In this updated and expanded second edition, new literature has been added on contaminant fate in the soil-subsurface environment. In particular, more data on the behavior of inorganic contaminants and on engineered nanomaterials were included, the latter comprising a group of “emerging contaminants� that may reach the soil and subsurface zones. New chapters are devoted to a new perspective of contaminant geochemistry, namely irreversible changes in pristine land and subsurface systems following chemical contamination. Two chapters were added on this topic, focusing attention on the impact of chemical contaminants on the matrix and properties of both liquid and solid phases of soil and subsurface domains. Contaminant impacts on irreversible changes occurring in groundwater are discussed and their irreversible changes on the porous medium solid phase are surveyed. In contrast to the geological time scale controlling natural changes of porous media liquid and solid phases, the time scale associated with chemical pollutant induced changes is far shorter and extends over a “human lifetime scale�.

Understandable by anyone concerned with crystals or solid state properties dependent on structure Presents a general system using simple notation to reveal similarities and differences among crystal structures More than 300 selected and prepared figures illustrate structures found in thousands of compounds

This book provides an introductory understanding of fluvial geomorphic principles and how these principles can be integrated with geochemical data to cost-effectively characterize, assess and remediate contaminated rivers. The book stresses the importance of needing to understand both geomorphic and geochemical processes. Thus, the overall presentation is first an analysis of physical and chemical processes and, second, a discussion of how an understanding of these processes can be applied to specific aspects of site assessment and remediation. Such analyses provide the basis for a realistic prediction of the kinds of environmental responses that might be expected, for example, during future changes in climate or land-use.

There have been numerous computer-based simulation studies carried out on the subject of CO2 geo-sequestration. However, the amount of experimental data available in the literature on this topic, especially with regards to multiphase flow characteristics of fluid-rock systems during such processes, is very limited. This research was carried out with the aim of providing a better understanding of the multiphase fluid flow characteristics of fluid-rock systems during the geo-sequestration process. The ultimate goal of this research was to experimentally evaluate the change in a number of multiphase flow characteristics of the system over time caused by the potential chemical and physical/mechanical processes occurring during deep CO2 disposal. In order to achieve this goal the effects of cyclic/alternating CO2-brine flooding, flow direction, existence of residual hydrocarbon (natural gas) and change in the reservoir stress field on the system's multiphase flow behaviour were investigated. Until completion of this study there were no experimental data published in the literature addressing the above mentioned issues and the results obtained, and published within this thesis were the first of their kind.

Uranium is an element to be found ubiquitous in rock, soil, and water. Uranium concentrations in natural ground water can be more than several hundreds g/l without impact from mining, nuclear industry, and fertilizers. Considering the WHO recommendation for drinking water of 15 g/l (has been as low as 2 g/l before) due to the chemical toxicity of uranium the element uranium has become an important issue in environmental research. Besides natural enrichment of uranium in aquifers uranium mining and milling activities, further uranium processing to nuclear fuel, emissions form burning coal and oil, and the application of uranium containing phosphate fertilizers may enrich the natural uranium concentrations in soil and water by far. In October 1995 the first international conference on Uranium Mining and Hydrogeology (UMH I) was held in Freiberg being organized by the Department of Geology at the Technical University Bergakademie Freiberg by the support of the Saxon State Ministry of Geology and Environment. Due to the large scientific interest in the topic of uranium a second conference (UMH II) took place in Freiberg in September 1998. Furthermore, in September 2002 scientists working on the topic of uranium mining and hydrogeology attended the third conference (UMH III) which was jointly held together with the International Mine Water - sociation (IMWA) Symposium 2002. The reviewed papers and posters of the 2002 conference have been published by Springer entitled Uranium in the aquatic en- ronment (edited by Merkel, Planer-Friedrich and Wolkersdorfer).

This thorough review is based on observational satellite, airborne and in-situ data, scientific literature and technical reports, as well as the substantial experience of the authors, who hail from several Baltic Sea countries. They pay special attention to national practices, HELCOM and EMSA CleanSeaNet activities in oil pollution monitoring, and show different applications of the Seatrack Web model for oil spill drift prediction and the identification of illegal polluters, as well as for environmental risk assessment. Furthermore, some of the results on satellite monitoring of the Nord Stream gas pipeline construction in the Gulf of Finland are presented. This volume addresses the needs of specialists working in different fields of marine, environmental, and remote sensing sciences. It is a useful handbook on oil pollution for international and governmental agencies, as well as for policy makers who plan and manage oil and gas projects, the construction of ports and terminals, shipping, fishery, recreation, and tourist activities in the Baltic Sea. It also offers graduate and undergraduate students in marine and environmental sciences a valuable resource and reference work on the subject.

