The founders of geology at the beginning of the last century were suspicious oflaboratories. Hutton's well-known dictum illustrates the point: "There are also superficial reasoning men . . . they judge of the great oper ations of the mineral kingdom from having kindled a fire, and looked into the bottom of a little crucible. " The idea was not unreasonable; the earth is so large and its changes are so slow and so complicated that labo ratory tests and experiments were of little help. The earth had to be studied in its own terms and geology grew up as a separate science and not as a branch of physics or chemistry. Its practitioners were, for the most part, experts in structure, stratigraphy, or paleontology, not in silicate chemistry or mechanics. The chemists broke into this closed circle before the physicists did. The problems of the classification of rocks, particularly igneous rocks, and of the nature and genesis of ores are obviously chemical and, by the mid- 19th century, chemistry was in a state where rocks could be effectively analyzed, and a classification built up depending partly on chemistry and partly on the optical study of thin specimens. Gradually the chemical study of rocks became one of the central themes of earth science."

The proposal of the School was made in 1998 to three institutions, which responded enthusiastically: The Abdus Salam International Centre for Theoretical Physics (ICTP), its main co-sponsor, the International Centre for Genetic Engineering and Biotechnology, both in Trieste, Italy, and the Chancellor's Office, Universidad Simon Bolfvar (USB). The secretarial and logistic support was provided in Trieste by the ICTP and in Caracas by USB and the IDEA Convention Center. In addition the event was generously supported by the following institutes, agencies, foundations and academies: NASA Headquarters, European Space Agency, TALVEN Programme, (Delegacion Permanente de Venezuela ante la UNESCO), The SETI Institute, Centro Latinoamericano .de Ffsica, The Third World Academy of Sciences, Academia de Ciencias Ffsicas, Matematicas y Naturales, Red Latinoamericana de Biologfa, The Planetary Society, The Latin American Academy of Sciences (Fondo ACAL), Alberto Vollmer Foundation, Inc, Fundacion J. Oro, Associated to the Catalonian Research Foundation, Red Latinoamericana de Astronomfa and Colegio Emil Friedman. A total of 36 lectures were delivered by 20 lecturers, of which 14 were from the following countries: Argentina, Mexico, Italy, Spain and the USA. Six lecturers were from the host country. In addition there were 5 chairpersons from the host country that were not participants; two participants acted as chairpersons (Pedro Benitez and Tomas Revilla).

Carbon dioxide and other `greenhouse' gases are increasing in the atmosphere due to the burning of fossil fuels, the destruction of rain forests, etc., leading to predictions of a gradual global warming which will perturb the global biosphere. An important process which counters this trend toward potential climate change is the removal of carbon dioxide from the surface ocean by photosynthesis. This process packages carbon in phytoplankton which enter the food chain or sink into the deep sea. Their ultimate fate is a `rain' of organic debris out of the surface-mixed layer of the ocean. On a global scale, the mechanisms and overall rate of this process are poorly known. The authors of the 25 papers in this volume present their state-of-the-art approaches to quantifying the mechanisms by which the `rain' of biogenic debris nourishes deep ocean life. Prominent deep sea ecologists, geochemists and modelers address relationships between data and models of carbon fluxes and food chains in the deep ocean. An attempt is made to estimate the fate of carbon in the deep sea on a global scale by summing up the utilization of organic matter among all the populations of the abyssal biosphere. Comparisons are made between these ecological approaches and estimates of geochemical fluxes based on sediment trapping, one-dimensional geochemical models and horizontal (physical) input from continental margins. Planning interdisciplinary enterprises between geochemists and ecologists, including new field programs, are summarized in the final chapter. The summary includes a list of the important gaps in understanding which must be addressed before the role of the deep-sea biota in global-scale processes can be put in perspective.

