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This volume addresses the fundamental factors that underlie our understanding of mineral behaviour and crystal chemistry - a timely topic given current advances in research into the complex behaviour of solids and supercomputing.

Dating the Quaternary, which covers approximately the last 2 million years, has experienced considerable progress over the past few decades. On the one hand, this resulted from the necessity to obtain a valid age concept for this period which had seen tremendous environmental changes and the advent of the genus Homo. On the other hand, instrumental improvements, such as the introduction of highly sensitive analytical techniques, gave rise to physical and chemical innovations in the field of dating. This rapid methodological development is still in full progress. The broad spectrum of chronometric methods applicable to young rocks and artifacts also becomes increasingly intricate to the specialist. Hence, it is my goal to present a comprehensive, state-of-the-art sum mary of these methods. This book is essentially designed as an aid for scientists who feel a demand for dating tasks falling into this period, i. e., Quaternary geologists and archaeologists in the broadest sense. Since it has been developed from a course of lectures for students of geological and archaeological sciences, held at the University of Heidelberg, it certainly shall serve as an introduction for students of these disciplines."

The handling of actinides and actinide-based materials provides significant technological challenges due to the toxicity and radioactivity associated with these materials. These challenges are particularly apparent in the nuclear power industry. Under normal operation, a reactor can produce a significant amount of spent fuel requiring subsequent containment for geologic times, and under accident conditions it can release lethal doses of radioactive material to the environment. Inevitably, radioactive material will enter the environment, necessitating as complete an understanding as possible of its behavior. An understanding of the interaction between actinides and the environment must be based on a knowledge of their basic physical and chemical properties. To date, although there is general agreement on the principles for waste disposal, no facility has been built for the long term disposal of high level radioactive waste from either normal reactor operations or from accidental catastrophes. This makes it most important for the scientific and technical community to develop the necessary cross-disciplinary understanding that will help us implement safe and secure waste management, accident remediation and accident prevention systems.

Biology Distribution and ecology Taphonomy and preservation Field sampling and coring Laboratory procedures Data analysis and interpretation Summary Acknowledgements References 9. Chrysophyte scales and cysts. B. A. Zeeb & J. P. Smol 203 Introduction Taxonomy and nomenclature Methods Paleolimnological applications Future research directions Summary Acknowledgements References 10. Ebridians. A. Korhola & J. P. Smol 225 Introduction Morphology, taxonomy and preservation in the sediments Methodological aspects Brief history of use of ebridians in palaeoecological research Indicator value and future research priorities Summary Acknowledgements References 11. Phytoliths. D. R. Piperno 235 Introduction and history Phytolith production and taxonomy Laboratory methods Applications of phytolith analysis in lake sediments Summary of the major results Other potential applications of phytoliths in lake sediments Summary Acknowledgments References x 12. Freshwater sponges. 253 T. M. Frost Introduction Sponge species and their distribution Sponge life history Sponge spicules Paleolimnological studies using freshwater sponges Techniques for assessing sponge spicules in sediments Future applications of sponges in paleolimnology Summary Acknowledgements References 13. Siliceous protozoan plates and scales. M. S. V. Douglas & J. P. Smol 265 Introduction History and taxonomy Ecology Paleoecological potential Laboratory methods Data presentation Paleolimnological applications Other related siliceous indicators Summary Acknowledgements References 14. Biogenic silica. D.J. Conley & C.L Schelske 281 Introduction and history Methods Applications Future directions Summary Acknowledgements References 15. Sedimentary pigments.

