This is a book about the why and how of doing experiments on rocks, minerals, magmas, and fluids. It could have as logically been subtitled "Experimental petrology" as "Experimental geochemistry," but we chose geochemistry to emphasize the broad and overlapping nature of current experimental work. We have tried to aim the book at a general readership which we hope will include advanced undergraduate students, graduate students, and anyone else interested in learning something about experimental petrology. Although we hope there will be something of interest for the practicing experimentalist, our aim is at the non-experimentalist interested in learning why experiments are useful, what kind of experiments can be done, and what some of the major problems and limitations are and how they can best be avoided. The result of a journey through this book should be an ability to evaluate published experimental work critically and a knowledge of the kinds of problems an experimentalist might be able to help solve. Some details of experimental technique are included in the Appendix for those readers who want to "get their hands dirty. " Indeed, one of our main incentives for writing this book was to try to encourage more petrologists and geochemists to become experimentalists. In our pedagogical approach we have chosen to discuss a small number of case histories as illustrations of principles and techniques. We have tried to select studies we regard as well executed.

This monograph presents an integrated perspective of the wide range of phenomena and processes applicable to the study of transport of species in porous materials. In order to formulate the entire range of porous media and their uses, this book gives the basics of continuum mechanics, thermodynamics, seepage and consolidation and diffusion, including multiscale homogenization methods. The particular structure of the book has been chosen because it is essential to be aware of the true properties of porous materials particularly in terms of nano, micro and macro mechanisms. This book is of pedagogical and practical importance to the fields covered by civil, environmental, nuclear and petroleum engineering and also in chemical physics and geophysics as it relates to radioactive waste disposal, geotechnical engineering, mining and petroleum engineering and chemical engineering.

Several important developments in our understanding of the chemistry of weathering have occurred in the last few years: 1. There has been a major breakthrough in our understanding of the mechanisms controlling the kinetics of sil icate dissolution, and there have been major advances in computer modeling of weathering processes. 2. There has been a growing recognition of the importance of organic solutes in the weathering process, and hence of the inter-relationships between mineral weathering and the terrestrial ecosystem. 3. The impact of acid deposition ("acid rain") has been widely recognized. The processes by which acid deposition is neutral ized are closely related to the processes of normal chemical weathering; an understanding of the chemistry of weathering is thus essential for predicting the effects of acid deposition. 4. More high-qual ity data have become available on the chemical dynamics of smal I watersheds and large river systems, which represent the integrated effects of chemical weathering.

The first edition of this book was published in 1965 and its French translation in 1966. The revised second edition followed in 1967 and its Russian translation became available in 1969. Since then, many new petrographic observations and experimental data elucidat- ing reactions in metamorphic rocks have made a new approach in the study of metamorphic transformation desirable and possible. It is felt that this new approach, attempted in this book, leads to a better unders- tanding of rock metamorphism. The concept of metamorphic facies and subfacies considers asso- ciations of mineral assemblages from diverse bulk compositions as characteristic of a certain pressure-temperature range. As new petrographic observations accumulated, it became increasingly difficult to accommodate this information within a manageable framework of metamorphic facies and subfacies. Instead, it turned out that mineral assemblages due to reactions in common rocks of a particular composi- tion provide suitable indicators of metamorphic conditions. Metamorphic zones, defined on the basis of mineral reactions, very effectively display the evolution of metamorphic rocks. Thus the im- portance ofreactions in metamorphic rocks is emphasized. Experimen- tal calibration of mineral reactions makes it possible to distinguish reac- tions which are of petrogenetic significance from those which are not. This distinction provides guidance in petrographic investigations un- dertaken with the object of deducing the physical conditions of metamorphism.

There have been numerous computer-based simulation studies carried out on the subject of CO2 geo-sequestration. However, the amount of experimental data available in the literature on this topic, especially with regards to multiphase flow characteristics of fluid-rock systems during such processes, is very limited. This research was carried out with the aim of providing a better understanding of the multiphase fluid flow characteristics of fluid-rock systems during the geo-sequestration process.

The ultimate goal of this research was to experimentally evaluate the change in a number of multiphase flow characteristics of the system over time caused by the potential chemical and physical/mechanical processes occurring during deep CO2 disposal. In order to achieve this goal the effects of cyclic/alternating CO2-brine flooding, flow direction, existence of residual hydrocarbon (natural gas) and change in the reservoir stress field on the system s multiphase flow behaviour were investigated.