This volume focuses on isotopic signatures of volatile elements as tracers for evolutionary processes during the formation of the Sun and the planets from an interstellar molecular cloud and, in turn, illuminates how the isotopic compositions of the present-day solar system objects have been established.
The book is an integrated collection of articles by experts in planetary science, solar and plasma physics, astrophysics, mineralogy and chemistry that met for an interdisciplinary workshop at the International Space Science Institute in Bern in January 2002. The authors present analyses of isotope abundance ratios for volatile elements in the sun, planets, satellites, comets, meteorites and interplanetary dust particles, as well as a review of isotopic ratios in star-forming interstellar clouds. This provides insight into the physical and chemical processes in the pre-solar molecular cloud that collapsed to form the Sun and the solar accretion disk. Furthermore, information is presented on dynamical processes and conditions inside this protoplanetary disk, in particular the degree of reprocessing of interstellar solid material, the formation of solids inside the disks, and the formation of terrestrial and giant planets and their satellites. Isotopic fractionation processes discussed in this book include chemical reactions such as ion-molecule and photochemical reactions, nuclear processes inside the sun and in its atmosphere, plasma processes, gravitational escape of gases from planetary atmospheres exposed to the solar wind and solar radiation, thermodynamic processes, a variety of accretion and adsorption processes and mixing of material from the interstellar environment with the material of the evolving solar system.
The volume is intended to provide active researchers in the fields of planetary science and space physics with an up-to-date status report on the topic, and also to serve graduate students with introductory material into the field.

The analysis of materials containing several elements used to be a difficult problem for analytical chemists, so a well established sequence of wet chemical qualitative tests were performed to ensure each element was detected. Quantitative tests could then be carried out on the sample, according to the range of elements present. Most analytical chemists were very familiar with these techniques, having been taugth them from a very early stage in their education and careers. The analytical chemist can now call on a range of specialist instrumental techniques which can detect the presence of many elements, often simultaneously, and often quantitatively, providing rapid results on samples which, in the past, could take days. The drawback is that the instruments tend to be expensive, suited to particular sample types or matrices and complex in both setting up and in the interpretation of results. Furthermore the general analytical chemist may have access and familiarity with only one or two methods. Written by an international team of contributors, each experts in their particular fields, this book familiarizes analytical chemists with the range of elemental analysis techniquers, to enable them to specify the most appropriate test for any given sample. In addition, it contains important chapters on sample preparation and quality control, essential elements in obtaining accurate and reliable analytical results. As such, this book will be essential reading for all analytical chemists. The techniques of elemental analysis are important in many other disciplines, so the book will be of particular interest to those commissioning a wide range of analytical measurements, such as chemists, geologists, environmental scientists and biologists. The breadth and depth of coverage will also make the book very useful for advanced students.

Dr. Heinonen reviews and critically evaluates the scientific literature on the biological role of inorganic pyrophosphate (PPi ) published from 1940 to the end of 1999. He describes and classifies all known biochemical reactions that produce Ppi; describes and evaluates all published methods used in biological Ppi; and compiles and critically evaluates information on the concentration of PPi (with the conclusion that, contrary to common belief, PPi exists throughout the living world in rather high concentrations). Many reactions in which PPi is used as a biochemical energy source instead of ATP have been described in recent decades, especially in bacteria, protists, and plants. These reactions are evaluated from the bioenergetic and regulatory points of view. Also considered is the possible role of PPi as a source of biochemical energy in the primitive phases of life, before ATP. Data is presented on the regulatory role of PPi in living systems, such as activities of enzymes, fidelity of syntheses of macromolecules, and proliferation of cells. PPi may also regulate the formation and dissolution of bone as well as pathologic calcification of soft tissues and the formation of urinary stones. The formation of calcium pyrophosphate dihydrate crystals in the extracellular fluids of joints cause the disease called pseudogout. Biological Role of Inorganic Pyrophosphate book is a unique and invaluable source of references (about 1120) and summarized data for professionals who study or plan to study the role of PPi in living systems. Many different branches of science (biochemistry, microbiology, bioenergetics, plant physiology, parasitology, evolution, orthopedics, rheumatology) have involvement with PPi. This book sums up available knowledge in one place and will help scientists cross disciplinary boundaries.