Origins of fallout radionuclides Sediment records of fallout radionuclides Simple dating models Vertical mixing Numerical techniques Radiometric techniques Discussion Summary Acknowledgements References 10. chronostratigraphic techniques in paleolimnology. Svante Bjorck & Barbara Wohlfarth 205 Introduction Methods and problems Radiocarbon-dating different fractions of the sediment as a chronostratigraphic tool Dating of long (old) stratigraphies High resolution dating and wiggle matching dating versus absolute dating techniques of lacustrine sediments Concluding remarks Summary Useful www addresses Acknowledgements References 11. Varve chronology techniques. Scott Lamoureux 247 Introduction Methods Summary and future directions Acknowledgements References 12. Luminescence dating. Olav B. Lian & D. J. Huntley 261 Introduction The mechanism responsible for luminescence Dating and estimation of the paleodose Thermoluminescence dating Optical dating Evaluating the environmental dose rate xi Sample collection and preparation What types of depositional environments are suitable for luminescence dating? What can lead to an inaccurate optical age? Summary Acknowledgements References 13. Electron spin resonance (ESR) dating in lacustrine environments. Bonnie A. B. Blackwell 283 Introduction Principles of ESR analysis Sample collection ESR analysis ESR microscopy and other new techniques Applications and datable materials in limnological settings Summary Acknowledgements References 14. Use of paleomagnetism in studies of lake sediments. John King & John Peck 371 Introduction Recording fidelity of geomagnetic behavior by sediments Field and laboratory methods Holocene SV records Magnetostratigraphic studies of Neogene lake sediments Excursions, short events and relative paleointensity Conclusions Summary References 15. Amino acid racemization (AAR) dating and analysis in lacustrine environments."

In a time when an unquestionable link between anthropogenic emissions of greenhouse gases and climatic changes has finally been acknowledged and * widely documented through IPCC reports, the need for precise estimates of greenhouse gas (GHG) production rates and emissions from natural as well as managed ecosystems has risen to a critical level. Future agreements between nations concerning the reduction of their GHG emissions will - pend upon precise estimates of the present level of these emissions in both natural and managed terrestrial and aquatic environments. From this viewpoint, the present volume should prove to a benchmark contribution because it provides very carefully assessed values for GHG emissions or exchanges between critical climatic zones in aquatic en- ronments and the atmosphere. It also provides unique information on the biases of different measurement methods that may account for some of the contradictory results that have been published recently in the literature on this subject. Not only has a large array of current measurement methods been tested concurrently here, but a few new approaches have also been developed, notably laser measurements of atmospheric CO concentration 2 gradients. Another highly useful feature of this book is the addition of - nitoring and process studies as well as modeling.

"Polymineral-Metasomatic Crystallogenesis" is dedicated to the foundations of polymineral crystallogenesis in solutions typically occurring in nature. Effects, laws, and mechanisms of a metasomatic crystal replacement, joint crystal growth of different phases, mixed crystal formation, and aggregate re-crystallization as well as oriented overgrowth (epitaxy and quasi-epitaxy) and crystal habit origin are considered experimentally. The behaviour of these processes in nature are discussed in addition to pseudomorphs, poikilitic crystals (and other replacement forms), features of rapakivi structure, fluorite morphology, and many more. The concept is a generalization of the classic theory on crystallogenesis which is complicated by phase interaction in polymineral systems.

"Polymineral-Metasomatic Crystallogenesis" is designed for chemists, geologists, physicists, and postgraduates and advanced undergraduate students of these fields.

This book covers the basics of abiotic colloid characterization, of biocolloids and biofilms, the resulting transport phenomena and their engineering aspects. The contributors comprise an international group of leading specialists devoted to colloidal sciences. The contributions include theoretical considerations, results from model experiments, and field studies. The information provided here will benefit students and scientists interested in the analytical, chemical, microbiological, geological and hydrological aspects of material transport in aquatic systems and soils.

This book presents contributions by experts from diverse disciplines, estimating the global levels of biogeogenic and anthropogenic emissions of organometal(loid) compounds, and thus presenting insight into processes which influence the genesis, as well as the distribution and stability of these species and their interaction with each other and other matrix compounds. The authors evaluate identify potential "hot spots" of organometal(loid)s, which can negatively influence ecosystems and human health.

