years, there has also been growing recognition of an association of such rocks with iron-oxide copper-gold (IOCG) deposits, intrusion-related gold deposits (IRGDs) and Carlin-type gold deposits. This fifth updated and expanded edition incorporates new data and references from world-class copper and gold deposits worldwide. It also includes the latest publications on the petrogenesis of high-K magmatism and related mineral deposits. Numerous new representative ore photographs of the mineral deposits described are also included in the new edition. As such, the book offers a valuable guide not only for academic petrologists working on alkaline rocks, but also for exploration geologists prospecting for epithermal gold and/or porphyry copper-gold deposits in modern and ancient terrains.

This thesis presents geological, petrological, geochemical, and zircon U-Pb-Lu-Hf isotopic field data for representative Precambrian lithologies in the Western Liaoning-Northeastern Hebei Provinces along the northern margin of the North China Craton (NCC). It describes late Neoarchean (2.64-2.48 Ga) supracrustal metavolcanic rocks and granitoid gneisses; late Paleoproterozoic (1.72-1.68 Ga) Jianping alkaline plutons and Pinggu alkaline volcanic rocks; and newly discovered ~1.23 Ga mafic dykes. The nature of magma sources and genesis of each magmatic episode are investigated, and the Precambrian (~2.6-1.2 Ga) lithospheric mantle evolution and crust-mantle interaction processes are established for the first time -aspects that provide important constraints in our understanding of the Precambrian crustal evolution and geodynamic processes in the region studied.

Chondrules are spherical silicate grains which formed from protoplanetary disk material, and as such provide an important record of the conditions of the Solar System in pre-planetary times. Chondrules are a major constituent in chondritic meteorites, however despite being recognised for over 200 years, their origins remain enigmatic. This comprehensive review describes state-of-the-art research into chondrules, bringing together leading cosmochemists and astrophysicists to review the properties of chondrules and their possible formation mechanisms based on careful observations of their chemistry, mineralogy, petrology and isotopic composition. Current and upcoming space missions returning material from chondritic asteroids and cometary bodies has invigorated research in this field, leading to new models and observations, and providing new insight into the conditions and timescales of the solar protoplanetary disk. Presenting the most recent advances, this book is an invaluable reference for researchers and graduate students interested in meteorites, asteroids, planetary accretion and solar system dynamics.

This book provides the first comprehensive compilation of cutting-edge research on Merapi volcano on the island of Java, Indonesia, one of the most iconic volcanoes in the world. It integrates results from both the natural (geology, petrology, geochemistry, geophysics, physical volcanology) and social sciences, and provides state-of-the-art information on volcano monitoring, the assessment of volcanic hazards, and risk mitigation measures. As one of Indonesia's most active and dangerous volcanoes, Merapi is perhaps best known for its pyroclastic density currents, which are produced by gravitational or explosive lava dome failures (commonly referred to as Merapi-type nuees ardentes). Merapi's eruptions have posed a persistent threat to life, property and infrastructure within the densely populated areas on the volcano's flanks, as demonstrated most recently by catastrophic eruptions, which attracted worldwide media interest.

This is the first book to provide a comprehensive and state-of-the-art introduction to the novel and fast-evolving topic of in-situ produced cosmogenic nuclides. It presents an accessible introduction to the theoretical foundations, with explanations of relevant concepts starting at a basic level and building in sophistication. It incorporates, and draws on, methodological discussions and advances achieved within the international CRONUS (Cosmic-Ray Produced Nuclide Systematics) networks. Practical aspects such as sampling, analytical methods and data-interpretation are discussed in detail and an essential sampling checklist is provided. The full range of cosmogenic isotopes is covered and a wide spectrum of in-situ applications are described and illustrated with specific and generic examples of exposure dating, burial dating, erosion and uplift rates, and process model verification. Graduate students and experienced practitioners will find this book a vital source of information on the background concepts and practical applications in geomorphology, geography, soil-science, and geology.

Large igneous provinces (LIPs) are intraplate magmatic events, involving volumes of mainly mafic magma upwards of 100,000 km3, and often above 1 million km3. They are linked to continental break-up, global environmental catastrophes, regional uplift and a variety of ore deposit types. In this up-to-date, fascinating book, leading expert Richard E. Ernst explores all aspects of LIPs, beginning by introducing their definition and essential characteristics. Topics covered include continental and oceanic LIPs; their origins, structures, and geochemistry; geological and environmental effects; association with silicic, carbonatite and kimberlite magmatism; and analogues of LIPs in the Archean, and on other planets. The book concludes with an assessment of LIPs' influence on natural resources such as mineral deposits, petroleum and aquifers. This is a one-stop resource for researchers and graduate students in a wide range of disciplines, including tectonics, igneous petrology, geochemistry, geophysics, Earth history, and planetary geology, and for mining industry professionals.

Granites are emblematic rocks developed from a magma that crystallized in the Earth's crust. They ultimately outcrop at the surface of every continent. This book offers a modern presentation of granitic rocks. It considers granites in their geological spatial and temporal frame, and in relation to plate tectonics and Earth history. The book - translated, edited, and updated from the original French edition Petrologie des Granites published by Vuibert in 2011 - gives a modern presentation of granitic rocks, or granites, from magma genesis to their emplacement into the crust and their crystallization. Mineralogical, petrological, physical, and economical aspects are explored and developed in a succession. The text is supported throughout by a large number of illustrations, descriptions of modern techniques, and additional boxes holding further discussions for those wishing to deepen their knowledge of the subject.