Oceanographic discontinuities (e. g. frontal systems, upwelling areas, ice edges) are often areas of enhanced biological productivity. Considerable research on the physics and biology of the physical boundaries defining these discontinues has been accomplished (see [I D. The interface between water and sediment is the largest physical boundary in the ocean, but has not received a proportionate degree of attention. The purpose of the Nato Advanced Research Workshop (ARW) was to focus on soft-sediment systems by identifying deficiencies in our knowledge of these systems and defining key issues in the management of coastal sedimentary habitats. Marine sediments play important roles in the marine ecosystem and the biosphere. They provide food and habitat for many marine organisms, some of which are commercially important. More importantly from a global perspective, marine sediments also provide "ecosystem goods and services" [2J. Organic matter from primary production in the water column and contaminants scavenged by particles accumulate in sediments where their fate is determined by sediment processes such as bioturbation and biogeochemical cycling. Nutrients are regenerated and contaminants degraded in sediments. Under some conditions, carbon accumulates in coastal and shelf sediments and may by removed from the carbon cycle for millions of years, having a potentially significant impact on global climate change. Sediments also protect coasts. The economic value of services provided by coastal areas has recently been estimated to be on the order of $12,568 9 10 y" [3J, far in excess of the global GNP.

Here is a collection of papers from BIOGEOMON, The Fourth International Symposium on Ecosystem Behavior. The contributions address a wider-than-ever range of concerns: aspects of catchment monitoring and modeling; nitrogen transformations and processes; stable and radiogenic isotopes; biogeochemistry of restored ecosystems; and the dynamics of such chemicals as mercury and phosphorous, among many other topics.

Following the long-standing tradition of the Seeheim-Workshops on Mossbauer Spectroscopy, 1978, 1983, 1988, 1994 always held in the same traditional place of the Lufthansa Training Center in Seeheim/Germany, the 5th workshop took place in 2002. The main topics covered are:
-new technical developments such as the techniques of Nuclear Inelastic Scattering (NIS) and Nuclear Forward Scattering (NFS) of Synchrotron Radiation and their applications in studying lattice dynamics, magnetism and surface phenomena;
-investigations of molecular structural and bonding properties in biomolecules and coordination compounds;
-problems related to geochemistry and earth sciences;
-applications of Mossbauer spectroscopy in molecular magnetism and photomagnetism.
The book will serve as a source of great actuality to physicists, chemists and geoscientists employing the Mossbauer effect and other hyperfine interaction techniques to explore solid state properties of bulk materials as well as surface phenomena."

This Special Issue of Water, Air and Soil Pollution offers original contributions from BIOGEOMON, an international symposium on ecosystem behavior and the evaluation of integrated monitoring of small catchments, held in Prague, Czech Republic, in September 1993. The meeting attracted nearly 200 scientists from 27 countries on five continents. BIOGEOMON was a loose continuation of another international meeting, GEOMON, which was held in Prague in 1987. Both sym posia provided a forum for the discussion of ideas on environmental problems in western and eastern Europe, with important contributions from the American continent. With the dramatic collapse of the iron curtain, it was our hope that more so than GEOMON, BIOGEOMON would provide opportunities for the free exchange of ideas, fostering the development of research collaborations between its participants. With international openness comes the increasing realization that every indus trialized nation has its own legacy of environmental degradation. Anthropogenic impacts differ in severity and scale; air and water transport of pollutants transform local impacts into regional and global ones, ignoring political boundaries and eco nomic differences. Environmental consequences of anthropogenic activities often are detectable at the ecosystem level. Thus, the challenge of ecosystem science, and to the individuals who practice it, is to develop a comprehensive understanding of ecosystem function in the past and at present, and to apply such understanding toward minimizing future insults to the local, regional, and global environment.

The workshop "From Dust to Terrestrial Planets" was initiated by a working group of planetary scientists invited to ISSI by Johannes Geiss in November 1997. The group split to focus on three topics, one of which was the history of the early solar system, including the formation of the terrestrial planets in the inner solar system. Willy Benz, Gunter Lugmair, and Frank Podosek were invited to convene planetary scientists, astrophysicists, and cosmochemists to synthesize the current knowledge on the origin and evolution of our inner planetary system. The convenors raised the interest of scientists from all over the world in the detailed assessment of the available astronomical, chronological, geochemical and dynamical constraints of the first period of inner solar system evolution. In partic ular, this included appraisal of the newest results from astronomical observations by the Hubble Space Telescope, the Infrared Space Observatory, and other space and ground-based facilities of solar-like systems and nebular disks, possibly repre senting early stages of the solar accretion disk and planet formation. At the same time, the current models of the origin, evolution, transport, and accretion processes of circum stellar disks were presented. This included the new insights provided by the recent discovery of extrasolar giant planets, which were considered insofar as they are relevant to the overall dynamics of the inner part of the solar system.

