This book presents contributions by experts from diverse disciplines, estimating the global levels of biogeogenic and anthropogenic emissions of organometal(loid) compounds, and thus presenting insight into processes which influence the genesis, as well as the distribution and stability of these species and their interaction with each other and other matrix compounds. The authors evaluate identify potential "hot spots" of organometal(loid)s, which can negatively influence ecosystems and human health.

Coalbed gas has been considered a hazard since the early 19th century when the first mine gas explosions occurred in the United States in 1810 and France in 1845. In eastern Australia methane-related mine disasters occurred late in the 19th century with hundreds of lives lost in New South Wales, and as recently as 1995 in Queensland's Bowen Basin. Ventilation and gas drainage technologies are now in practice. However, coalbed methane recently is becoming more recognized as a potential source of energy; rather than emitting this gas to the atmosphere during drainage of gassy mines it can be captured and utilized. Both economic and environmental concerns have sparked this impetus to capture coalbed methane. The number of methane utilization projects has increased in the United States in recent years as a result, to a large extent, of development in technology in methane recovery from coal seams. Between 1994 and 1997, the number of mines in Alabama, Colorado, Ohio, Pennsylvania, Virginia, and West Virginia recovering and utilizing methane increased from 1 0 to 17. The Environmental Protection Agency estimates that close to 49 billion cubic feet (Bet) of methane was recovered in 1996, meaning that this amount was not released into the atmosphere. It is estimated that in the same year total emissions of methane equaled 45. 7 Bcf. Other coal mines are being investigated at present, many ofwhich appear to be promising for the development of cost-effective gas recovery.

This book covers the basics of abiotic colloid characterization, of biocolloids and biofilms, the resulting transport phenomena and their engineering aspects. The contributors comprise an international group of leading specialists devoted to colloidal sciences. The contributions include theoretical considerations, results from model experiments, and field studies. The information provided here will benefit students and scientists interested in the analytical, chemical, microbiological, geological and hydrological aspects of material transport in aquatic systems and soils.

Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the geosciences. It is subdivided into three parts: theoretical and experimental principles; fractionation processes of light and heavy elements; the natural variations of geologically important reservoirs. Since the application of stable isotopes to earth sciences has grown in the last few years, a new edition appears necessary. Recent progress in analysing the rare isotopes of certain elements for instance allow the distinction between mass-dependent and mass-independent fractionations. Special emphasis has been given to the growing field of "heavy" elements. Many new references have been added, which will enable quick access to recent literature. For students and scientists alike the book will be a primary source of information with regard to how and where stable isotopes can be used to solve geological problems.

Contamination of the earth's ecosystems by potentially toxie metalsl metalloids is a global problem. It will likely grow with our planet's increasing populations and their requirements for natural resources (e. g. , water, food, energy, waste-disposal sites) and metals-based goods. The health impacts of pollution from the ingestion of heavy metals/metalloids via respiration, food, and drinking water are most often long-term and manifest themselves in many ways. These include, for example, disminution of mental acuity, loss of motor control, critieal organ dysfunction, cancer, chronie illnesses and con- comitant suffering, incapacitation, and finally death. The incidence and geographie distribution of disease (epidemiology) has been well-documented historieally and in modern times for toxic metals- triggered diseases in humans, animals and vegetation. The role of the environmental geochemist and colleagues in environ- mental sciences is to scientifically evaluate how to manage metalsl metalloids at sources or in-situ so as to alleviate or eliminate their negative health impacts on living populations. This is initiated by identifying sources and by developing models of the physieal, chem- ieal and biologieal controls on mobilization, interaction, deposition and accumulation of potentially toxie metals/metalloids in source systems and earth ecosystems. Prom this knowledge base, environ- mental scientists (e. g. , geologists, chemists, biologists, environmen- tal engineers, physicists/meteorologists) work together to develop Preface VI concepts and technologieal methodologies to preserve global eco- systems. Their concerted efforts are equally focussed on devising strategems to remediate ecosystems still carrying heavy metals/metal- loids pollutant burdens from ancient and modern societies.

Geochemical barrier zones play an important role in determining various physical systems and characteristics of the oceans, e.g. hydrodynamics, salinity, temperature and light. In this book, each of the 40 barrier zones covered are illustrated and defined by physical-chemical parameters. Among the topics discussed are the processes of inflow, transformation and precipitation of the sedimentary layer of the open oceans and more restricted areas such as the Baltic, Black and Mediterranean Seas. This well-illustrated book may serve as the basis for courses such as "Marine Geochemistry" or "Ocean Usage" and can be useful to researchers in the fields of geology, geography, marine chemistry, geoecology and hydrochemistry.

