Proceedings of the NATO Advanced Study Institute, Aussois, France, September 4-15, 1985

MYRON J. MITCHELL* The biota of soils constitute an integral part of both natural and agronomic ecosystems. The soil microflora and fauna in conjunction with the belowground portion of the Metaphyta or higher plants constitute the living milieu, components of which are in intimate association with each other as well as the abiotic constituents of the soil. Since these associations or interactions are important in regulat ing both the flux and availability of energy and nutrients, the central theme of the present book focuses on these interactions. The effects of microfloral and faunal inter actions with regard to overall ecosystem dynamics and specific critical processes will be examined. HISTORICAL ASPECTS The coverage of this volume is an extension of a vast body of literature which dates back to the 18th century. A brief compendium of major books and reviews published from 1960 to 1983 is given chronologically in Tables 1 and 2, respectively. Russell (1961) has reviewed work in the 1800's during which some of the basic tenets on the relationships between plant nutrition and soil properties became estab lished. In this period agricultural science was founded and the study of soil bacteriology began. The evolution of soil biology up to the early 1970's has been described by Satch211 in the volume edited by Dickinson and Pugh (1974). *Department of Environmental and Forest Biology, SUNY, College of Environmental Science and Forestry, Syracuse, NY 13210 2 ~ .

For the first time in human history, developments in many branches of science provide us with an opportunity of formula ting a comprehensive picture of the universe from its beginning to the present time. It is an awesome reflection that the carbon in our bodies is the very carbon which was generated during the birth of a star. There is a perceptible continuum through the billions of years which can be revealed by the study of chemistry. Studies in nucleosynthesis have related the origin of the elements to the life history of the stars. The chemical elements we find on earth, HYdrogen, Carbon, Oxygen, and Nitrogen, were created in astronomical processes that took place in the past, and these elements are not spread throughout space in the form of stars and galaxies. Radioastronomers have discovered a vast array of organic molecules in the interstellar medium which have a bearing on prebiological chemical processes. Many of the molecules found so far contain the four elements, C, N, 0, H. Except for the chem ically unreactive He, these four elements are the most abundant in the galaxy. The origin of polyatomic interstellar molecules is an unresolved problem. While we can explain the formation of some diatomic molecules as due to two atom collisions, it is much more difficult to form polyatomic molecules by collisions between diatomic molecules and atoms. There may be other produc tion mechanisms at work such as reactions taking place on the surface of interstellar dust grains."

In the Fall of 1988, 64 geologists and geophysicists from 11 countries met in Killarney, Ontario, on the north shore of Lake Huron to examine evidence that suggests that the continental crust is exposed in cross-section at several key locations on the Earth's surface. The meeting, which was held under NATO auspices as an Advanced Study Institute, was a landmark event in that it was the first time that many of the lead scientists working on these complexes in relative isolation around the world had' ever gathered together to compare results. The present volume is a compendium of the invited lectures given on the principle sections, plus an array of supporting papers on these and other sections as well as on related topics such as crustal emplacement mechanisms, deformation and rheology. Nearly all of the best known sections are represented, including the Ivrea Zone, Calabria, the Kapuskasing Zone, Fiordland and many others. It is our hope that this Volume will serve as a reference for Earth scientists who are trying to understand levels of the crust not normally exposed to view, as well as a point of departure for new research and a teaching aid to new entrants in this relatively new field of study.

This book represents the proceedings of the 9th written by a very active group of physicists at Kongsberg seminar, held at the Norwegian Mining the University of Oslo - physicists interested in Museum located in the city of Kongsberg about complex systems in general and geo-like systems 70 km Southwest of Oslo. The Kongsberg district in particular. is known for numerous Permian vein deposits of The content of the book is organized into three native silver, and mining activity in the area lasted major parts following the introductory chapter. for more than 300 years, finally ceasing in 1957. Chapters 2 to 7 primarily treat the role of fluids The previous eight Kongsberg seminars were in specific geological environments, ranging from focused on ore-forming processes and all of these sedimentary basins (Chapters 2-3) to contact were organized by Professor Arne Bj0rlykke, now metamorphic/hydrothermal scenarios (Chapters director of the Norwegian Geological Survey. 4-5) and regional metamorphic settings (Chapters Since process-orientated research tends to break 6-7). The following four chapters (8-11) focus down the traditional barriers between the different on various properties of fluid-rock systems that geological disciplines, this seminar has always are critical in controlling flow and transport been a meeting point for people with a variety through rocks. These include: mineral solubility of geological backgrounds.