As this is the first general textbook for the field published in over twenty years, the editors have taken great care to make sure coverage is comprehensive. Diagenesis of organic matter, kerogens, exploration for fossil fuels, and many other subjects are discussed in detail to provide faculty and students with a thorough introduction to organic geochemistry.

Fission track dating is based on the microscopic observation and counting of etchable tracks left by the spontaneous fission of uranium in minerals. Since its development in 1963 the method attracted a steadily growing interest from geologists and geochronologists throughout the world. Apart from its relative experimental ease the success must be mainly ascribed to the specific ability of the method of unravelling the thermal and tectonic history of rocks, a potential which only became fully exploited during the last decade with the systematic introduction of track size analysis. The present work is the first one to deal entirely with fission track dating covering all of its aspects from the origin of the fission tracks, the basis of track etching and fading, the various dating techniques as well as practical procedures and the geologic interpretation to the most recent applications in geology and archaeology.

The future of the Common Fisheries Policy depends on progress in the relevant areas of research. This applies to the whole range of management decisions, where precise, reliable and complete data are essential to inform those who must decide on the pursuit of existing activities, especially in the area of maritime fisheries, and the development of promising new activities such as aquaculture. Every day the Director-General of DG XIV requires more and more information to prepare decisions which will affect the future of all those in the Community who are dependent on fishing and aquaculture. There is thus a high level of direct demand from DG XIV. Over and above this immediate and specific requirement for short- and medium-term applications, research affects the competitivity of the Community. This is one area which favours the collaboration across frontiers of all those who seek to advance knowledge. But although DG XIV is uniquely placed to appreciate the importance of research into fisheries and aquaculture, there is no question of succumbing to the temptation to directly control the scope of research or its conduct. The notion of subsidiarity can best be understood by examining the existing structures in the Member States. The Commission must act first and foremost as a catalyst, by promoting the circulation of information and the coordination of research programmes.

John E. Mylroie and Ira D. Sasowsky' Caves occupy incongruous positions in both our culture and our science. The oldest records of modem human culture are the vivid cave paintings from southern France and northern Spain, which are in some cases more than 30,000 years old (Chauvet, et ai, 1996). Yet, to call someone a "caveman" is to declare them primitive and ignorant. Caves, being cryptic and mysterious, occupied important roles in many cultures. For example, Greece, a country with abundant karst, had the oracle at Delphi and Hades the god of death working from caves. People are both drawn to and mortified by caves. Written records ofcave exploration exist from as early as 852 BC (Shaw, 1992). In the decade of the 1920's, which was rich in news events, the second biggest story (as measured by column inches of newsprint) was the entrapment of Floyd Collins in Sand Cave, Kentucky, USA. This was surpassed only by Lindbergh's flight across the Atlantic (Murray and Brucker, 1979).

A significant advance in climatological scholarship, Tectonic Uplift and Climate Change is a multidisciplinary effort to summarize the current status of a new theory steadily gaining acceptance in geoscience circles: that long-term cooling and glaciation are controlled by plateau and mountain uplift. Researchers in many diverse fields, from geology to paleobotany, present data that substantiate this hypothesis. The volume covers most of the key, dramatic transformations of the Earth's surface.

This is the first book to deal specifically with the procedures used in the analysis of structural relationships and the determination of structural successions in complexly deformed rocks such as migmatites and gneisses. The establishment of structural successions enables: The rigorous control of the dating of specific events in the deformational history by constraining the sites of the dated rocks within the structural succession; The establishment of the time span of orogenic events throughout the structural succession, and the rate of orogenic processes;Their comparison to be used as a basis for correlation between dismembered and separated crustal segments in continental reconstructions;The resolution of the complex relationships between deformed ore bodies and host rocks in high grade terranes, and hence determination of the structural control of ore bodies, an essential part of any successful geological exploration, and a precondition to efficient exploitation. With its new approach, and the use of practical field examples from various parts of the world, this highly illustrated work will form an invaluable reference resource for postgraduates, lecturers and researchers in the structural and isotope geology of high-grade metamorphic terranes, as well as for exploration and survey geologists working in the field. Dr Alaric M. Hopgood who holds an Honorary Readership at the University of St Andrews, Scotland, was a Reader in the Department of Geology there until 1995.