Natural saline water, waste water, and irrigation return flow endanger the groundwater aquifers in the Rift. In the long run this will ruin the socio-economic backbone of the settlements in the area. Sustainability of the water resources will only be achieved when the process of water replenishment and its underground flow is understood and water extraction is regionally controlled. Rare earth element and spider patterns are presented as new tools for studying the hydrology. Progress in 3-D modelling of groundwater flow proved successfully the impact of pumping on the surroundings of wells and overexploitation of aquifers.

This book provides a comprehensive description of groundwater resources in Ethiopia and its various dimensions (groundwater as resource, environmental functions, and socioeconomics). The prevailing knowledge of groundwater resources in Ethiopia (or elsewhere in Sub Saharan Africa) was based on geological and stratigraphic framework known nearly four decades ago (mainly 1960's and 70's). Thanks to the substantial geoscientific research since the 70's a new set of relevant geological/stratigrahpic data has been created that helps to re-define our understanding of groundwater resources in Africa as a whole and in Ethiopia in particular: a) For the first time the basement aquifer of Ethiopia has been described hydrogeologically based on genesis of regoliths (deep weathering and striping history); clear regional difference in groundwater potential is shown for the first time; comparative accounty has been given regarding groundwater occurrence in the generally low grade basement rocks of Ethiopia (Arabian Nubian shield) and high grade basement rocks of the rest of Africa. b) For the first time groundwater occurrence in multilayred sedimentary rocks account for spatial variation in degree of karstification; deformation history, and stratigraphy. c) The vast volcanic aquifers of Ethiopia which have previously classified based on their ages are now reclassified based on age, morphology (eg. groundwater in plateau volcanics, groundwater in shield volcanics) and aquifer structure. d) The loose alluvio lacustrine sediments which were known as least extensive in previous works based on areal cover are in fact shown to host the most voluminous groundwater resources in Ethiopia. These aquifers have now been described based on their geomorphology, extent, and genesis. The aim of this book is to use these newly created knowledge to redefine the understanding of groundwater resources in Ethiopia.

Focusing on issues of when and how Archean crust in the craton was formed, this PhD thesis book presents major research outcomes of field based metamorphic, geochemical and geochronological investigations on Meso-Neoarchean basement rocks from Shandong Province in the Eastern Block of the North China Craton. Based on major findings and new data, the author proposes that the formation and evolution of Archean crust was governed by mantle plumes, not by plate tectonics. As one of the oldest cratonic blocks in the world containing rocks as old as 3.85 billion years, the formation and evolution of North China Craton is still controversial. Therefore this book will be of value to anyone interested in the evolution of cratonic blocks and Precambrian geology.

This volume provides a comprehensive overview of advanced research in the field of efficient, clean and renewable energy production, conversion and storage. The ten chapters, written by internationally respected experts, address the following topics: (1) solar and wind energy; (2) energy storage in batteries; (3) biomass; and (4) socio-economic aspects of energy. Given its multidisciplinary approach, which combines environmental analysis and an engineering perspective, the book offers a valuable resource for all researchers and students interested in environmentally sustainable energy production, conversion, storage and its engineering.

This volume provides a detailed overview of water pollution and control of several selected Chinese reservoirs. It explores sediment contamination as well as algal blooms and their impact on water quality. Several chapters also discuss various methods of quality control, such as mixing-oxygenation combined with microbial remediation technologies. Due to their broad geographical distribution and different nutrition levels, the investigated reservoirs, the Jinpen, Shibianyu, Fenhe, Zhelin and Zhoucun reservoirs, can be regarded as representative for China. This comprehensive work will appeal to researchers, advanced students and reservoir managers.

