Studies of prehistoric exchange of goods provide information about the types of economic interaction, social organization, or political structures in which prehistoric peoples were engaged. Long-distance exchange is a special situation where the materials exchanged crossed significant boundaries, whether they were geographic, social, political, or otherwise. By examining the types and quantities of goods exchanged, along with the directions and distances they moved, archaeologists are able to examine the dynamic properties of exchange systems, i.e., how they operate and why they undergo change.

The purpose of this volume is to present a number of case studies of long-distance exchange from around the world which demonstrate the use of geochemical analysis of artifacts to find evidence of exchange. More important than the use of analytical technique employed or the types of artifacts studied are the interpretations themselves which illustrate that exchange studies are maturing and helping archaeologists to develop more accurate models of exchange.

Noble Gas Geochemistry gives a comprehensive description of the physical chemistry and cosmochemistry of noble gases, before leading on to applications for problem-solving in the earth and planetary sciences. There have been many developments in the use of the noble gases since publication of the first edition of this book in 1983. This second edition has been fully revised and updated. The book will be invaluable to graduate students and researchers in the earth and planetary sciences who use noble gas geochemistry techniques.

The Biogeochemistry of the Amazon Basin synthesizes more than a decade of process-level research into the flows of water, carbon, nutrients and other bioactive elements through Amazon terrestrial and aquatic ecosystems. Emphasis is placed on the unique combinations of physical and biogeochemical conditions that support sustainable development of the region.

There is much scientific interest in ice, both because of its unique and intriguing properties and because of its importance in the natural environment. This book is written for professional scientists and engineers, and is the only currently available book of its kind. It describes the physical properties of ice, interprets them in terms of its molecular structure, and shows their relevance to the forms of ice found on Earth and in space.

Adsorption of Metals by Geomedia, serves as a needed resource for this topic which has received much attention during the past 15 years. The book provides an in-depth review of the field, followed by numerouschapters that document the current status of adsorption research for a variety of metals by geomedia ranging from individual minerals to sediments and soils. Adsorption mechanisms are detailed and precipitation is presented as a distinct sorption process.Virtually all factors affecting the extent of metal adsorption are examined, including the effects of selected anions, competition among metals, pH, metal concentration, loading, variable metal adsorption capacity, ionic strength, hydrogen exchange and stoichiometry, and solids concentration. A variety of adsorption models are briefly presented and some are used to extend laboratory studies to field sites. The book is comprised of a collection of papers contributed by leading investigators from Canada, France, the Netherlands, the United Kingdom and the US.

* Includes a wide-ranging review of the status of adsorption research and a prospectus on
future research
* Details all known factors affecting the extent of adsorption
* Covers basic adsorption equations and interrelationships
* Clearly documents experimental procedures
* Presents adsorption data for eleven metals and three other elements
* Uses normalization to greatly reduce apparent variability among absorbents
* Provides extensive literature citations and a comprehensive index

This is the seventh edition of a book which has been for years the 'bible' of professional and amateur gemmologists, as well as retail jewellers. Originally written by Robert Webster, an expert who dedicated most of his life to the subject and who worked in the London Gem Testing Laboratory for twenty-five years, this edition has been completely revised and updated by E. Alan Jobbins, Keeper of Minerals and Gemstones at the Geological Museum in London for thirty-five years. The first part of the book is a comprehensive glossary on all aspects of gemstones and the terms associated with them. The second part includes sections on manufactured gems, the enhancement of gem materials and on the precautions necessary for avoiding damage to gemstones and jewellery during manufacturing, repairs and cleaning. There are comprehensive sets of tables of the physical constraints needed for gem testing, of the sources of gem materials and the cuts used to demonstrate their beauty. Fifteen pages of colour photographs will assist in the identification of inclusions and there are many useful conversion tables. Acknowledged as one of the most useful reference books available, this should be the vade mecum of all gemmologists.