The chemical interaction of water and rock is one of the most fascinating an d multifaceted process in geology. The composition of surface water and groundwater is largely controlled by the reaction of water with rocks and minerals. At elevated temperature, hydrothermal features, hydrothermal 0 re deposits and geothermal fields are associated with chemical effects of water-rock interaction. Surface outcrops of rocks from deeper levels in the crust, including exposures of lower crustal and mantle rocks, often display structures that formed by interaction of the rocks with a supercritical aqueous fluid at very high pT conditions. Understanding water-rock interaction is also of great importance to applied geology and geochemistry, particularly in areas such as geothermal energy, nuclear waste repositories and applied hydrogeology. The extremely wide-ranging research efforts on the universal water-rock interaction process is reflected in the wide diversity of themes presented at the regular International Symposia on Water-Rock Interaction (WRI). Because of the large and widespread interest in water-rock interaction, the European Union of Geosciences organized a special symposium on "water-rock interaction" at EUGI0, the biannual meeting in Strasbourg 1999 convened by the editors of this volume. In contrast to the regular WRI symposia addressed to the specialists, the EUG 10 "water-rock interaction" symposium brought the subject to a general platform This very successful symposium showed the way to the future of water-rock reaction research.

Every year Earth is bombarded with about 40,000 tons of extraterrestrial material. This includes microscopic cosmic dust particles shed by comets and asteroids in outer space, meteorites, as well as large comets and asteroids that have led to catastrophic events in the geologic past. Originally considered only a curiosity, extraterrestrial matter found on Earth provides the only samples we have from comets, asteroids and other planets. Only recently mankind has started to actively collect extraterrestrial matter in space (Apollo program, Stardust mission) rather than to wait for its delivery to Earth. Still, most of our knowledge of the origin and evolution of our solar system is based on careful studies of meteorites, cosmic dust, and traces of large impact events in the geologic record such as the mass extinction that terminated the Cretaceous Period and led to the extinction of the dinosaurs. This book summarizes our current knowledge of the properties, origin, orbital evolution and accretion mechanism of extraterrestrial matter accreted on Earth and sheds light on accretion processes and fluxes in the geologic past. The chapters in the first part of the book are arranged in order to follow extraterrestrial matter from its origin in space, its orbital evolution on its way to Earth, its interaction with the Earth magnetosphere and atmosphere to its more or less violent collision with the Earth's surface. In the second part of the book several chapters deal with the present?day flux of cosmic dust and meteorites to Earth. Finally, several chapters deal with the reconstruction of the accretion history of extraterrestrial matter on Earth, starting with the most recent geologic past and ending with the very early, violent accretion period shortly after the formation of Earth, Moon and other solid planets in our solar system.

Research of the origins of life in connection with a marine environment started at the end of the seventies, when the black smokers' in the Pacific were discovered and the Red Sea deep hydrothermal brines were found to be a fruitful environment for abiotic synthesis of life precursors. For a while this research was categorised under the heading chemistry', but in less than a decade the topic became fully integrated into the science of 'oceanography'. The Scientific Committee on Oceanographic Research (SCOR) initiated Working Group 91: Chemical Evolution and Origin of Life in Marine Hydrothermal Systems'. This volume contains the final report of this working group.