Until completion of this study there were no experimental data published in the literature addressing the above mentioned issues and the results obtained, and published within this thesis were the first of their kind.

The Baltic Sea is an area extensively explored by the oceanographers. Hence it is one of the most often described marine areas in the scientific literature. However, there are still several fields which are poorly investigated and reported by scientists. One of them is the carbon cycle of the Baltic Sea. Although it is believed the shelf seas are responsible for about 20% of all marine carbon dioxide uptake, while they constitute only 7% of the whole sea surface, still a scientific debate exists on the role of the Baltic Sea in the global carbon cycle. "Carbon cycle of the Baltic Sea" is intended to be a comprehensive presentation and discussion of state of the art research by biogeochemists involved in the Baltic Sea carbon cycle research. This work presents both qualitative and quantitative descriptions of the main carbon flows in the Baltic Sea as well as their possible shifts induced by climatic and global change.

'The most incomprehensible thing about the world is that it is comprehensible.' ALBERT EINSTEIN, 1950 The tremendous progress of recent years in the field of isotopes in the earth sciences has proved invaluable in attempting to solve a varied spectrum of geological and geochemical problems. The lunar exploration programmes provided rocks for analysis, stimulating refinements in mass spectrometry which were later used for terrestrial samples too. Among significant advances was the development of electrostatic tandem accelerator mass spectrometers allowing the precise measure ment of abundances of cosmic radionuclides. Also, new geochronometers were devised, for instance those dependent upon the radioactive decay of samarium-I47 to neodymium-I43, lutetium-176 to hafnium-176, rhenium-I87 to osmium-I87 and potassium-40 to calcium40, these supplementing prior dating methods. Their impact as regards the origin of igneous rocks was considerable. Isotopic compositions of neodymium, strontium, lead and hafnium in these rocks showed that magmas from the mantle are often crustally contaminated. In addition, isotopic compositions of carbon, oxygen and sulphur aided the elucidation of aspects of petrogenesis. These and many other facets of the subject are discussed in this book."

This book is an outgrowth of my interest in the chemistry of sedimentary rocks. In teaching geochemistry, I realized that the best examples for many chemical processes are drawn from the study of ore deposits. Consequently, we initiated a course at The University of Cincinnati entitled "Sedimentary Ore Deposits," which serves as the final quarter course for both our sedimentary petrology and our ore deposits sequence, and this book is based on that teaching experience. Because of my orientation, the treatment given is perhaps more sedimentological than is usually found in books on ore deposits, but I hope that this proves to be an advantage. It will also be obvious that I have drawn heavily on the ideas and techniques of Robert Garrels. A number of people have helped with the creation of this book. I am especially grateful to my students and colleagues at Cincinnati and The Memorial University of Newfoundland for suffering through preliminary versions in my courses. I particularly thank Bill Jenks, Malcolm Annis, and Dave Strong. For help with field work I thank A. Hallam, R. Hiscott, J. Hudson, R. Kepferle, P. O'Kita, A. Robertson, C. Stone, and R. Stevens. I am also deeply indebted to Bob Stevens for many hours of insightful discussion.

Lessons in Environmental Microbiology provides an understanding of the microbial processes used in the environmental engineering and science fields. It examines both basic theory as well as the latest advancements in practical applications, including nutrient removal and recovery, methanogenesis, suspended growth bioreactors, and more. The information is presented in a very user-friendly manner; it is not assumed that readers are already experts in the field. It also offers a brief history of how microbiology relates to sanitary practice, and examines the lessons learned from the great epidemics of the past. Numerous worked example problems are presented in every chapter.

How large is the natural variation in concentration of the various elements in different media? How do the oft-cited "World average concentrations" in different media compare with actual analytical data? How low a detection limit do I need to attain if I want to analyse for an element in soils, sediments, water or plants? All these questions and many more can be answered by using this unique reference book. It collates data on the most important properties and uses of all naturally occurring chemical elements. It combines these with data obtained from actual analyses of different sample media (soil, stream sediment, stream water, ground water, plants, human body fluids). This combination of facts and actual data makes this book suitable for learning and teaching applied geochemistry as well.