Fossil hydrocarbons form a continuous series whose"heavy"members--heavy oils, bitumens, oil shale kerogens, and coal--are important sources of conventional lighter fuels. These hydrocarbons are much more abundant and easier to extract than natural gas and oil. This book discusses the origins and compositions of fossil hydrocarbons and shows how the"heavies"can be chemically transformed into environmentally clean gas, liquid transportation fuels, and an almost unlimited range of petrochemicals.
Dr. Berkowitz explodes the entrenched dichotomy between"petroleum hydrocarbons"and coal that has shaped popular perceptions of energy, showing that it is feasible to develop new technologies that capitalize on the availability of"synthetic"natural gas and light oils.
Fossil Hydrocarbons: Chemistry and Technology is a comprehensive treatment of fossil hydrocarbons, covering the source materials, biosources, metamorphic histories, geochemistry, classification, and molecular structure. It discusses the use of fossil hydrocarbons as a viable energy source in our future, detailing the preparation, processing and conversion technologies, as well as discussing the environmental issues that arise from production, processing, and use of various fossil hydrocarbons.
Key Features
* Approaches various fossil hydrocarbons as chemically related entities, thus dispelling the unwarranted distinctions between crude oils and coal
* Explains how heavy fossil hydrocarbons can be processed by much the same methods as crude oils for good economic and environmental purpose
* Illustrates how bitumens, oil shales, and coals are convertible into synthetic natural gas and oils
* Shows a path for reasonable energy self-sufficiency, through conversion of heavy hydrocarbons into synthetic natural gas and oils
* Augments each chapter with end-of-chapter notes and a detailed bibliography
* Provides more than 200 useful tables, schematics, and figures

What happens to a chemical once it enters the natural environment? How do its physical and chemical properties influence its transport, persistence, and partitioning in the biosphere? How do natural forces influence its distribution? How are the answers to these questions useful in making toxicological and epidemiological forecasts?

Environmental Chemodynamics, Second Edition introduces readers to the concepts, tools, and techniques currently used to answer these and other critical questions about the fate and transport of chemicals in the natural environment. Like its critically acclaimed predecessor, its main focus is on the mechanisms and rates of movement of chemicals across the air/soil, soil/water, and water/air interfaces, and on how natural processes work to mobilize chemicals near and across interfaces—information vital to performing human and ecological risk assessments.

Also consistent with the first edition, Environmental Chemodynamics, Second Edition is organized to accommodate readers of every level of experience. The first section is devoted to theoretical underpinnings and includes discussions of mass balance, thermodynamics, transport science concepts, and more. The second section concentrates on practical aspects, including the movement between bed-sediment and water, movement between soil and air, and intraphase chemical behavior.

This revised and updated edition of Louis J. Thibodeaux's 1979 classic features new or expanded coverage of:

• Equilibrium models for environmental compartments
• Dry deposition of particles and vapors onto water and soil surfaces
• Chemical profiles in rivers and estuaries, particles and porous media
• Fate and transport in the atmospheric boundary layer and within subterranean media
• Chemical exchange between water column and bed-sediment
• Intraphase chemical transport and fate

This Second Edition of Environmental Chemodynamics also includes twice as many references and 50% more exercises and practice problems.

This book is the first to detail the chemical changes that occur in deforming materials subjected to unequal compressions. While thermodynamics provides, at the macroscopic level, an excellent means of understanding and predicting the behavior of materials in equilibrium and non-equilibrium states, much less is understood about nonhydrostatic stress and interdiffusion at the chemical level. Little is known, for example, about the chemistry of a state resulting from a cylinder of deforming material being more strongly compressed along its length than radially, a state of non-equilibrium that remains no matter how ideal the cylinder's condition in other respects. M. Brian Bayly here provides the outline of a comprehensive approach to gaining a simplified and unified understanding of such phenomena. The author's perspective differs from those commonly found in the technical literature in that he emphasizes two little-used equations that allow for a description and clarification of viscous deformation at the chemical level. Written at a level that will be accessible to many non-specialists, this book requires only a fundamental understanding of elementary mathematics, the nonhydrostatic stress state, and chemical potential. Geochemists, petrologists, structural geologists, and materials scientists will find Chemical Change in Deforming Materials interesting and useful.

