Understanding spatial statistics requires tools from applied and mathematical statistics, linear model theory, regression, time series, and stochastic processes. It also requires a mindset that focuses on the unique characteristics of spatial data and the development of specialized analytical tools designed explicitly for spatial data analysis. Statistical Methods for Spatial Data Analysis answers the demand for a text that incorporates all of these factors by presenting a balanced exposition that explores both the theoretical foundations of the field of spatial statistics as well as practical methods for the analysis of spatial data. This book is a comprehensive and illustrative treatment of basic statistical theory and methods for spatial data analysis, employing a model-based and frequentist approach that emphasizes the spatial domain. It introduces essential tools and approaches including: measures of autocorrelation and their role in data analysis; the background and theoretical framework supporting random fields; the analysis of mapped spatial point patterns; estimation and modeling of the covariance function and semivariogram; a comprehensive treatment of spatial analysis in the spectral domain; and spatial prediction and kriging. The volume also delivers a thorough analysis of spatial regression, providing a detailed development of linear models with uncorrelated errors, linear models with spatially-correlated errors and generalized linear mixed models for spatial data. It succinctly discusses Bayesian hierarchical models and concludes with reviews on simulating random fields, non-stationary covariance, and spatio-temporal processes. Additional material on the CRC Press website supplements the content of this book. The site provides data sets used as examples in the text, software code that can be used to implement many of the principal methods described and illustrated, and updates to the text itself.

'The most incomprehensible thing about the world is that it is comprehensible.' ALBERT EINSTEIN, 1950 The tremendous progress of recent years in the field of isotopes in the earth sciences has proved invaluable in attempting to solve a varied spectrum of geological and geochemical problems. The lunar exploration programmes provided rocks for analysis, stimulating refinements in mass spectrometry which were later used for terrestrial samples too. Among significant advances was the development of electrostatic tandem accelerator mass spectrometers allowing the precise measure ment of abundances of cosmic radionuclides. Also, new geochronometers were devised, for instance those dependent upon the radioactive decay of samarium-I47 to neodymium-I43, lutetium-176 to hafnium-176, rhenium-I87 to osmium-I87 and potassium-40 to calcium40, these supplementing prior dating methods. Their impact as regards the origin of igneous rocks was considerable. Isotopic compositions of neodymium, strontium, lead and hafnium in these rocks showed that magmas from the mantle are often crustally contaminated. In addition, isotopic compositions of carbon, oxygen and sulphur aided the elucidation of aspects of petrogenesis. These and many other facets of the subject are discussed in this book."

Human activity has dramatically altered the global nitrogen cycle in recent decades. These changes are not evenly distributed around the world; rather, they are greatest in regions of significant industrial and agricultural activity, as the synthesis and use of inorganic fertilizers, cultivation of legumes, burning of fossil fuels, and the simple act of concentrating humans and animals in dense populations all lead to the release of excess, reactive forms of nitrogen into the environment. In part because reactive nitrogen is frequently a limiting nutrient in many terrestrial and aquatic systems, an excess can lead to a variety of adverse effects on both environmental and human health. The North Atlantic Ocean and its contributing watersheds constitute a region which has seen perhaps the greatest increase in anthropogenically-derived nitrogen. In May of 1994, the International Scope Nitrogen Project, with funding from the Andrew Mellon Foundation, the United Nations Environment Program, and the World Meteorological Organization, sponsored a workshop held on Block Island, RI, USA, entitled Nitrogen Dynamics of the North Atlantic Basin'. More than 50 scientists from 12 different countries convened with a unique set of goals: an integrated and comprehensive estimate of the current nitrogen cycle of the ocean, coastal systems, and contributing watersheds of the North Atlantic region; an analysis of human-induced changes to those cycles; and an assessment of the current and future effects of human-induced changes to nitrogen cycling throughout the globe.