The origin of different kinds of igneous rocks can be understood in terms of their tectonic setting, and by way of the isotope compositions of strontium, neodymium, and lead. This book explains the petrogenesis of igneous rocks as a consequence of tectonic processes resulting from interactions between asthenopheric plumes and the overlying lithospheric mantle. The relevant principles of isotope geochemistry are explained in the first chapter, making it accessible for university students as well as professionals. The relevant isotopic data is presented in diagrammatic form. The book contains more than 400 original drawings.

Geochemical barrier zones play an important role in determining various physical systems and characteristics of the oceans, e.g. hydrodynamics, salinity, temperature and light. In this book, each of the 40 barrier zones covered are illustrated and defined by physical-chemical parameters. Among the topics discussed are the processes of inflow, transformation and precipitation of the sedimentary layer of the open oceans and more restricted areas such as the Baltic, Black and Mediterranean Seas. This well-illustrated book may serve as the basis for courses such as "Marine Geochemistry" or "Ocean Usage" and can be useful to researchers in the fields of geology, geography, marine chemistry, geoecology and hydrochemistry.

This book describes advances in this new, fast developing science, which seeks to decipher fundamental mechanisms ruling the behaviour in water, soils, atmosphere, food and living organisms of toxic metals, fossil fuels, pesticides and other organic pollutants. Sections on eco-toxicology, green chemistry, and analytical chemistry round out this thorough survey of conditions and analytical techniques in an emerging specialty.

The volume focuses on the ecological functioning of rivers, which has received less attention than functioning of lakes and reservoirs. The selected papers cover a large range of topics relating to aquatic communities, eutrophication, nutrient dynamics and organic pollution, erosion and sediment transport, and fate of micropollutants at the basin scale. Integrated approaches developed in order to study the ecological functioning of fluvial systems perturbed by human activity are presented. This functioning is analysed from the point of view of fundamental research, but insights into system management are not neglected. This book will be of interest to researchers in the field of aquatic ecology, river system functioning, and water surface pollution, to postgraduate students, to the institutions involved in water resource management, and to the drinking water and waste water treatment industries. It draws information from many large river systems in the world.

Mechanochemistry as a branch of solid state chemistry enquires into processes which proceed in solids due to the application of mechanical energy. This provides a thorough, up to date overview of mechanochemistry of solids and minerals. Applications of mechanochemistry in nanoscience with special impact on nanogeoscience are described. Selected advanced identification methods, most frequently applied in nanoscience, are described as well as the advantage of mechanochemical approach in minerals engineering. Examples of industrial applications are given. Mechanochemical technology is being applied in many industrial fields: powder metallurgy (synthesis of nanometals, alloys and nanocompounds), building industry (activation of cements), chemical industry (solid waste treatment, catalyst synthesis, coal ashes utilization), minerals engineering (ore enrichment, enhancement of processes of extractive metallurgy), agriculture industry (solubility increase of fertilizers), and pharmaceutical industry (improvement of solubility and bioavailability of drugs).

This reference serves as an introduction to newcomers to mechanochemistry, and encourages more experienced researchers to broaden their knowledge and discover novel applications in the field.

This book focuses on sediments as a pollutant in natural freshwater and marine habitats, and as a vector for the transfer of chemicals such as nutrients and contaminants. Sediment-water research is carried out all over the world within a variety of disciplines. The selected papers cover three main topics:
-assessment and/or restoration of disturbed watersheds
-sediment-water linkages in terrestrial and aquatic environments
-evaluation of sediment and ecological changes in marine and freshwater habitats.

Innovative research in both developed and less developed countries is included and both fundamental research and insight into applied research and system management are covered.

This book will be of interest to graduate students, researchers, catchment managers and government regulators working within many areas of education, protection and management of the environment, including sediment geochemistry and dynamics, aquatic habitats, water quality, aquatic ecology, river morphology, restoration techniques and catchment management.