This text outlines the fundamentals required to understand the science of thermodynamics and provides a comprehensive and balanced coverage of the application of thermodynamics in geochemistry.

This work is based on the observation that further major advances in geochemistry, particularly in understanding the rules that govern the ways in which elements come together to form minerals and rocks, will require the application of the theories of quantum mechanics. The book therefore outlines this theoretical background and discusses the models used to describe bonding in geochemical systems. It is the first book to describe and critically review the application of quantum mechanical theories to minerals and geochemical systems. The book consolidates valuable findings from chemistry and materials science as well as mineralogy and geochemistry, and the presentation has relevance to professionals in a wide range of disciplines. Experimental techniques are surveyed, but the emphasis is on applying theoretical tools to various groups of minerals: the oxides, silicates, carbonates, borates, and sulfides. Other topics dealt with in depth include structure, stereochemistry, bond strengths and stabilities of minerals, various physical properties, and the overall geochemical distribution of the elements.

The dynamic, evolving Earth, and the mathematical representation of its geochemical changes are the subject of this timely, helpful handbook. Global warming, changes in the ocean, and the effects of fossil fuel combustion are just a few of the phenomena that make the development of geochemical models critical. But what computational methods will help to accurately carry out this task? This new text teaches the methodology of computational simulation of environmental change. The author presents interesting applications of his methods to describe the response of the ocean and atmosphere to the infusion of pollutants, the effect of evaporation on seawater composition, climate change, and many other aspects of the Earth's evolving ecosystem. He also presents simple approaches for solving non-linear systems, calculating isotope ratios, and dealing with chains of identical reservoirs. With creative programs that can be executed on any personal computer, Walker offers earth scientists the techniques necessary to address the key problems in their field.

First published in 1988 this textbook on crystal chemistry covers the basic principles of crystal chemistry and physics and crystallography and introduces the concept of crystal refractivity. The book begins with a discussion of atoms and atomic structure and moves from there to atomic bonding. Throughout this discussion, special emphasis is given to Pauling's rules. The author then treats crystal symmetry, crystal field theory, polyhedral structure and atomic packing. He concludes by introducing the student to more sophisticated optical properties of minerals, refractivity and polarisability in crystals. The material covered is sufficiently basic so that the book will be suitable for undergraduate and graduate student in advanced mineralogy courses. It will also be of interest to individuals, including mineralogists, materials scientists, crystallographers and inorganic chemists who are engaged in academic and industrial research dealing with the structure of the solid state.

This textbook describes the physics of the plastic deformation of solids at high temperatures. It is directed at geologists or geophysicists interested in the high-temperature behaviour of crystals who wish to become acquainted with the methods of materials science in so far as they are useful to earth scientists. It explains the most important models and recent experimental results without losing the reader in the primary literature of materials science. In turn the book deals with the essential solid-state physics; thermodynamics and hydrostatics of creep; creep models and their applications in the geological sciences; diffusion creep; superplastic deformation and deformation enhanced by phase transformations. Five concluding chapters give experimental results for metals, ceramics and minerals. There are extensive bibliographies to aid further study.

This new edition of the classic textbook presents a large number of diagrams showing the stability relations among minerals and groups of minerals found in metamorphic rocks. The diagrams help to determine the pressure and temperature conditions under which a given set of metamorphic rocks may have formed. Other parameters that control metamorphic mineral assemblages are also discussed and pitfalls resulting from simplifications and generalizations are highlighted. The book discusses the most common metamorphic rock types, their nomenclature, structure and graphical representation of their mineral assemblages. Part I defines basic principles of metamorphism, introduces metamorphic processes, geologic thermometry and barometry and defines metamorphic grade. Part II presents in a systematic way mineralogical changes and assemblages found in the most common types of metamorphic rocks. The computation of diagrams is based on recent advances in quantitative petrology and geochemistry. An extensive bibliography, including the key contributions and classic papers in the field, make it an invaluable source book for graduate students and professional geologists.