Proceedings of the NATO Advanced Research Workshop, Bremen, Germany, October 10-14, 1988

Viewed from space, the Earth appears as a globe without a beginning or an end. Encompassing the globe is the atmosphere with its three phases- gaseous, liquid, and solid--moving in directions influenced by sunlight, gravity, and rotation. The chemical compositions of these phases are determined by biogeochemical cycles. Over the past hundred years, the processes governing the rates and reactions in the atmospheric biogeochemical cycles have typically been studied in regions where scientists lived. Hence, as time has gone by, the advances in our knowledge of atmospheric chemical cycles in remote areas have lagged substantially behind those for more populated areas. Not only are the data less abundant, they are also scattered. Therefore, we felt a workshop would be an excellent mechanism to assess the state of-knowledge of the atmospheric cycles of sulfur and nitrogen in remote areas and to make recommendations for future research. Thus, a NATO Advanced Research Workshop ' he Biogeochemical Cycling of Sulfur and Nitrogen in the Remote Atmosphere" was held at the Bermuda Biological Station, St. Georges, Bermuda, from 8-12 October 1984. The workshop was attended by 24 international scientists known for their work in atmospheric cycling in remote areas. This volume contains the back ground papers and the discussions resulting from that workshop. The workshop was organized along the lines of the atmospheric cycle. There were working groups on emission, transport, transformation, and deposi tion."

Agriculture in the industrial world has gone A common interest of the contributors is increas through dramatic changes over the past decades. ing the understanding of the turnover of carbon Mechanization in combination with high inputs of and inorganic nutrients in terestrial ecosystems. fertilizers and pesticides has turned deficits of agri The authors approach this topic from different cultural products into surplus. Over the same directions depending on their interests and ex period we have experienced increased environment pertise. Difficulties are identified in the quantifica al problems in both the atmosphere and our water tion of below-ground production where death and resources, which have been associated with the re-growth, if incorporated into the calculations, changes in management practices. can change production figures considerably as Concern about the potential pollution by compared to values derived from "peak" estimates. nitrogen fertilizers as well as the low utilization The role of root-derived carbon is investigated in efficiency of applied nitrogen by plants has created relation to nutrient competition between roots and a need for a better understanding of nitrogen microorganisms, the cost of N2 fixation and the cycling in the plant-soil-water system. To achieve decomposition of organic nitrogen. Mycorrhizae this, it is neccessary to study process interactions use root-derived carbon and their roles in phos and process regulation in an ecosystem context. phorus conservation and in supplying nutrients to During the last decade many ecosystem studies the host are exemplified.

This book provides a detailed description of light absorption and absorbents in seawaters with respect to provenance, region of the sea, depth of the occurrence and trophicity. The text is based on a substantial body of contemporary research results taken from the subject literature (over 400 references) and the work of the authors over a period of 30 years.

Three symposia on environmental geochemistry in tropical countries, held in Niter6i, Brazil (1993), in Cartagena, Colombia (1996) and in Nova Friburgo, Brazil (1999), made it very clear that tropical geochemistry is of world standard and fast increasing in multi disciplinarily and impact on important geochemical paradigms. It has additionally strong links with the economy of tropical countries, such as mining and industrialisa tion and is in full development for treating environmental problems caused by human activities of urban or industrial origin. We must compliment Prof. Jorge Abriio and his colleagues in Brazil and Dr. Gloria Prieto and her colleagues in Colombia for these ini tiatives. The participation of respectively 180 and 150 scientists, coming from 15 different countries for the first and second symposia, has shown that a large interest exists for tropical environmental geochemistry. It also demonstrates the necessity to understand tropical environmental problems. The organisation of a large international symposium is not possible without the assistance of state and federal authorities, for which those of Brazil and Colombia have to be complimented. The 3rd Symposium on Environmental Geochemistry in Tropical Countries was the last of the series and was attended by 22 countries and 170 participants and treated a number of related environmental and economic problems."