This textbook gives a concise introduction to modern crystal structure determination, emphasising both its theoretical background and the way it is actually carried out. The theoretical sections are supported by many illustrations, and lay emphasis on a good understanding rather than rigorous mathematics. The most important data collection techniques, and the methods of data reduction, structure solution and refinement are discussed from a practical point of view. Many tips and insights help readers to recognise and avoid possible errors and traps, and to judge the quality of results. The second edition has been considerably updated, especially the chapter on experimental methods, which is now mainly concerned with modern data collection using area-detectors.

The first edition of this book was published in 1965 and its French translation in 1966. The revised second edition followed in 1967 and its Russian translation became available in 1969. Since then, many new petrographic observations and experimental data elucidat- ing reactions in metamorphic rocks have made a new approach in the study of metamorphic transformation desirable and possible. It is felt that this new approach, attempted in this book, leads to a better unders- tanding of rock metamorphism. The concept of metamorphic facies and subfacies considers asso- ciations of mineral assemblages from diverse bulk compositions as characteristic of a certain pressure-temperature range. As new petrographic observations accumulated, it became increasingly difficult to accommodate this information within a manageable framework of metamorphic facies and subfacies. Instead, it turned out that mineral assemblages due to reactions in common rocks of a particular composi- tion provide suitable indicators of metamorphic conditions. Metamorphic zones, defined on the basis of mineral reactions, very effectively display the evolution of metamorphic rocks. Thus the im- portance of reactions in metamorphic rocks is emphasized. Experimen- tal calibration of mineral reactions makes it possible to distinguish reac- tions which are of petrogenetic significance from those which are not. This distinction provides guidance in petrographic investigations un- dertaken with the object of deducing the physical conditions of metamorphism.

Proceedings of the NATO Advanced Research Workshop, Bremen, Germany, October 10-14, 1988

The large and rapidly expanding body ofliterature related to nitrogen cycling in both managed and native terrestrial ecosystems reflects the importance accorded to the behaviour of this vital and often limiting nutrient. Research at the organism, ecosystem and landscape levels commonly addresses questions concerning nitrogen acquisition, internal cycling and retention. Goals for this research include increased agricultural productivity and a better understanding of human impact on local, regional and global nitrogen cycles. Nitrogen cycle research in tropical regions has a long and distinguished history. Research on different aspects of nitrogen cycling in ecosystems of the tropics has been carried out in many regions. In relatively few instances has there, however, been a focus on the biogeochemical cycles at the ecosystem level. The meeting resulting in this volume was an attempt to bring together existing information on nitrogen cycling in ecosystems of Latin America and the Caribbean and discuss this in an ecosystem context.

This book represents the proceedings of the 9th written by a very active group of physicists at Kongsberg seminar, held at the Norwegian Mining the University of Oslo - physicists interested in Museum located in the city of Kongsberg about complex systems in general and geo-like systems 70 km Southwest of Oslo. The Kongsberg district in particular. is known for numerous Permian vein deposits of The content of the book is organized into three native silver, and mining activity in the area lasted major parts following the introductory chapter. for more than 300 years, finally ceasing in 1957. Chapters 2 to 7 primarily treat the role of fluids The previous eight Kongsberg seminars were in specific geological environments, ranging from focused on ore-forming processes and all of these sedimentary basins (Chapters 2-3) to contact were organized by Professor Arne Bj0rlykke, now metamorphic/hydrothermal scenarios (Chapters director of the Norwegian Geological Survey. 4-5) and regional metamorphic settings (Chapters Since process-orientated research tends to break 6-7). The following four chapters (8-11) focus down the traditional barriers between the different on various properties of fluid-rock systems that geological disciplines, this seminar has always are critical in controlling flow and transport been a meeting point for people with a variety through rocks. These include: mineral solubility of geological backgrounds.