This book describes advances in this new, fast developing science, which seeks to decipher fundamental mechanisms ruling the behaviour in water, soils, atmosphere, food and living organisms of toxic metals, fossil fuels, pesticides and other organic pollutants. Sections on eco-toxicology, green chemistry, and analytical chemistry round out this thorough survey of conditions and analytical techniques in an emerging specialty.

The volume focuses on the ecological functioning of rivers, which has received less attention than functioning of lakes and reservoirs. The selected papers cover a large range of topics relating to aquatic communities, eutrophication, nutrient dynamics and organic pollution, erosion and sediment transport, and fate of micropollutants at the basin scale. Integrated approaches developed in order to study the ecological functioning of fluvial systems perturbed by human activity are presented. This functioning is analysed from the point of view of fundamental research, but insights into system management are not neglected. This book will be of interest to researchers in the field of aquatic ecology, river system functioning, and water surface pollution, to postgraduate students, to the institutions involved in water resource management, and to the drinking water and waste water treatment industries. It draws information from many large river systems in the world.

Rare Earth Elements in Groundwater Flow Systems is the first volume of its kind entirely focused on the geochemistry of the lanthanide series elements in groundwater/aquifer environments. Consisting of ten chapters, each of which is an original, peer-reviewed contribution by some of the leading researchers in the study of the low-temperature geochemistry of rare earth elements, the volume addresses analytical techniques, water-rock interactions, aqueous complexation, and the reactions/processes that influence these heavy metals along groundwater flow paths.

Mechanochemistry as a branch of solid state chemistry enquires into processes which proceed in solids due to the application of mechanical energy. This provides a thorough, up to date overview of mechanochemistry of solids and minerals. Applications of mechanochemistry in nanoscience with special impact on nanogeoscience are described. Selected advanced identification methods, most frequently applied in nanoscience, are described as well as the advantage of mechanochemical approach in minerals engineering. Examples of industrial applications are given. Mechanochemical technology is being applied in many industrial fields: powder metallurgy (synthesis of nanometals, alloys and nanocompounds), building industry (activation of cements), chemical industry (solid waste treatment, catalyst synthesis, coal ashes utilization), minerals engineering (ore enrichment, enhancement of processes of extractive metallurgy), agriculture industry (solubility increase of fertilizers), and pharmaceutical industry (improvement of solubility and bioavailability of drugs).

This reference serves as an introduction to newcomers to mechanochemistry, and encourages more experienced researchers to broaden their knowledge and discover novel applications in the field.

This book focuses on sediments as a pollutant in natural freshwater and marine habitats, and as a vector for the transfer of chemicals such as nutrients and contaminants. Sediment-water research is carried out all over the world within a variety of disciplines. The selected papers cover three main topics:
-assessment and/or restoration of disturbed watersheds
-sediment-water linkages in terrestrial and aquatic environments
-evaluation of sediment and ecological changes in marine and freshwater habitats.

Innovative research in both developed and less developed countries is included and both fundamental research and insight into applied research and system management are covered.

This book will be of interest to graduate students, researchers, catchment managers and government regulators working within many areas of education, protection and management of the environment, including sediment geochemistry and dynamics, aquatic habitats, water quality, aquatic ecology, river morphology, restoration techniques and catchment management.

This book reviews current ideas explaining the formation of granite in terms of melting, segregation, ascent and emplacement. It introduces an alternative hypothesis that granites are endogenic in that they essentially form and remain at melting sites in the middle upper crust under conditions of abnormally high heat flow. The book highlights results of Chinese research over the last 30 years in English for the first time.

The Legacy of Carbon Dioxide: Past and Present Impacts covers the truly varied roles carbon dioxide has played and continues to play in the character of our planet. Chapters address the synthesis of CO2 in stars, the evolution of the atmosphere over billions of years, the chemical and physical properties of CO2 and how those influence common phenomena. How well this knowledge is understood and how it was determined, including existing uncertainties in our confidence and the stress from competing possibilities are discussed. Much of the technological jargon in various incorporated sciences has been modified to ease consumption by the non-expert. Features: Provides a historical panorama on how much the world has changed over the eons and the vast influence of carbon dioxide in these changes Follows CO2 through acidic explosive waters, volcanic episodes, sequestered reservoirs, and the chemistry of life Examines the broad scope of chemical and physical attributes carbon dioxide is capable of and their impacts Much of the technological verbiage in various incorporated sciences has been modified to ease consumption by the non-expert. This book is a valuable resource for readers interested in the science of carbon dioxide as well as natural science, the environment, scientific methods, chemistry, and geological sciences.

Extreme weather and climate change aggravate the frequency and magnitude of disasters. Facing atypical and more severe events, existing early warning and response systems become inadequate both in scale and scope. Earth Observation (EO) provides today information at global, regional and even basin scales related to agrometeorological hazards. This book focuses on drought, flood, frost, landslides, and storms/cyclones and covers different applications of EO data used from prediction to mapping damages as well as recovery for each category. It explains the added value of EO technology in comparison with conventional techniques applied today through many case studies.