Human activity has dramatically altered the global nitrogen cycle in recent decades. These changes are not evenly distributed around the world; rather, they are greatest in regions of significant industrial and agricultural activity, as the synthesis and use of inorganic fertilizers, cultivation of legumes, burning of fossil fuels, and the simple act of concentrating humans and animals in dense populations all lead to the release of excess, reactive forms of nitrogen into the environment. In part because reactive nitrogen is frequently a limiting nutrient in many terrestrial and aquatic systems, an excess can lead to a variety of adverse effects on both environmental and human health. The North Atlantic Ocean and its contributing watersheds constitute a region which has seen perhaps the greatest increase in anthropogenically-derived nitrogen. In May of 1994, the International Scope Nitrogen Project, with funding from the Andrew Mellon Foundation, the United Nations Environment Program, and the World Meteorological Organization, sponsored a workshop held on Block Island, RI, USA, entitled Nitrogen Dynamics of the North Atlantic Basin'. More than 50 scientists from 12 different countries convened with a unique set of goals: an integrated and comprehensive estimate of the current nitrogen cycle of the ocean, coastal systems, and contributing watersheds of the North Atlantic region; an analysis of human-induced changes to those cycles; and an assessment of the current and future effects of human-induced changes to nitrogen cycling throughout the globe.

Chlorinated paraffins are one of the last classes of chlorinated compounds that are still being produced worldwide and used in high quantities in many applications. They are particularly used in cutting oils in the metal industry, but also as lubricants, plasticizers, flame retardants and as additives in adhesives, rubber, paints and sealants. This volume covers the state-of-the-art of methods for the synthesis and analysis of chlorinated paraffins. Experts in the field provide an overview of their worldwide occurrence and utilization and describe their toxicological properties. International regulations and production volumes are presented as well as an example of a risk assessment study that was carried out in Japan. This book is a valuable and comprehensive source of information for environmental scientists interested in the occurrence and toxicology of chlorinated paraffins and for authorities and producers.

The system of international co-operation in the Antarctic has been evolving rapidly since the signing of the Antarctic Treaty in 1959. Inextricably linked to this co-operation is the question of the rational management of Antarctic resources. In this book Professor Orrego Vicuna examines in depth the legal framework - the Antarctic Treaty, sovereignty, jurisdiction and the law of the sea - as it relates to the exploitation of Antarctic minerals. This is fast becoming a live issue with the ever-growing potential for the development of these resources. The first part of the book examines the main characteristics of the international legal framework governing the co-operation of states in Antarctica, particularly in relation to resource conservation. Against this background, in the second part of the book, the regime for mineral resources is discussed in sufficient detail to identify the basic issues and interests which have to be accommodated in order to attain an acceptable convention. The final part of the book considers the important set of questions raised by the interest of the world community at large in the Antarctic: most significantly, the initiatives concerning a broader international participation under the auspices of the United Nations.

The founders of geology at the beginning of the last century were suspicious oflaboratories. Hutton's well-known dictum illustrates the point: "There are also superficial reasoning men . . . they judge of the great oper ations of the mineral kingdom from having kindled a fire, and looked into the bottom of a little crucible. " The idea was not unreasonable; the earth is so large and its changes are so slow and so complicated that labo ratory tests and experiments were of little help. The earth had to be studied in its own terms and geology grew up as a separate science and not as a branch of physics or chemistry. Its practitioners were, for the most part, experts in structure, stratigraphy, or paleontology, not in silicate chemistry or mechanics. The chemists broke into this closed circle before the physicists did. The problems of the classification of rocks, particularly igneous rocks, and of the nature and genesis of ores are obviously chemical and, by the mid- 19th century, chemistry was in a state where rocks could be effectively analyzed, and a classification built up depending partly on chemistry and partly on the optical study of thin specimens. Gradually the chemical study of rocks became one of the central themes of earth science."

Research of the origins of life in connection with a marine environment started at the end of the seventies, when the black smokers' in the Pacific were discovered and the Red Sea deep hydrothermal brines were found to be a fruitful environment for abiotic synthesis of life precursors. For a while this research was categorised under the heading chemistry', but in less than a decade the topic became fully integrated into the science of 'oceanography'. The Scientific Committee on Oceanographic Research (SCOR) initiated Working Group 91: Chemical Evolution and Origin of Life in Marine Hydrothermal Systems'. This volume contains the final report of this working group.