The first edition of this book was published in 1965 and its French translation in 1966. The revised second edition followed in 1967 and its Russian translation became available in 1969. Since then, many new petrographic observations and experimental data elucidat- ing reactions in metamorphic rocks have made a new approach in the study of metamorphic transformation desirable and possible. It is felt that this new approach, attempted in this book, leads to a better unders- tanding of rock metamorphism. The concept of metamorphic facies and subfacies considers asso- ciations of mineral assemblages from diverse bulk compositions as characteristic of a certain pressure-temperature range. As new petrographic observations accumulated, it became increasingly difficult to accommodate this information within a manageable framework of metamorphic facies and subfacies. Instead, it turned out that mineral assemblages due to reactions in common rocks of a particular composi- tion provide suitable indicators of metamorphic conditions. Metamorphic zones, defined on the basis of mineral reactions, very effectively display the evolution of metamorphic rocks. Thus the im- portance of reactions in metamorphic rocks is emphasized. Experimen- tal calibration of mineral reactions makes it possible to distinguish reac- tions which are of petrogenetic significance from those which are not. This distinction provides guidance in petrographic investigations un- dertaken with the object of deducing the physical conditions of metamorphism.

During the last few years, carbonatites have received a considerable amount of attention. Some of this interest was no doubt kindled by the importance of volatiles in the Earth's mantle, particularly CO , by the fact that carbonatites 2 can be used to monitor the chemical evolution of the sub-continental upper mantle, and by the fact that carbonatites may be effective metasomatizing agents at both mantle and crustal levels. The interest in Oldoinyo Lengai has extended over at least 100 years, but it was not until the eruptions of 1960, when the unique carbonatitic nature of its lavas was recognized, that the volcano took on special significance in volcanology and igneous petrology. The recognition of carbonatitic flows coin cided with the first successful laboratory experiments carried out on carbonatitic melts. Since then, Oldoinyo Lengai has formed a cornerstone in all carbonatite discussions. It is probably true to say that the findings from Oldoinyo Lengai have dominated our ideas about carbonatites, in spite of the fact that the alkali rich, natrocarbonatitic lavas of Oldoinyo Lengai are markedly different from other carbonatites.

Chemical petrology is essentially the physical chemistry of rocks and associated fluids, although it also borrows heavily from such other sciences as mineralogy. In terms of fundamentals it is firmly grounded in chemical thermodynamics and kinetics. In its treatment of terrestrial environments it grades imperceptably into sedimentology, geochemistry, and geophysics and in extraterrestrial environments into cosmochemistry. It is one of the most important branches of planetology and meteoritics. The unity of approach of thermodynamics and kinetics to processes in these diverse environments is stressed in this book by numerous examples which have been chosen to illuminate different aspects of the subject. Thus we have discussed in some depth such problems as the genesis of layered basic complexes, calc-alkaline batholiths, chondri tic meteorites, and the surface-atmosphere interaction of the planet Venus because these are important and because they are particularly good illustrations of the chemical petrology approach. Considerable attention also has been devoted to volcanic processes. In our treatment of metamor phism in particular, an attempt has been made to correlate and integrate the vast number of recent experimental, theoretical, and field studies. However, we have not attempted a comprehensive survey of all known rock types or occurrences, nor did we review all the diverse opinions and conclusions on the origins of controversial rocks. Instead we have chosen to stress interpretations we regard as following most directly from the evidence."

Proceedings of the NATO Advanced Study Institute, Aussois, France, September 4-15, 1985

For the first time in human history, developments in many branches of science provide us with an opportunity of formula ting a comprehensive picture of the universe from its beginning to the present time. It is an awesome reflection that the carbon in our bodies is the very carbon which was generated during the birth of a star. There is a perceptible continuum through the billions of years which can be revealed by the study of chemistry. Studies in nucleosynthesis have related the origin of the elements to the life history of the stars. The chemical elements we find on earth, HYdrogen, Carbon, Oxygen, and Nitrogen, were created in astronomical processes that took place in the past, and these elements are not spread throughout space in the form of stars and galaxies. Radioastronomers have discovered a vast array of organic molecules in the interstellar medium which have a bearing on prebiological chemical processes. Many of the molecules found so far contain the four elements, C, N, 0, H. Except for the chem ically unreactive He, these four elements are the most abundant in the galaxy. The origin of polyatomic interstellar molecules is an unresolved problem. While we can explain the formation of some diatomic molecules as due to two atom collisions, it is much more difficult to form polyatomic molecules by collisions between diatomic molecules and atoms. There may be other produc tion mechanisms at work such as reactions taking place on the surface of interstellar dust grains."