This book is an outgrowth of my interest in the chemistry of sedimentary rocks. In teaching geochemistry, I realized that the best examples for many chemical processes are drawn from the study of ore deposits. Consequently, we initiated a course at The University of Cincinnati entitled "Sedimentary Ore Deposits," which serves as the final quarter course for both our sedimentary petrology and our ore deposits sequence, and this book is based on that teaching experience. Because of my orientation, the treatment given is perhaps more sedimentological than is usually found in books on ore deposits, but I hope that this proves to be an advantage. It will also be obvious that I have drawn heavily on the ideas and techniques of Robert Garrels. A number of people have helped with the creation of this book. I am especially grateful to my students and colleagues at Cincinnati and The Memorial University of Newfoundland for suffering through preliminary versions in my courses. I particularly thank Bill Jenks, Malcolm Annis, and Dave Strong. For help with field work I thank A. Hallam, R. Hiscott, J. Hudson, R. Kepferle, P. O'Kita, A. Robertson, C. Stone, and R. Stevens. I am also deeply indebted to Bob Stevens for many hours of insightful discussion.

This book focuses on sediments as a pollutant in natural freshwater and marine habitats, and as a vector for the transfer of chemicals such as nutrients and contaminants. Sediment-water research is carried out all over the world within a variety of disciplines. The selected papers cover three main topics relating to assessment and/or restoration of disturbed watersheds, sediment-water linkages in terrestrial and aquatic environments and evaluation of sediment and ecological changes in marine and freshwater habitats. Innovative research in both developed and less developed countries is included. Both fundamental research, insight into applied research and system management are covered. The volume will also appeal to readers involved in sediment geochemistry and dynamics, aquatic habitats, water quality, aquatic ecology, river morphology, restoration techniques and catchment management.

Marble in Ancient Greece and Rome: Geology, Quarries, Commerce, Artifacts Marble remains the sine qua non raw material of the an cient Greeks and Romans. Beginning in the Bronze Age sculptu re began in marble and throughout classical times the most im portant statues, reliefs, monuments and inscriptions were made of it. Yet, quarry sources changed in time as preferences for different marbles were influenced by local traditions, the pos sibilities of transport, esthetic tastes, and economics. Marble studies and the identification of the provenance of marble can thus reveal much about Greek and Roman history, trade, esthe tics and technology. Persons in many disciplines are studying various aspects of Greek and Roman marble usage. Geologists and geochemists are working on methods to determine the provenance of marble; ar chaeologists are noting changing patterns of import and use in excavation and discovering how improving quarrying techniques and prelimihary dressing of the extracted material influenced the final shape of artifacts; ancient historians are now under standing quarry organization and bureaucracies that controlled marble production and trade; art historians are seeing how phy sical characteristics of the stone affected the techniques and style of sculpture; architects and engineers are interested in quarry technologies and usage in building construction. These specialists drawn from many disciplines rarely have an opportu nity to compare notes and see how each can contribute to the research effort of others."

PGE V-Voisey's Bay (Canada) D -Duluth Complex (USA) K-Kambalda (Australia) M-Merensky Reef (Bushveld) N -Noril'sk region (Russia) P-Pechenga(Russia) S-Sudbury (Canada) T-Thompson (Canada) J -Jinchuan (China) L-Lac des lies (Canada) PR-Platreef (Bushveld) Po-Portimo Complex (Finland) R-Raglan (Canada) U-UG-2 chromitite (Bushveld) Z-Great Dyke of Zimbabwe e-Mt Keith (Australia) . a. -Perseverance (Australia) +-Stillwater (USA) 0 0 0 'c9 -~ Ni+Co Cu Relative value of Ni+Co Fig. 1. 1. Relative va1ue of the contributions of Ni+Co, Cu and PGE to the mag- matic su1fide deposits listed in Table 1. 1 sulfide deposits are closely related to bodies of mafic or ultramafic rock, and the most convenient way in which to consider them is in terms of the type of magma responsible for the rocks with which they are associated. Typically the type of magma involved bears a close relationship to the tec- tonic setting within which it was emplaced. The locations of important deposits, both Ni-Cu dominant and PGE dominant, are shown in Fig. 1. 2. Considering first Ni-Cu deposits, these are further divided into six classes (Table 1. 2) on the basis of their associated magma type. Class NC- 1 (Chap. 3) comprises those related to komatiitic magmatism. Currently known deposits fall into two sub-classes, those related to Archean komatiites ( e. g. the deposits of Western Australia, Zimbabwe and the Abitibi belt of Canada) and those related to Proterozoic komatiites (e. g. those ofthe Raglau and Thompson belts which arebothin Canada)l.