The future of the Common Fisheries Policy depends on progress in the relevant areas of research. This applies to the whole range of management decisions, where precise, reliable and complete data are essential to inform those who must decide on the pursuit of existing activities, especially in the area of maritime fisheries, and the development of promising new activities such as aquaculture. Every day the Director-General of DG XIV requires more and more information to prepare decisions which will affect the future of all those in the Community who are dependent on fishing and aquaculture. There is thus a high level of direct demand from DG XIV. Over and above this immediate and specific requirement for short- and medium-term applications, research affects the competitivity of the Community. This is one area which favours the collaboration across frontiers of all those who seek to advance knowledge. But although DG XIV is uniquely placed to appreciate the importance of research into fisheries and aquaculture, there is no question of succumbing to the temptation to directly control the scope of research or its conduct. The notion of subsidiarity can best be understood by examining the existing structures in the Member States. The Commission must act first and foremost as a catalyst, by promoting the circulation of information and the coordination of research programmes.

This book presents a review of those efforts that have been and are being made to determine the geochemical composition of the moon and planets. The authors have attempted to present both a review as well as their philosophy about the development of flight experiments for geo chemical studies. Their basic premise is that such flight experiments should emphasize the scientific objectives and a total systems approach to meeting these objectives, involving the analytical device, data handling and data interpretation. While the above seems reasonably obvious, many proposals of experiments often tend to begin with an instrument with too little concern about the constraints imposed and whether the data that can be obtained are sufficiently useful to meet the scientific objectives. This book covers the accomplishments in space science exploration, bearing on the history and composition ofthe solar system. 'It also covers the rationale behind the lunar and planetary exploration program. The latter part of the book is concerned with future plans for lunar and planetary exploration instrumentation and techniques in various stages of development. There is an exposition of the methods of remote analysis of the moon and planets, including some concepts developed by the authors as a result of their long term involvement with the space program, from its early inception to the present day preparation for remote geochemical analysis in the Apollo, Mariner and Viking missions."

About three years ago Catherine de Berg and I published a short article in Nature in which we attempted to explain why the chemistry of the atmosphere of the Earth is today so completely different from that of our two neighbor ing planets, Mars and Venus. Our atmosphere is composed mainly of N2 and O with traces of A, H0, CO , 0 , etc. , while the atmospheres of both 2 2 2 3 Mars and Venus are almost entirely made up of CO , Also, the Earth appears 2 to be the only one ofthe three planets which has oceans ofliquid water on the surface. Since the presence of liquid water on Earth is probably an essential requirement for life to have originated and evolved to its present state, the question of the apparent absence ofliquid water on Mars and Venus suddenly acquires significant proportions. In our paper in Nature, and later in a more detailed discussion of the subject (Planetary Atmospheres, in Exobiology, edited by C. Ponnamperuma, North Holland Publishing Co. ), we tried to describe why we believe that in the early history of the solar system all the terrestrial planets lost the atmospheres of H2 and He which they had acquired from the solar nebula at the time of their formation. These planets, completely devoid of atmos pheres, like the Moon today, started accumulating new gases which were exhumed from the interior by the commencement of volcanic activity.

The Evolution of Matter explains how all matter in the Universe developed following the Big Bang and through subsequent stellar processes. It describes the evolution of interstellar matter and its differentiation during the accretion of the planets and the history of the Earth. Unlike many books on geochemistry, this volume follows the chemical history of matter from the very beginning to the present, demonstrating connections in space and time. It provides also solid links from cosmochemistry to the geochemistry of Earth. The book presents comprehensive descriptions of the various isotope systematics and fractionation processes occurring naturally in the Universe, using simple equations and helpful tables of data. With a glossary of terms and over 900 references, this volume is a valuable reference for researchers and advanced students studying the chemical evolution of the Earth, the Solar System and the wider Universe.

This book focuses on sediments as a pollutant in natural freshwater and marine habitats, and as a vector for the transfer of chemicals such as nutrients and contaminants. Sediment-water research is carried out all over the world within a variety of disciplines. The selected papers cover three main topics relating to assessment and/or restoration of disturbed watersheds, sediment-water linkages in terrestrial and aquatic environments and evaluation of sediment and ecological changes in marine and freshwater habitats. Innovative research in both developed and less developed countries is included. Both fundamental research, insight into applied research and system management are covered. The volume will also appeal to readers involved in sediment geochemistry and dynamics, aquatic habitats, water quality, aquatic ecology, river morphology, restoration techniques and catchment management.