First published in 1957, this classic study has been reissued in a paperback version that includes an additional chapter bringing the material up to date. The author formulates the physical properties of crystals systematically in tensor notation, presenting tensor properties in terms of their common mathematical basis and the thermodynamic relations between them. The mathematical groundwork is laid in a discussion of tensors of the first and second ranks. Tensors of higher ranks and matrix methods are then introduced as natural developments of the theory. A similar pattern is followed in discussing thermodynamic and optical aspects.

This open access book summarizes the results of the collaborative project "GeomInt: Geomechanical integrity of host and barrier rocks - experiment, modeling and analysis of discontinuities" within the Program: Geo Research for Sustainability (GEO: N) of the Federal Ministry of Education and Research (BMBF). The use of geosystems as a source of resources, a storage space, for installing underground municipal or traffic infrastructure has become much more intensive and diverse in recent years. Increasing utilization of the geological environment requires careful analyses of the rock-fluid systems as well as assessments of the feasibility, efficiency and environmental impacts of the technologies under consideration. The establishment of safe, economic and ecological operation of underground geosystems requires a comprehensive understanding of the physical, (geo)chemical and microbiological processes on all relevant time and length scales. This understanding can only be deepened on the basis of intensive laboratory and in-situ experiments in conjunction with reliable studies on the modeling and simulation (numerical experiments) of the corresponding multi-physical/chemical processes. The present work provides a unique handbook for experimentalists, modelers, analysts and even decision makers concerning the characterization of various types of host rocks (salt, clay, crystalline formations) for various geotechnical applications.

Shipping is responsible for transporting 90% of the world's trade. This book provides a comprehensive review of the impact shipping has on the environment. Topics covered include pollutant discharges such as atmospheric emissions, oil, chemical waste, sewage and biocides; as well as non-pollutant impacts including invasive species, wildlife collisions, noise, physical damage, and the environmental effects associated with shipwrecks and shipbreaking. The history of relevant international legislation is also covered. With chapters written by eminent international authors, this book provides a global perspective on the environmental impact of ships, making it a useful reference for advanced students and researchers of environmental science, as well as practitioners of maritime law and policy, and marine business.

Geochemical Modeling for Mine Site Characterization and Remediation is the fourth of six volumes in the Management Technologies for Metal Mining Influenced Water series about technologies for management of metal mine and metallurgical process drainage. This handbook describes the important components of hydrogeochemical modeling for mine environments, primarily those mines where sulfi de minerals are present-metal mines and coal mines. It provides general guidelines on the strengths and limitations of geochemical modeling and an overview of its application to the hydrogeochemistry of both unmined mineralized sites and those contaminated from mineral extraction and mineral processing. The handbook includes an overview of the models behind the codes, explains vital geochemical computations, describes several modeling processes, provides a compilation of codes, and gives examples of their application, including both successes and failures. Hydrologic modeling is also included because mining contaminants most often migrate by surface water and groundwater transport, and contaminant concentrations are a function of water residence time as well as pathways. This is an indispensable resource for mine planners and engineers, environmental managers, land managers, consultants, researchers, government regulators, nongovernmental organizations, students, stakeholders, and anyone with an interest in mining influenced water. The other handbooks in the series are Basics of Metal Mining Influenced Water; Mitigation of Metal Mining Influenced Water; Mine Pit Lakes: Characteristics, Predictive Modeling, and Sustainability; Techniques for Predicting Metal Mining Influenced Water; and Sampling and Monitoring for the Mine Life Cycle.

Imagine a statistics book for bioassays written by a statistician. Next, imagine a statistics book for bioassays written for a layman. Bioassays with Arthropods, Third Edition offers the best of both worlds by translating the terse, precise language of the statistician into language used by the laboratory scientist. The book explains the statistical basis and analysis for each kind of quantal response bioassay in just the right amount of detail. The first two editions were a great reference for designing, conducting, and interpreting bioassays: this completely revised and updated third edition will also train the laboratory scientist to be an expert in estimation of dose response curves. New in the Third Edition: Introduces four new Windows and Apple-based computer programs (PoloJR, OptiDose, PoloMixture and PoloMulti) for the analyses of binary and multiple response analyses, respectively Replaces out-of-date GLIM examples with R program samples Includes a new chapter, Population Toxicology, and takes a systems approach to bioassays Expands the coverage of invasive species and quarantine statistics Building on the foundation set by the much-cited first two editions, the authors clearly delineate applications and ideas that are exceptionally challenging for those not already familiar with their use. They lead you through the methods with such ease and organization, that you suddenly find yourself readily able to apply concepts that you never thought you would understand. To order the PoloSuite computer software described in Bioassays with Arthropods, Third Edition, use the order form found at www.leora-software.com or contact the LeOra Software Company at [email protected].