This volume contains the lectures presented at the Advanced Study Institute on "New Trends in Coal Science" which was held at Datca, HUgla, Turkey during August 23 - September 4, 1987. The book includes 23 chapters which were originally written for the meeting by some of the world's foremost investigators. Chemists everywhere are carrying out exciting research that has important implications for the energy and fuels industries and for society in general. For the near future, coal resources will continue to be of great importance and science and technology of the highest order are needed to extend this fossil energy resource and to utilize it in an economical way that is also environmentally acceptable. These were the main purposes for the organization of this NATO ASI. The Institute constituted two working weeks on structure and reactivity of coal and so is the book. Through the presentation of many specific recent results on structure and characterization of coal and its products the potential of new instrumental techniques is presented in the first part of the book. Finally the reactivity of coals at different conditions both in laboratory and industry is discussed. We hope that the volume will be of great use to research workers from academic and industrial background. In addition it could serve as a textbook for a graduate course on coal science and technology.

The large and rapidly expanding body ofliterature related to nitrogen cycling in both managed and native terrestrial ecosystems reflects the importance accorded to the behaviour of this vital and often limiting nutrient. Research at the organism, ecosystem and landscape levels commonly addresses questions concerning nitrogen acquisition, internal cycling and retention. Goals for this research include increased agricultural productivity and a better understanding of human impact on local, regional and global nitrogen cycles. Nitrogen cycle research in tropical regions has a long and distinguished history. Research on different aspects of nitrogen cycling in ecosystems of the tropics has been carried out in many regions. In relatively few instances has there, however, been a focus on the biogeochemical cycles at the ecosystem level. The meeting resulting in this volume was an attempt to bring together existing information on nitrogen cycling in ecosystems of Latin America and the Caribbean and discuss this in an ecosystem context.

Hydraulic parameter identification is a crucial step in hydrogeological investigations. The book proposes a unique and generalized interpretation method for single and multiple pumping tests made in groundwater reservoirs with layered heterogeneity and with or without lateral anisotropy. This method eliminates the drawbacks of the numerous and frequently applied interpretation methods. The book also presents an introduction to inverse modeling, resulting in optimal parameter values with their joint confidence region and the corresponding residuals. Cross sections through this multidimensional region elucidate the relation between the shape of this region and some statistical parameters describing the reliability of the identified parameters. This method is demonstrated by means of five pumping or recharge tests.

MYRON J. MITCHELL* The biota of soils constitute an integral part of both natural and agronomic ecosystems. The soil microflora and fauna in conjunction with the belowground portion of the Metaphyta or higher plants constitute the living milieu, components of which are in intimate association with each other as well as the abiotic constituents of the soil. Since these associations or interactions are important in regulat ing both the flux and availability of energy and nutrients, the central theme of the present book focuses on these interactions. The effects of microfloral and faunal inter actions with regard to overall ecosystem dynamics and specific critical processes will be examined. HISTORICAL ASPECTS The coverage of this volume is an extension of a vast body of literature which dates back to the 18th century. A brief compendium of major books and reviews published from 1960 to 1983 is given chronologically in Tables 1 and 2, respectively. Russell (1961) has reviewed work in the 1800's during which some of the basic tenets on the relationships between plant nutrition and soil properties became estab lished. In this period agricultural science was founded and the study of soil bacteriology began. The evolution of soil biology up to the early 1970's has been described by Satch211 in the volume edited by Dickinson and Pugh (1974). *Department of Environmental and Forest Biology, SUNY, College of Environmental Science and Forestry, Syracuse, NY 13210 2 ~ .

Manganese nodules were first discovered on the ocean floor 160 miles south-west of the Canary Islands on February 18, 1803, during the first complex oceano logical cruise of the Challenger. They surprised researchers by their unusual shape and also by their unusual chemical composition; nevertheless for many years after wards, they were considered merely as one of Nature's exotic marine tricks. After the Secpnd World War, a comprehensive investigation of the World Ocean started, and new data were obtained on a wide distribution of manganese nodules and their polymetallic composition, that made scientists consider nodules as one of the major characteristics of the deep oceanic zone. Recently, meaning since the 1960's, nodules have been recognized as a potential ore source, investigation of which is stimulated by the progressive depletion of land-based mineral resources. Several generations of scientists from various countries have contributed to the problem of exploration of manganese nodules on the ocean floor. Though the problem has been posed, it has not been solved yet because it required, in its turn, a scrutiny of some fundamental aspects such as composition, nature, accretion r'ate of nodules and retrieval of nodule fields. These problems have been discussed in thousands of papers and larger publications; see, in particulare, Mero, 1965; Horn, 1972; Morgenstein, 1973; Bezrukov, 1976; Glasby, 1977; Bischoff and Piper, 1979; Lalou, 1979; Manganese nodules, 1979; Varentsov, 1980; Cronan, 1980; Manganese nodules . . ., 1984, 1986."