The extraordinary growth of the computer and semiconductor industries and the increasing consumption of indium in these technologies in recent years have placed major constraints on current and future reserves of this metal. In the past, geoscientists have noticed the occurrence of indium in a large variety of ore de posits and detailed geochemical and mineralogical work is available for a few ex amples. However, despite the current technological interest, there is no compre hensive textbook that deals with all aspects of indium mineralization and economics. The present study attempts to develop a general metallogenic concept for indium in identifying the essential enrichment processes and their economic significance. The study 'Indium Geology, Mineralogy, and Economics' was commissioned and funded by the German Federal Institute for Geosciences and Natural Re sources (BGR Hannover) and is a contribution to the research program 'BGR 2000 - Raw Materials with Short Lifetime Reserves'. This program focuses on raw materials with known reserves confined to the next 20-25 years at static de mand. The future availability of reserves is usually estimated by dividing the known reserves by the current annual consumption. In fact, lifetimes of reserves are inappropriate measures because they depend on many parameters and there fore represent a "snapshot" of a dynamic system. In order to provide a sustainable use of raw materials with short lifetime reserves, a significantly higher amount of innovation is needed compared to raw materials with long lifetime reserves."

Over the past decade the scientific activities of the Joint Global Ocean Flux Study (JGOFS), which focuses on the role of the oceans in controlling climate change via the transport and storage of greenhouse gases and organic matter, have led to an increased interest in the study of the biogeochemistry of organic matter. There is also a growing interest in global climate fluctuations. This, and the need for a precise assessment of the dynamics of carbon and other bio-elements, has led to a demand for an improved understanding of biogeochemical processes and the chemical characteristics of both particulate and dissolved organic matter in the ocean. A large amount of proxy data has been published describing the changes of the oceanic environment, but qualitative and quantitative estimates of the vertical flux of (proxy) organic compounds have not been well documented. There is thus an urgent need to pursue this line of study and, to this end, this book starts with several papers dealing with the primary production of organic matter in the upper ocean. Thereafter, the book goes on to follow the flux and characterization of particulate organic matter, discussed in relation to the primary production in the euphotic zone and resuspension in the deep waters, including the vertical flux of proxy organic compounds. It goes on to explain the decomposition and transformation of organic matter in the ocean environment due to photochemical and biological agents, and the reactivity of bulk and specific organic compounds, including the air-sea interaction of biogenic gases. The 22 papers in the book reflect the interests of JGOFS and will thus serve as a valuable reference source for future biogeochemical investigations of both bio-elements and organic matter in seawater, clarifying the role of the ocean in global climate change.