This book aims to give an overview on the present state of volcanic lake research, covering topics such as volcano monitoring, the chemistry, dynamics and degassing of acidic crater lakes, mass-energy-chemical-isotopic balance approaches, limnology and degassing of Nyos-type lakes, the impact on the human and natural environment, the eruption products and impact of crater lake breaching eruptions, numerical modeling of gas clouds and lake eruptions, thermo-hydro-mechanical and deformation modeling, CO2 fluxes from lakes, volcanic lakes observed from space, biological activity, continuous monitoring techniques, and some aspects more. We hope to offer an updated manual on volcanic lake research, providing classic research methods, and point towards a more high-tech approach of future volcanic lake research and continuous monitoring.

Large igneous provinces (LIPs) are intraplate magmatic events, involving volumes of mainly mafic magma upwards of 100,000 km3, and often above 1 million km3. They are linked to continental break-up, global environmental catastrophes, regional uplift and a variety of ore deposit types. In this up-to-date, fascinating book, leading expert Richard E. Ernst explores all aspects of LIPs, beginning by introducing their definition and essential characteristics. Topics covered include continental and oceanic LIPs; their origins, structures, and geochemistry; geological and environmental effects; association with silicic, carbonatite and kimberlite magmatism; and analogues of LIPs in the Archean, and on other planets. The book concludes with an assessment of LIPs' influence on natural resources such as mineral deposits, petroleum and aquifers. This is a one-stop resource for researchers and graduate students in a wide range of disciplines, including tectonics, igneous petrology, geochemistry, geophysics, Earth history, and planetary geology, and for mining industry professionals.

The Evolution of Matter explains how all matter in the Universe developed following the Big Bang and through subsequent stellar processes. It describes the evolution of interstellar matter and its differentiation during the accretion of the planets and the history of the Earth. Unlike many books on geochemistry, this volume follows the chemical history of matter from the very beginning to the present, demonstrating connections in space and time. It provides also solid links from cosmochemistry to the geochemistry of Earth. The book presents comprehensive descriptions of the various isotope systematics and fractionation processes occurring naturally in the Universe, using simple equations and helpful tables of data. With a glossary of terms and over 900 references, this volume is a valuable reference for researchers and advanced students studying the chemical evolution of the Earth, the Solar System and the wider Universe.

The congress "Arsenic in the Environment" offers an international, multi- and interdisciplinary discussion platform for arsenic research aimed at short-term solutions of problems with considerable social impact, rather than only focusing on cutting edge and breakthrough research in physical, chemical, toxicological, medical and other specific issues on arsenic on a broader environmental realm. The congress "Arsenic in the Environment" was first organized in Mexico City (As 2006 ) followed by As 2008 in Valencia, Spain. The Third International Congress As 2010 was held in Tainan, Taiwan from May 17-21, 2010 entitled: "Arsenic in Geosphere and Human Diseases". The session topics comprised: 1. Geology + hydrogeology of arsenic; 2. Ecological effects: Arsenic in soils, plants and food chain; 3. Marine + terrestrial biota; 4. Health effects on humans: Epidemiology + biomarkers; 5. Toxicological effects; 6. Assessment and remediation; 7. Analytical methods. Hosting this congress in Taiwan was especially relevant, because the endemic Blackfoot Disease, related to the arsenic uptake from drinking water supplied by artesian wells, was discovered here half a century ago. Since then Taiwan has become an important region specializing in arsenic research. This volume presents the extended abstracts of the congress and will give the latest state of the art knowledge based on current research performed by the global scientific community.