This book is an outgrowth of my interest in the chemistry of sedimentary rocks. In teaching geochemistry, I realized that the best examples for many chemical processes are drawn from the study of ore deposits. Consequently, we initiated a course at The University of Cincinnati entitled "Sedimentary Ore Deposits," which serves as the final quarter course for both our sedimentary petrology and our ore deposits sequence, and this book is based on that teaching experience. Because of my orientation, the treatment given is perhaps more sedimentological than is usually found in books on ore deposits, but I hope that this proves to be an advantage. It will also be obvious that I have drawn heavily on the ideas and techniques of Robert Garrels. A number of people have helped with the creation of this book. I am especially grateful to my students and colleagues at Cincinnati and The Memorial University of Newfoundland for suffering through preliminary versions in my courses. I particularly thank Bill Jenks, Malcolm Annis, and Dave Strong. For help with field work I thank A. Hallam, R. Hiscott, J. Hudson, R. Kepferle, P. O'Kita, A. Robertson, C. Stone, and R. Stevens. I am also deeply indebted to Bob Stevens for many hours of insightful discussion.

Marble in Ancient Greece and Rome: Geology, Quarries, Commerce, Artifacts Marble remains the sine qua non raw material of the an cient Greeks and Romans. Beginning in the Bronze Age sculptu re began in marble and throughout classical times the most im portant statues, reliefs, monuments and inscriptions were made of it. Yet, quarry sources changed in time as preferences for different marbles were influenced by local traditions, the pos sibilities of transport, esthetic tastes, and economics. Marble studies and the identification of the provenance of marble can thus reveal much about Greek and Roman history, trade, esthe tics and technology. Persons in many disciplines are studying various aspects of Greek and Roman marble usage. Geologists and geochemists are working on methods to determine the provenance of marble; ar chaeologists are noting changing patterns of import and use in excavation and discovering how improving quarrying techniques and prelimihary dressing of the extracted material influenced the final shape of artifacts; ancient historians are now under standing quarry organization and bureaucracies that controlled marble production and trade; art historians are seeing how phy sical characteristics of the stone affected the techniques and style of sculpture; architects and engineers are interested in quarry technologies and usage in building construction. These specialists drawn from many disciplines rarely have an opportu nity to compare notes and see how each can contribute to the research effort of others."

Destructive plate margin magmagenesis is one of the most intensely studied and widely debated topics in the earth sciences at present. Calc-alkaline volcanic and plutonic rocks in orogenic settings exhibit such a diversity of composition and character that the subducted oceanic lithosphere, the overlying 'enriched' lithospheric mantle and the lower continental crust all have been advocated recently as the primary source region for island-arc and continental-margin basaltic to andesitic magmas. The role of the upper continental crust is also a matter of continuing controversy. It is clear that crustal contamination is a common, but not universal, feature of destructive plate margin magmatism. Whether this contamination is introduced at source by subduction-related processes or occurs during magma transit by bulk anatexis and magma mixing, selective contamination or coupled fractional crystallization-assimilation mechanisms is central to most current discussions of andesite petrogenesis. This book presents a series of papers which directly address these and other important geological and geochemical problems within the context of the Mesozoic-Cenozoic calc-alkaline magmatism characteristic of the Andean Cordillera of western South America. Although it is aimed primarily at postgraduate students and researchers familiar with the Andes, it is also a useful general reference for workers in other fields who wish to gain an insight into current thoughts, ideas and speculations on 'andesitic' magmatism at destructive plate margins.

Over the past decade the scientific activities of the Joint Global Ocean Flux Study (JGOFS), which focuses on the role of the oceans in controlling climate change via the transport and storage of greenhouse gases and organic matter, have led to an increased interest in the study of the biogeochemistry of organic matter. There is also a growing interest in global climate fluctuations. This, and the need for a precise assessment of the dynamics of carbon and other bio-elements, has led to a demand for an improved understanding of biogeochemical processes and the chemical characteristics of both particulate and dissolved organic matter in the ocean. A large amount of proxy data has been published describing the changes of the oceanic environment, but qualitative and quantitative estimates of the vertical flux of (proxy) organic compounds have not been well documented. There is thus an urgent need to pursue this line of study and, to this end, this book starts with several papers dealing with the primary production of organic matter in the upper ocean. Thereafter, the book goes on to follow the flux and characterization of particulate organic matter, discussed in relation to the primary production in the euphotic zone and resuspension in the deep waters, including the vertical flux of proxy organic compounds. It goes on to explain the decomposition and transformation of organic matter in the ocean environment due to photochemical and biological agents, and the reactivity of bulk and specific organic compounds, including the air-sea interaction of biogenic gases. The 22 papers in the book reflect the interests of JGOFS and will thus serve as a valuable reference source for future biogeochemical investigations of both bio-elements and organic matter in seawater, clarifying the role of the ocean in global climate change.