This book involves application of the Calphad method for derivation of a self consistent thermodynamic database for the geologically important system Mg0- Fe0-Fe203-Alz03-Si02 at pressures and temperatures of Earth's upper mantle and the transition zone of that mantle for Earth. The created thermodynamic database reproduces phase relations at 1 bar and at pressures up to 30 GPa. The minerals are modelled by compound energy formalism, which gives realistic descriptions of their Gibbs energy and takes into account crystal structure data. It incorporates a detailed review of diverse types of experimental data which are used to derive the thermodynamic database: phase equilibria, calorimetric stud ies, and thermoelastic property measurements. The book also contains tables of thermodynamic properties at 1 bar (enthalpy and Gibbs energy of formation from the elements, entropy, and heat capacity, and equation of state data at pressures from 1 bar to 30 GPa. Mixing parameters of solid solutions are also provided by the book. Table of Contents Introduction to the Series . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V Acknowledgments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . VII Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XI Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XIII Vitae of Co-Authors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XV CODATA Task Group on Geothermodynamic Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . XXIII Chapter 1. Thermodynamics and Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 2 Thermodynamic Modeling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1. 3 Experimental Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1. 4 Programs and Assessment. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 System and Phases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1. 5 Chapter 2. Experimental Phase Equilibrium Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 The Si02 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 2. 1 2. 2 The Fe-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2. 3 The Fe-Si-0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 2. 4 The Mg0-Si0 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

The significance of manganese ores is very weil known in cast iron and steel production, as weil as in various types of chemical raw material and agricultural fertilizers. The world industry development in recent years requires their increased production in the vicinity of the metallurgical centers in different regions of the world; high grade manganese and associated metalores are needed. Analysis of the world production and consumption of manganese ores by industrial countries indicates convincingly that the highest commercial value belongs to the ores associated with the supergene zone (National Minerals Advi- sory Board, 1981; Coffman and Palencia, 1984; Doncoisne, 1985; Iones, 1990, 1991; Manganese, 1990; McMichael, 1989). The remarkable property of manganese, in contrast to many other types of mineral resources, is that the ore accumulations of this metal are distributed in the wide geochrono- logical interval from the Archean to the present time; these ores are deposited in basins and supergene environments of different types from lakes, internal seas to pelagic and abyssal regions of the World ocean, as weIl as different types of weathering crusts and karst. At the same time the manganese accumulations and features of their mineral and chemical compositions are relatively sensitive indicators, reflecting facies and geodynamic condi- tions of their formation. These properties aid the investigation of the Earth's evolution processes.

This volume follows a Specialized Symposium on "Mantle denudation in slow spreading ridges and in ophiolites," held at the XII EUG Meeting in Strasbourg, spring 1993. During the meeting it was felt that the contribu tions to the Symposium justified a volume presenting its main scientific achievements. The present title of the volume shows that the center of inter est has slightly shifted with respect to the initial objective: in order to under stand the processes involved in accretion taking place at oceanic ridges, it is crucial to study the interaction between uppermost mantle and lower crust. The approach favored here is that of petrological and structural analysis of oceanic rocks in present-day oceanic ridges combined with similar studies in ophiolites. Rock specimen collected by submersibles or dredge hauls in oceanic ridge environments provide a "ground truth." However, except for areas such as the MARK (Mid-Atlantic Ridge ne ar Kane fracture zone) where, thanks to multiple submersible dives, the local geology is known with aprecision even better than in many onshore ophiolites, mutual rela tionships between uppermost mantle and lower crust are poorly known. In contrast, onshore ophiolites provide a necessary large-scale picture built up over many years of structural and petrological mapping."

This volume contains the lectures presented at the Advanced Study Institute on "New Trends in Coal Science" which was held at Datca, HUgla, Turkey during August 23 - September 4, 1987. The book includes 23 chapters which were originally written for the meeting by some of the world's foremost investigators. Chemists everywhere are carrying out exciting research that has important implications for the energy and fuels industries and for society in general. For the near future, coal resources will continue to be of great importance and science and technology of the highest order are needed to extend this fossil energy resource and to utilize it in an economical way that is also environmentally acceptable. These were the main purposes for the organization of this NATO ASI. The Institute constituted two working weeks on structure and reactivity of coal and so is the book. Through the presentation of many specific recent results on structure and characterization of coal and its products the potential of new instrumental techniques is presented in the first part of the book. Finally the reactivity of coals at different conditions both in laboratory and industry is discussed. We hope that the volume will be of great use to research workers from academic and industrial background. In addition it could serve as a textbook for a graduate course on coal science and technology.