The current scenario provides an ideal opportunity to confer higher priority to the marine resources of the Indian Ocean, particularly in terms of integrated management of the deep sea, shallow sea and coastal resources. This will maximize their potential in the sustainable development goal (SDG) pattern, leading to an appropriate environmental management. Therefore, this book aims to provide an overview of the area and to highlight the potential market opportunities represented by this vast and rapidly developing nation. In doing so the following aspects have been covered: Exclusive title focussing on mineral resources of Indian ocean. Discusses living, nonliving, ocean waves and tidal energy, ocean environment and protection aspects. Includes information on key themes, details of organizations associated with the Indian Ocean. Illustrates deep sea mining technology and environmental perspectives. Covers hydrocarbons-sub sea oil and gas, minerals from placer deposits to deep sea nodules, sea floor massive sulphides and cobalt rich encrustations.

Dramatic advances in understanding global tectonics have been made in the last half century and the information and specific data acquired on the floor of the World Ocean by the scientific community probably has exc- ded that available in all previous time. With the benefit of new technology and advanced concepts in the earth sciences extensive exploration of the deep seabed became possible, and has been carried out in many parts of the world. Many features have been recognized and data recorded that are vital for understanding the fundamental processes that shape the earth=s surface and control the habitable environment. The data collected to date on the o- an floor and its physical environment greatly exceeds our understanding and appreciation of their fundamental importance in the earth sciences, and our ability to apply this knowledge effectively in improving our way of life. With his extensive scientific knowledge and unique experience from - ny cruises in association with scientists throughout the world, Dr. Evgeny Gurvich has made an outstanding contribution in acquiring basic data on hydrothermal and sedimentation processes in the ocean, as well as in the synthesis of data and concepts available from cruise reports and an extensive literature.

Introducing the essentials of modern geochemistry for students across the Earth and environmental sciences, this new edition emphasises the general principles of this central discipline. Focusing on inorganic chemistry, Francis Albarede's refreshing approach is brought to topics that range from measuring geological time to the understanding of climate change. The author leads the student through the necessary mathematics to understand the quantitative aspects of the subject in an easily understandable manner. The early chapters cover the principles and methods of physics and chemistry that underlie geochemistry, to build the students' understanding of concepts such as isotopes, fractionation, and mixing. These are then applied across many of the environments on Earth, including the solid Earth, rivers, and climate, and then extended to processes on other planets. Three new chapters have been added - on stable isotopes, biogeochemistry, and environmental geochemistry. End-of-chapter student exercises, with solutions available online, are also included.

When Darwin wrote his Origin of Species, one of his main concerns was with the perceived shortness of the fossil record of life. Until the work of J. William Schopf and his colleagues, much of this history was thought to be unknowable. This book, through a memoire of Schopf's personal recollections, documents astonishing discoveries revealing the first 85% of the history of life. These earliest periods of life on Earth emerge as a tale of individual and internationally collaborative exploration told by a scholar whose 60 years of research contributed to the recognition of the richness and diversity which forms the foundation of today's biodiversity. Key Features Documents, through personal narrative, a paradigm shift is the study of the earliest life Summarizes a fossil record largely unknown until relatively recently Addresses one of Darwin's most troubling concerns about his theory of natural selection Predicts future developments in the study of first life

The first part of this book reviews the basics of atmospheric chemistry, radiation transport, and optical spectroscopy before detailing the principles underlying DOAS. The second part describes the design and application of DOAS instruments as well as the evaluation and interpretation of spectra. The recent expansion of DOAS application to the imaging of trace gas distributions by ground, aircraft, and satellite-based instruments is also covered.

Magnesium is one of the most abundant minerals in seawater. Extracting magnesium from seawater could reduce cost of this mineral, resulting in positive implications for industries that use it. This book addresses mineral process engineering with emphasis on magnesium and provides practicing engineers and students with comprehensive knowledge on magnesium and how it is extracted from seawater and magnesium ores. It takes a chemical engineering approach as separation of magnesium from seawater involves the application of the powerful science of chemistry and transport phenomena principles. This monograph discusses magnesium resources and occurrence, includes an exploration study on deriving magnesium and mineral salts from seawater, and features coverage of magnesium chloride. It also covers commercial methods for magnesium production as an end product, current and prospective applications in the energy domain, and offers an account of the use of magnesium to store hydrogen in the form of magnesium hydride.