One of the basic concepts of ocean biogeochemistry is that of an ocean with extremely active boundary zones and separation boundaries of extensive biochemical interactions. The areas of these zones are characterized by a sharp decrease of element migration intensity and consequently the decrease in their concentrations gave the boundaries for the naming of the geochemical barriers (Perelman, 1972). For the purposes of biogeo chemistry the most important ones are the boundaries of separation between river-sea, ocean-atmosphere, and water-ground (Lisitzin, 1983). The most complicated of them is the river-sea boundary, where the biogeochemical processes are the most active and complicated (Monin and Romankevich, 1979, 1984). The necessity of studying organic matter in rivers, mouth regions and adjoining sea aquatories has been repeatedly pointed out by v.I. Vernadsky (1934, 1960) who noted both the importance of registration of solid and liquid run-off of rivers, coming into the sea, and "the quality and the character of those elements, which are washed-down into the sea", emphasizing that "wash-down of organic substances into the sea is of great value". The interest in studying organic matter in natural waters, including river and sea waters, has grown considerably over the last 30 years. During this period essential material was collected on the content and composition of organic matter in various types of river waters of the USSR, and this was published in papers by B.A Scopintzev, AD. Semenov, M.V.

This book represents the proceedings of the 9th written by a very active group of physicists at Kongsberg seminar, held at the Norwegian Mining the University of Oslo - physicists interested in Museum located in the city of Kongsberg about complex systems in general and geo-like systems 70 km Southwest of Oslo. The Kongsberg district in particular. is known for numerous Permian vein deposits of The content of the book is organized into three native silver, and mining activity in the area lasted major parts following the introductory chapter. for more than 300 years, finally ceasing in 1957. Chapters 2 to 7 primarily treat the role of fluids The previous eight Kongsberg seminars were in specific geological environments, ranging from focused on ore-forming processes and all of these sedimentary basins (Chapters 2-3) to contact were organized by Professor Arne Bj0rlykke, now metamorphic/hydrothermal scenarios (Chapters director of the Norwegian Geological Survey. 4-5) and regional metamorphic settings (Chapters Since process-orientated research tends to break 6-7). The following four chapters (8-11) focus down the traditional barriers between the different on various properties of fluid-rock systems that geological disciplines, this seminar has always are critical in controlling flow and transport been a meeting point for people with a variety through rocks. These include: mineral solubility of geological backgrounds.

Granulites are, by definition, rocks that crystallized at high temperatures. It is generally agreed that they were formed in regions where the geothermal gradient exceeded normal continental values. These rocks commonly display coronitic mineral fabrics which may be used to trace the thermal and geodynamic history of the continental crust. In the same way that eclogites provide information on the earliest stages of some orogenic episodes, granulites usually tell us about later events, including thermal anomalies, thermal reequilibration, CO streaming, crustal melting, and 2 differentiation of the continental crust. Their study is particularly important if we are to under stand the nature of the middle and lower continental crust. Consistent with the contributions I received, the contents of this volume fall into four general areas: Crustal Evolution, Regional Syntheses, F1uids and Petrological Equilibria, Geochemistry and Geophysics. These represent an up-to-date reflection of the centres of interest in the field of granulites. The first manuscripts arrived in September 1988 while the conference was held, the last contribution arrived in November 1989, more than a year later. I apologize to those who were prompt and took deadlines seriously, but I believe that it was worth waiting to secure a product covering most of the important aspects concerning granulite genesis. All papers were vetted by at least two reviewers. I would like to thank RJ. Arculus, N.T. Arndt, P. Barbey, SR. Bohlen, AM. Boullier, M. Brown, T. Chacko, 1.D. Clemens, K.C. Condie, J.C. Duchesne, C. Dupuy, w.G."

This book provides a detailed description of light absorption and absorbents in seawaters with respect to provenance, region of the sea, depth of the occurrence and trophicity. The text is based on a substantial body of contemporary research results taken from the subject literature (over 400 references) and the work of the authors over a period of 30 years.