Microbial systems in extreme environments and in the deep biosphere may be analogous to potential life on other planetary bodies and hence may be used to investigate the possibilities of extraterrestrial life. This book examines the mode and nature of links between geological processes and microbial activities and their significance for the origin and evolution of life on the Earth and possibly on other planets. This is a truly interdisciplinary science with societal relevance.

The book emphasizes various aspects of processing secondary sources for recovery of uranium. The field of secondary resource processing is gaining ground over the last few years as it is eco-friendly, economical and in tune with the philosophy of sustainable development. The book is the first one of its type in the area and includes a succint and comprehensive description of related areas of ore mineralogy, resource classification, processing principles involved in uranium solubilisation followed by separation and safety aspects. The clear organisation and the carefully selected figures and tables makes the treatment invaluable for practising engineers, research workers and academic institutions.

Origin and Mineralogy of Clays, the first of two volumes, lays the groundwork for a thorough study of clays in the environment. The second volume will deal with environmental interaction. Going from soils to sediments to diagenesis and hydrothermal alteration, the book covers the whole spectrum of clays. The chapters on surface environments are of great relevance in regard to environmental problems in soils, rivers and lake-ocean situations, showing the greatest interaction between living species and the chemicals in their habitat. The book is of interest to scientists and students working on environmental issues.

This book is the proceedings of the 11th Kongsberg seminar, held at the Norwegian Mining Museum in the city of Kongsberg, about 70 km Southwest of Oslo. The Kongs berg district is known for numerous Permian vein deposits, rich in native silver. Mining activity in the area lasted for more than 300 years, finally ceasing in 1957. The first eight Kongsberg seminars, organized by professor Arne Bj0rlykke, now director of the Norwegian Geological Survey, were focused on ore-forming processes. These seminars have always been a meeting point for people with a variety of geological backgrounds. Since 1995, the Kongsberg seminars have focussed on geological processes, rather than on specific geological systems, and the selection of invited speakers has been strongly influenced by their interest in the dynamics of geological systems. In 1995 and 1996, various aspects of fluid flow and transport in rocks, were emphasized. The first "Kongsberg proceedings" (of the 1995 seminar) published by Chapman and Hall (Jamtveit and Yardley, 1997) contained 17 chapters dealing with a wide range of topics from field based studies of the effects of fluid flow in sedimentary and metamorphic rocks to computer simulations of flow in complex porous and fractured media. In 1997, the focus was changed to growth, and dissolution processes in geological systems."

Destructive plate margin magmagenesis is one of the most intensely studied and widely debated topics in the earth sciences at present. Calc-alkaline volcanic and plutonic rocks in orogenic settings exhibit such a diversity of composition and character that the subducted oceanic lithosphere, the overlying 'enriched' lithospheric mantle and the lower continental crust all have been advocated recently as the primary source region for island-arc and continental-margin basaltic to andesitic magmas. The role of the upper continental crust is also a matter of continuing controversy. It is clear that crustal contamination is a common, but not universal, feature of destructive plate margin magmatism. Whether this contamination is introduced at source by subduction-related processes or occurs during magma transit by bulk anatexis and magma mixing, selective contamination or coupled fractional crystallization-assimilation mechanisms is central to most current discussions of andesite petrogenesis. This book presents a series of papers which directly address these and other important geological and geochemical problems within the context of the Mesozoic-Cenozoic calc-alkaline magmatism characteristic of the Andean Cordillera of western South America. Although it is aimed primarily at postgraduate students and researchers familiar with the Andes, it is also a useful general reference for workers in other fields who wish to gain an insight into current thoughts, ideas and speculations on 'andesitic' magmatism at destructive plate margins.