This book will broaden readers' understanding of pegmatites in a special geodynamic setting, dealing with the emplacement of the Hagendorf-Pleystein Pegmatite Province (HPPP) in the Central European Variscides. This treatise illustrates the complex processes leading to the formation and partial destruction of the pegmatites, documenting the geochronological, chemical, mineralogical, geological and geomorphological / sedimentological data set. The book starts with a detailed account of the economic geology of the various pegmatites, explaining why these deposits are a major resource of ceramic raw materials. In its concluding section, a model of the pegmatite evolution in an ensialic orogen provides meaningful insights into the genetic aspects of pegmatite generation. The Late Paleozoic rare-element pegmatites of the HPPP, Oberpfalz-SE, Germany, rank among the largest concentrations in Europe. The biggest pegmatite of this mining district totals 4.4 million tons of ore (Hagendorf-South). The mining history of the HPPP is restricted to the 20th century, when local entrepreneurs started mining operations in search of ceramic raw materials, feldspar and quartz. Today the "Silbergrube Aplite" is still worked for feldspar. The traditional mining of pegmatitic and aplitic rocks in Central Europe, such as the Bohemian Massif, which is shared by Germany, the Czech Republic, Poland and Austria, has been focused on these industrial minerals. In addition to these major commodities, lithium was mined for a period of time. But even today many of these pegmatites of calc-alkaline affiliation have not lost their appeal to mineralogists and mineral enthusiasts for their wealth of minerals that contain P, Nb, Ta, Li, Be, B, U, Th, Sc, Ti and Sn. The most favorable crustal section to bring about pegmatitic rocks of this type, encompassing pegmatoids, metapegmatites, reactivated pseudopegmatites and pegmatites sensu stricto is the ensialic orogen, exemplified by the Variscan (Hercynian) Orogen, which geodynamically connects the Paleozoic pegmatite provinces in North America and Europe. The geological history of the HPPP, however, goes much further than the Carboniferous-Permian magmatic activity, when the last structural disturbances of the Variscan orogeny affected the NE-Bavarian Basement between 450 and 330 Ma. During this time mafic magmatic rocks together with calcareous and arenaceous sediments were converted into paragneisses, calcsilicate rocks, and amphibolites. It is the period of time when tectonic shortening led to over thrusting and when the emplacement of nappes and the architectural elements of the ensialic orogen began taking shape. During the Late Permian, the Mesozoic and the Cenozoic, the HPPP did not lie idle in geological terms; hypogene and supergene alteration continued and found its most recent expression in alluvial-fluvial "nigrine" placer deposits, which resulted from the unroofing of the pegmatites and aplites in the HPPP and can be used even outside HPPP as an ore guide to pegmatites.

Understanding acid-base equilibria made easy for students in chemistry, biochemistry, biology, environmental and earth sciences. Solving chemical problems, be it in education or in real life, often requires the understanding of the acid-base equilibria behind them. Based on many years of teaching experience, Heike Kahlert and Fritz Scholz present a powerful tool to meet such challenges. They provide a simple guide to the fundamentals and applications of acid-base diagrams, avoiding complex mathematics. This textbook is richly illustrated and has full color throughout. It offers learning features such as boxed results and a collection of formulae.

This volume synthesizes the relevant data that is fundamental to our understanding of trace metal biogeochemistry and the ecology of biological communities of deep-sea vent systems. It presents the combined results of biological and geochemical research and analyzes the microdistribution of animals and the spatial structure of vent communities. Careful consideration is given to the export of iron and other trace metals from hydrothermal vents. The environmental conditions to be found in deep-sea hydrothermal community habitats, along with the trace metal behavior in biotope water are characterized and the sources and forms of trace metals taken up by dominant hydrothermal vent animals are discussed. Special attention is paid to the poorly investigated deep biosphere of the sub-seafloor igneous crust. The book is illustrated with a wealth of exceptional deep-sea photos taken by the manned submersible "Mir", and a dedicated chapter focuses on the role of deep manned submersibles in ocean research. The book will be of interest to researchers and students in the fields of oceanography, geochemistry, biology, the environmental sciences and marine ecology.

This volume presents a unique and comprehensive glimpse of current and emerging issues of concern related to potable water. The themes discussed include: (1) historical perspective of the evolution of drinking water science and technology and drinking water standards and regulations; (2) emerging contaminants, water distribution problems and energy demand for water treatment and transportation; and (3) using alternative water sources and methods of water treatment and distribution that could resolve current and emerging global potable problems. This volume will serve as a valuable resource for researchers and environmental engineering students interested in global potable water sustainability and a guide to experts affiliated with international agencies working toward providing safe water to global communities.