Many geologists have an equivocal attitude to fluid movements within the crust and the associated changes in the chemical and physical properties of crustal rocks. The controversies earlier this centuary between the "soaks" and the "pontiffs" memorably summarised by H. H. Read (1957) in The Granite Controversy have largely been resolved. Few would now advocate the formation of large granitic bodies by in situ transformation of pre-existing crust as the result of the passage of ichors without the formation of a granitic melt. To many geochemists fluid transport and metasomatism have become slightly suspect processes which at the most locally disturb the primary geochemical and isotopic signatures. While there is common agreement that there are marked differences in the composition of the lower and upper crust, the role of fluid movement as one of the controls of this differentiation is often neglected in favour of suggested primary differences in the composition of igneous rocks emplaced at different depths. Selective fluid transport however provides many geologists with their livelyhood. Without the secondary concentration of commercially important elements by fluids within the crust the mining industry, geological science and human activities based on their products would be very different.

The idea for this book was born at the June 1996 meeting of the IDEAL Steering Committee in Milwaukee, Wisconsin. We had just completed a successful and stimulating special symposium during the annual meeting of the American Society for Limnology and Oceanography, and enthusiasm was running high for the production of a volume that could assemble in one place the scientific findings that were starting to emerge from East Africa. IDEAL, an International Decade for the East African Lakes, had ended one round of field investigations, many of which had been centered on Lake Victoria. As the climatologists, geologists, paleolimnologists, and biologists displayed their results and debated interpretations, it appeared that some paradigms were shifting, and that new explanations of climate history and modem processes were taking shape. The Steering Committee endorsed the production of a volume that would draw together the different research results that were emerging and which would be representative of the scope of science issues that exist within IDEAL. This book follows in the spirit of The Limnology, Climatology, and Paleoclimatology of the East African Lakes, published in 1996, but has a somewhat different purpose. The previous publication also included original science results, but it was conceived to review the state of knowledge, identify critical problems, and point to new paths of inquiry. It accompanied the development of our first Science and Implementation Plan for the East African Lakes.

Agriculture in the industrial world has gone A common interest of the contributors is increas through dramatic changes over the past decades. ing the understanding of the turnover of carbon Mechanization in combination with high inputs of and inorganic nutrients in terestrial ecosystems. fertilizers and pesticides has turned deficits of agri The authors approach this topic from different cultural products into surplus. Over the same directions depending on their interests and ex period we have experienced increased environment pertise. Difficulties are identified in the quantifica al problems in both the atmosphere and our water tion of below-ground production where death and resources, which have been associated with the re-growth, if incorporated into the calculations, changes in management practices. can change production figures considerably as Concern about the potential pollution by compared to values derived from "peak" estimates. nitrogen fertilizers as well as the low utilization The role of root-derived carbon is investigated in efficiency of applied nitrogen by plants has created relation to nutrient competition between roots and a need for a better understanding of nitrogen microorganisms, the cost of N2 fixation and the cycling in the plant-soil-water system. To achieve decomposition of organic nitrogen. Mycorrhizae this, it is neccessary to study process interactions use root-derived carbon and their roles in phos and process regulation in an ecosystem context. phorus conservation and in supplying nutrients to During the last decade many ecosystem studies the host are exemplified.

Studying the distribution of certain elements, present in very low concentrations in igneous and metamorphic rocks, can yield important clues about the rocks' origin and evolution. Trace elements do not give rise to characteristic minerals, but their behaviour can be modelled to provide historical information about the source magma. This book brings together the essential theory required to understand the behaviour of trace elements in magmas and magma-derived rocks. It presents a wide range of models and mechanisms which explain trace element distribution. Trace Elements in Magmas provides an excellent resource for graduate students, petrologists, geochemists and mineralogists, as well as researchers in geophysics and materials science.

The goal of this book is to examine the complex state of radioactivity in the environment, and to understand the interplay of its two principal sources: man-made and natural. The text examines human contributions to release of radionuclides, with an eye to future reductions, and assesses natural occurrences in an evaluation of baseline radioactivity.