One of the basic concepts of ocean biogeochemistry is that of an ocean with extremely active boundary zones and separation boundaries of extensive biochemical interactions. The areas of these zones are characterized by a sharp decrease of element migration intensity and consequently the decrease in their concentrations gave the boundaries for the naming of the geochemical barriers (Perelman, 1972). For the purposes of biogeo chemistry the most important ones are the boundaries of separation between river-sea, ocean-atmosphere, and water-ground (Lisitzin, 1983). The most complicated of them is the river-sea boundary, where the biogeochemical processes are the most active and complicated (Monin and Romankevich, 1979, 1984). The necessity of studying organic matter in rivers, mouth regions and adjoining sea aquatories has been repeatedly pointed out by v.I. Vernadsky (1934, 1960) who noted both the importance of registration of solid and liquid run-off of rivers, coming into the sea, and "the quality and the character of those elements, which are washed-down into the sea", emphasizing that "wash-down of organic substances into the sea is of great value". The interest in studying organic matter in natural waters, including river and sea waters, has grown considerably over the last 30 years. During this period essential material was collected on the content and composition of organic matter in various types of river waters of the USSR, and this was published in papers by B.A Scopintzev, AD. Semenov, M.V.

Manganese nodules were first discovered on the ocean floor 160 miles south-west of the Canary Islands on February 18, 1803, during the first complex oceano logical cruise of the Challenger. They surprised researchers by their unusual shape and also by their unusual chemical composition; nevertheless for many years after wards, they were considered merely as one of Nature's exotic marine tricks. After the Secpnd World War, a comprehensive investigation of the World Ocean started, and new data were obtained on a wide distribution of manganese nodules and their polymetallic composition, that made scientists consider nodules as one of the major characteristics of the deep oceanic zone. Recently, meaning since the 1960's, nodules have been recognized as a potential ore source, investigation of which is stimulated by the progressive depletion of land-based mineral resources. Several generations of scientists from various countries have contributed to the problem of exploration of manganese nodules on the ocean floor. Though the problem has been posed, it has not been solved yet because it required, in its turn, a scrutiny of some fundamental aspects such as composition, nature, accretion r'ate of nodules and retrieval of nodule fields. These problems have been discussed in thousands of papers and larger publications; see, in particulare, Mero, 1965; Horn, 1972; Morgenstein, 1973; Bezrukov, 1976; Glasby, 1977; Bischoff and Piper, 1979; Lalou, 1979; Manganese nodules, 1979; Varentsov, 1980; Cronan, 1980; Manganese nodules . . ., 1984, 1986."

Granulites are, by definition, rocks that crystallized at high temperatures. It is generally agreed that they were formed in regions where the geothermal gradient exceeded normal continental values. These rocks commonly display coronitic mineral fabrics which may be used to trace the thermal and geodynamic history of the continental crust. In the same way that eclogites provide information on the earliest stages of some orogenic episodes, granulites usually tell us about later events, including thermal anomalies, thermal reequilibration, CO streaming, crustal melting, and 2 differentiation of the continental crust. Their study is particularly important if we are to under stand the nature of the middle and lower continental crust. Consistent with the contributions I received, the contents of this volume fall into four general areas: Crustal Evolution, Regional Syntheses, F1uids and Petrological Equilibria, Geochemistry and Geophysics. These represent an up-to-date reflection of the centres of interest in the field of granulites. The first manuscripts arrived in September 1988 while the conference was held, the last contribution arrived in November 1989, more than a year later. I apologize to those who were prompt and took deadlines seriously, but I believe that it was worth waiting to secure a product covering most of the important aspects concerning granulite genesis. All papers were vetted by at least two reviewers. I would like to thank RJ. Arculus, N.T. Arndt, P. Barbey, SR. Bohlen, AM. Boullier, M. Brown, T. Chacko, 1.D. Clemens, K.C. Condie, J.C. Duchesne, C. Dupuy, w.G."