This book is both a review and a look to the future, highlighting challenges for better predicting quantitatively the impact of diagenesis on reservoir rocks. Classical diagenesis studies make use of a wide range of descriptive analytical techniques to explain specific, relatively time-framed fluid-rock interaction processes, and deduce their impacts on reservoir rocks. Future operational workflows will consist of constructing a conceptual diagenesis model, quantifying the related diagenetic phases, and modelling the diagenetic processes. Innovative approaches are emerging for applied quantitative diagenesis, providing numerical data that can be used by reservoir engineers as entry (input) data, and for validating results of numerical simulations. Geometry-based, geostatistical and geochemical modelling do not necessarily mimic natural processes, they rather provide reasonable solutions to specific problems.

This book focuses on the development of DGT (diffusive gradients in thin films) and the related techniques for measuring and investigating the geochemical process and P transfer across the sediment/water or sediment/root interface in lakes. A series of DGT techniques such as new types of probes, test methods in sediment or the rhizosphere, DIFS (DGT induced fluxes in sediments and soils) model for kinetic P exchange, CID (computer imaging densitometry) for S(-II), and microchelex gel/LA-ICP-MS (laser ablation inductively coupled plasma mass spectrometry) have been developed. The corresponding chapters on the theory and methodology of DGT, the "internal P loading" or P transfer across sediment/root in two lakes, provide insights into the research method and conclusions, including the P release mechanism, the quantification of "internal P loading", kinetic P exchange in DGT/sediment interface, Fe- or S(-II)-microniches at submillimeter scales in sediments for the prediction of P release, and DGT as a surrogate for the prediction of P uptake by roots. It also offers new perspectives in the fields of P analysis and P process in micro-interfaces in lakes using DGT techniques. The P remobilization from Fe-bound P, the coupled Fe-S(-II)-P geochemical reaction and algae biomass breakdown causing P release, are elucidated using DGT methods in sediment layers. DGT parameters and curves for time or distance derived from DIFS can be used to assess kinetic P release in the sediment microzone. CID and LA-ICP-MS methods deliver Fe- and S(-II) images at submillimeter scales, which can be used for the quantification of flux related to microniche peaks and the prediction of P release from Fe-microniche or Fe-S(-II)-P geochemical reactions. DGT measurements in-situ in rhizosphere or rhizonbox can give CE (effective concentration) and CDGT values for the prediction of P accumulated in plant tissues. This book provides a valuable reference resource for senior graduate students, lecturers and researchers in the fields of the geochemical process of eutrophic elements in lakes, lake eutrophication mechanism and environmental analysis.

This book provides an overview of air quality in urban environments in Europe, focusing on air pollutant emission sources and formation mechanisms, measurement and modeling strategies, and future perspectives. The emission sources described are biomass burning, vehicular traffic, industry and agriculture, but also African dust and long-range transport of pollutants across the European regions. The impact of these emission sources and processes on atmospheric particulate matter, ozone, nitrogen oxides and volatile and semi-volatile organic compounds is discussed and critical areas for particulate matter and nitrogen dioxide in Europe are identified. Finally, this volume presents future perspectives, mainly regarding upcoming air quality monitoring strategies, metrics of interest, such as submicron and nanoparticles, and indoor and outdoor exposure scenarios.

Over the last fifteen years, space-based exploration of the solar system has increased dramatically, with more and more sophisticated orbiters and landers being sent to Mars. This intense period, rich in unprecedented scientific results, has led to immense progress in our perception of Mars and of its evolution over geological time. In parallel, advances in numerical simulations and laboratory experiments also shed new light on the geochemical evolution of the planet Mars. The ISSI-Europlanet Workshop entitled "Quantifying the Martian Geochemical Reservoirs" was held in Bern in April 2011 with the objective to create a diverse interdisciplinary forum composed of scientists directly involved in space-based exploration of the Martian surface, meteoriticists studying SNC meteorites, and planetary and/or Earth scientists simulating, numerically or experimentally, the physical and chemical processes occurring on or within Mars. The chapters of this book provide an overview of current knowledge of the past and present Martian geochemical reservoirs, from the accretionary history to the secondary alteration processes at the surface. In addition to the detailed description of data from Mars and the methods used to obtain them, the contributions also emphasize comparison with features on Earth, providing a perspective on the extent to which our knowledge of terrestrial systems influences interpretation of data from Mars. Areas that would benefit from future work and measurements are also identified, providing a view of the short-term and long-term future of the study of Mars. This collection of chapters constitutes a timely perspective on current knowledge and thinking concerning the geochemical evolution of Mars, providing context and a valuable reference point for even more exciting future discoveries. It is aimed at graduate students and researchers active in geochemistry and space science. Previously published in Space Science Reviews, Vol. 174/1-4, 2013.