This book is the first systematic treatise of available data and view-points obtained from geological and geochemical studies of the Mo deposits in Qinling Orogen, China. Qinling Orogen has a minimum reserve of 8.7 Mt Mo, ranking the largest molybdenum province both in China and the world. Incorporating all known Mo deposit types in the world, it presents extensive studies of Mo deposits of world-class and unusual types within tectonic settings. The Qinling Orogen was finally formed during continental collision between Yangtze and North China cratons, following the Triassic closure of the northernmost paleo-Tethys. It hosts 49 Mo deposits formed in seven mineralization events since 1850 Ma, with all the world-class deposits being formed during 160-105 Ma, coeval with collisional orogeny. These deposits are assigned to magmatic and metamorphic hydrothermal classes. The magmatic hydrothermal class includes porphyries, skarns, and intrusion-related veins (carbonatite, fluorite and quartz). The porphyry Mo systems in Qinling Orogen are predominated by Dabie-type formed in continental collision setting, followed by Endako- and Climax-types formed in continental arcs and rifts, respectively. The metamorphic hydrothermal Mo deposits are only reported in Qinling Orogen, and thus a new crustal continuum model for the orogenic class mineral systems is proposed. A scientific linkage between ore geology and fluid inclusions is introduced and verified both by theory and case studies. This is the first research book comprehensively displaying continental collision metallogeny. This literature will benefit both Western and Chinese mineral explorers and miners, as well as research scientists and students.

1. PURPOSE OF PRESENT BOOK During the period May 19-26, 2003 the NATO Advanced Research Workshop (ARW) "Mud volcanism, Geodynamics and Seismicity" was held in Baku. Participants coming from USA, Germany, France, Italy, Portugal, Russian Federation, Ukraine, Romania, Georgia, UK, Israel, Azerbaijan, Tunisia have discussed about different geodynamic features of mud volcanism and participated to field trips oriented to a better knowledge of mud volcanic features. The Meeting focused on many features of mud volcanism occurrence and related geodynamic topics. The purpose of present book is to collect contributions discussed during the Meeting and to fill a marked editorial gap on mud volcanism. Mud volcanism was to date described by local monographies or by articles published by scientific journals. In particular no books were published on topics able to highlight the link among mud volcanism, geodynamics and seismicity. Mud volcano of Nirano (Northern Italy). Engraving from Stoppani A. (1871), Corso di Geologia, Milan, Bernardoni G. and Brigola G. Publishers. 2. WHY MUD VOLCANOES ARE GEOLOGICALLY IMPORTANT ? Mud volcanoes have attracted the attention of earth scientists for many years. Due to their importance in hydrocarbon research, a consistent progress in the knowledge of mud volcanism took place in the past twenty years. Mud extrusion is a well-known phenomenon occurring in geological environments where fluid-rich, fine grained sediments ascend within a lithologic succession due to their buoyancy.

Modern Biogeochemistry is aimed to generalize modern ideas of biogeochemical developments during the last decades. It is designed to support a general course in biogeochemistry, and as such, is likely to have a broad market among the many universities and colleges that are adding such courses to their curricula. This book aims to supplement the existing textbooks by providing modern understanding of biogeochemistry, from evolutionary biogeochemistry to practical applications of biogeochemical ideas such as human biogeochemistry, biogeochemical standards and biogeochemical technologies.
To a certain extent this textbook is a summary of both scientific results of various authors and classes in biogeochemistry, that have been given to students by authors during the last 5 to 10 years at different universities throughout the world such as Cornell, Moscow, Seoul and Bangkok. Biogeochemistry is becoming an increasingly popular subject for graduate and postgraduate education. Courses in ecology, geography, biology, chemistry, environmental science, public health and environmental engineering all tend to have a biogeochemical component in their syllabuses to a greater or lesser extent.

courses more petrogenesis-orientated are im My main objective in writing this book has been to mediately confronted with a basic problem; the review the processes involved in present-day mag ma generation and their relationship to global average student does not have a strong enough tectonic processes. Clearly, these are fundamental background in geochemistry to understand the to our understanding of the petrogenesis of ancient finer points of most of the relevant publications in volcanic and plutonic sequences, the original tec scientific journals. It is virtually impossible to fmd tonic setting of which may have been obscured by suitable reading material for such students, as most subsequent deformation and metamorphism. authors of igneous petrology textbooks have de Until fairly recently, undergraduate courses in liberately steered clear of potentially controversial igneous petrology tended to follow rather classical petrogenetic models. Even the most recent texts lines, based on the classification of igneous rocks, place very little emphasis on the geochemistry of descriptive petrography, volcanic landforms, types magmas erupted in different tectonic settings, of igneous intrusions and regional petrology . despite extensive discussions of the processes re However, the geologist of the late 1980s requires, in sponsible for the chemical diversity of magmas.

The book presents a new and comprehensive model for the development of phosphate sediments. Starting with geochemistry and including new methods in sedimentology (sequence stratigraphy), it results in an interdisciplinary approach to a resource system covering all fields of phosphate geology. For researchers, teachers and students alike the book offers a complete overview of the whole field including case studies of major deposits.