Observational, experimental and analytical data show that C60, larger fullerenes, and related structures of elemental carbon exist in interstellar space, meteorites, and on Earth and are associated with meteorite in impact events and in carbon-rich environments such as coals (shungite) and bitumen. The existence of natural fullerenes is at best contested and incompletely documented; realistically it is still controversial. Their presence in astronomical environments can be experimentally constrained but observationally they remain elusive. Fullerenes formation in planetary environments is poorly understood. They survived for giga-years when the environmental conditions were exactly right but even then only a fraction of their original abundance survived. Natural fullerenes and related carbon structures are found in interstellar space, in carbonaceous meteorites associated with giant meteorite impacts (including at the Cretaceous-Tertiary boundary) as well as in soot, coal and natural bitumen.
This book provides an up-to-date summary of the state of knowledge on natural fullerenes occurrences and the laboratory techniques used to determine their presence at low concentration in rock samples. It demonstrates that natural fullerenes exist and should be searched for in places not yet considered such as carbon-containing deep-seated crustal rocks.
"Natural Fullerenes and Related Structures of Elemental Carbon" is written for professional astronomers, meteoriticists, earth and planetary scientists, biologists and chemists interested in carbon and hydrocarbon vapor condensation. It is an invaluable resource for practicing research scientists and science teachers in Earth and Planetary Science, Astronomy and Carbon Science.

Following release to the environment, synthetic chemicals may be degraded by biotic and abiotic processes. The degradation of the chemical can follow a plethora of pathways and a range of other substances can be formed via thesedifferentpathways(e.g.[1]).Anumberoftermshavebeenusedforthese substances including metabolites, degradates and transformation products - in this book we use the term transformation products. While we often know a lot about the environmental properties and effects of the parent synthetic chemical, we know much less about the transformationproducts. Transformationproductscanbehave very differently fromtheparent c- pound (e.g. [2]). For example, selected transformation products are much more persistent than their associated parent compound in soils, waters and sediments andsomemaybetransported aroundthelocal,regionalandglobal environmentstoadifferentextentthantheparentcompound.Transformation products can also have very different toxicities than the parent compound (e.g. [3]) and in some cases transformation products can be orders of mag- tude more toxic than their parent compound; although this situation is rare. The environmental risks of transformation products can therefore be very different than the risks of the parent compound. Thepotentialenvironmentalimpactsoftransformationproductsarerec- nised by many regulatory assessment schemes. For example, in the EU, pes- cideproducersarenotonlyrequiredtoassessthefateandeffectsoftheparent pesticide but are also required to assess the potential adverse effects of major metabolitesandminor metabolitesthat aredeemed tobeofconcern[4]. S- ilar requirements also exist for new human and veterinary pharmaceuticals and biocides (e.g. [5]). However, for many older substances and many other substance classes (e.g. industrial chemicals), data on the environmental risks of transformationproductscan be limited or non-existent.

Hydrogeology of Crystalline Rocks deals with deep groundwater in the granite and gneiss basement of the continents. It has become evident during the past years that highly mineralized water is present in an interconnected fracture network of the basement. Thus, the upper part of the crust of the continents can be viewed as an aquifer and investigated with tools common in hydrogeology. This book presents accounts on water-conducting features of crystalline rocks and summarizes the hydraulic properties of the basement. The volume includes reviews, new data and research on the often remarkable chemical composition of deep groundwater. Microbial processes in the deep basement aquifer are probably more important than previously thought. Two contributions focus on this recent extension of research of the biosphere to greater depth in the Earth. This book represents the first multidisciplinary and integrated account of deep groundwater hydrology in crystalline basement. It is of interest to hydrologists and hydrogeologists working with water in crystalline rocks, but also to solid earth geophysicists, geochemists and petrologists with an interest in fluids in the crust. Scientists involved in nuclear waste disposal programs and geothermal energy development will find a wealth of stimulating ideas in this volume.