Fluid-aided mass transfer and subsequent mineral re-equilibration are the two defining features of metasomatism and must be present in order for metamorphism to occur. Coupled with igneous and tectonic processes, metasomatism has played a major role in the formation of the Earth's continental and oceanic crust and lithospheric mantle as well as in their evolution and subsequent stabilization. Metasomatic processes can include ore mineralization, metasomatically induced alteration of oceanic lithosphere, mass transport in and alteration of subducted oceanic crust and overlying mantle wedge, which has subsequent implications regarding mass transport, fluid flow, and volatile storage in the lithospheric mantle overall, as well as both regional and localized crustal metamorphism. Metasomatic alteration of accessory minerals such as zircon or monazite can allow for the dating of metasomatic events as well as give additional information regarding the chemistry of the fluids responsible. Lastly present day movement of fluids in both the lithospheric mantle and deep to mid crust can be observed utilizing geophysical resources such as electrical resistivity and seismic data. Such observations help to further clarify the picture of actual metasomatic processes as inferred from basic petrographic, mineralogical, and geochemical data. The goal of this volume is to bring together a diverse group of geologists, each of whose specialities and long range experience regarding one or more aspects of metasomatism during geologic processes, should allow them to contribute to a series of review chapters, which outline the basis of our current understanding of how metasomatism influences and helps to control both the evolution and stability of the crust and lithospheric mantle.

The book will include contributions of the state of the art of quartz raw materials (deposits and properties) and their analytics. The chapters are presented by leading scientists in the quartz field. The presentations cover the main interrelations between genesis of quartz - formation of specific properties - analytics - industrial applications of SiO2 raw materials.

The aim of this book is to unlock the power of the freeware R language to advanced university students and researchers dealing with whole-rock geochemistry of (meta-) igneous rocks. The first part covers data input/output, calculation of commonly used indexes and plotting in R. The core of the book then focusses on the presentation and practical implementations of modelling techniques used for fingerprinting processes such as partial melting, fractional crystallization, binary mixing or AFC using major-, trace-element and radiogenic isotope data. The reader will be given a firm theoretical basis for forward/reverse modelling, followed by exercises dealing with typical problems likely to be encountered in real life, and their solutions using R. The concluding sections demonstrate, using practical examples, how a researcher can proceed in developing a realistic model simulating natural systems. The appendices outline the fundamentals of the R language and provide a quick introduction to the open-source R-package GCDkit for interpretation of whole-rock geochemical data from igneous and metamorphic rocks.

This book provides an overview of the fundamentals and reference values for Ca stable isotope research, as well as current analytical methodologies including detailed instructions for sample preparation and isotope analysis. As such, it introduces readers to the different fields of application, including low-temperature mineral precipitation and biomineralisation, Earth surface processes and global cycling, high-temperature processes and cosmochemistry, and lastly human studies and biomedical applications. The current state of the art in these major areas is discussed, and open questions and possible future directions are identified. In terms of its depth and coverage, the current work extends and complements the previous reviews of Ca stable isotope geochemistry, addressing the needs of graduate students and advanced researchers who want to familiarize themselves with Ca stable isotope research.

This book represents a rather complicated history of encounters, changes in research interest and some very interesting results. Initially it is the very fruitful interaction of Ecology and Geology. The point of view of ecologists is extremely refreshing for hard science people. Interaction and inter-relationships are the focus of Ecology whereas the traditional sciences, such as Geology, have tried to isolate the natural phenomena so that thye could be studied in a more rigorous manner. The traditional sciences were of course natural science - based since the world to be observed was at the door step of everyone, mountains, weather patterns, plants and so forth. Chemistry and Physics were de ned after Mathematics in order to establish more precise and viable principles of the behavior of the materials that formed the world around mankind. It became quite clear that the observation of the natural world was too complicated to consider all of the possible variables which could affect an observed process or situation. The systems were simpli ed and taken into the laboratory in order to better master the phenomena observed. Physics c- cerned itself with non-reacting materials, subjected to essentially mechanical forces.