Anoxic basins are ofgreat interest to oceanographersofall disciplines. Theirextreme conditionsresult from acombinationofhigh oxygen utilization and restricted circulation. It is necessery to understand present -day anoxic environments ifwe are to understand the early evolution of the oceans (e.g. SiIlen, 1965). Sarmiento et al.(1988a) explored the causes of anoxia in the global ocean, which is in effect a "closed" basin and in marginal seas such as the Eastern Mediterranean (Sarmiento et al. 1988b). Anoxic conditions have been proposed toexist in various ocean basins at different times in the geological past (e.g. the Crataceous period; Weissert, 1981) and possibly as recent as the last glacial maximum (e.g., Sarmiento and Toggweiler,1984). The modern Black Sea has been considered as the type anoxic basin. It is the world's 2 3 largest permanaently anoxic basin (area = 423,000 km; volume = 534,000 km ) and is thought to be aquasi-steady state system. It is extremely isolated from the rest ofthe world's oceans. Only the narrow and shallow Bosporus Strait provides water exchange with the Mediterranean. Concentrationsofhydrogen sulfide reach valuesof350 Mm in the deep water and the oxygen-hydrogen sulfide Interface exists between 80 and 200m waterdepth. The hydrographic regime is characterized by low salinity surface water of riverine origin overlying high salinity deep waterofMediterranean origin. Asteep pycnocline is the primary phycical barrier to mixing and is the origin of the stability of the anoxic interface.

Since their first industrial use polymers have gained a tremendous success. The two volumes of "Polymers - Opportunities and Risks" elaborate on both their potentials and on the impact on the environment arising from their production and applications. Volume 11 "Polymers - Opportunities and Risks I: General and Environmental Aspects" is dedicated to the basics of the engineering of polymers - always with a view to possible environmental implications. Topics include: materials, processing, designing, surfaces, the utilization phase, recycling, and depositing. Volume 12 "Polymers - Opportunities and Risks II: Sustainability, Product Design and Processing" highlights raw materials and renewable polymers, sustainability, additives for manufacture and processing, melt modification, biodegradation, adhesive technologies, and solar applications. All contributions were written by leading experts with substantial practical experience in their fields. They are an invaluable source of information not only for scientists, but also for environmental managers and decision makers.

The management and disposal of radioactive wastes are key international issues requiring a sound, fundamental scientific basis to insure public and environmental protection. Large quantities of existing nuclear waste must be treated to encapsulate the radioactivity in a form suitable for disposal. The treatment of this waste, due to its extreme diversity, presents tremendous engineering and scientific challenges. Geologic isolation of transuranic waste is the approach currently proposed by all nuclear countries for its final disposal. To be successful in this endeavor, it is necessary to understand the behavior of plutonium and the other actinides in relevant environmental media. Conceptual models for stored high level waste and waste repository systems present many sCientific difficulties due to their complexity and non-ideality. For example, much of the high level nuclear waste in the US is stored as alkaline concentrated electrolyte materials, where the chemistry of the actinides under such conditions is not well understood. This lack of understanding limits the successful separation and treatment of these wastes. Also, countries such as the US and Germany plan to dispose of actinide bearing wastes in geologic salt deposits. In this case, understanding the speciation and transport properties of actinides in brines is critical for confidence in repository performance and risk assessment activities. Many deep groundwaters underlying existing contaminated sites are also high in ionic strength. Until recently, the scientific basis for describing actinide chemistry in such systems was extremely limited."

Accelerating progress in the application of radioactive and stable isotope analysis to a varied range of geologicla and geochemical problems in geology has required a complete revision of Isotopes in the Earth Sciences, published in 1988. This new book comprises four parts: the first introduces isotopic chemistry and examines mass spectroscopic methods; the second eeals with radiometric dating methods. Part Three examines the importance of isotopes in climato-environmental studies, and increasingly significant area of research. The last part looks at extra-terrestrial matter, geothermometry and the isotopic geochemistry of the Earth's lithosphere. Post-graduate and post-doctoral researchers in geochemistry, as well as final year undergraduates in the earth and environmental sciences, will find Radioactive and Stable Isotope Geology an invaluable, uo-to-date and thorough treatment of the theory and practice of isotopie geology.

Solid-solution equilibria of marine evaporites are important in a wide range of science and technology. However, the data had not yet been summarized in a form that is at the same time comprehensive and permits to understand how the quinary seawater system builds up from its bounding systems. Thus the goal of the present volume is at the same time scientific and educational. The understanding of solid-solution equilibria of the various systems with respect to dissolution, precipitation and transformation of solids, their application to the evolution of brines, and a fast access to data is a necessary requirement for any modelling, especially in Geoscience. Another goal is to show the avail ability of data. Unfortunately, though solubility data are numereous there are substantial gaps, especially with respect to high temperatures. But also up to about 100 0 C data are missing for some of the systems so that they cannot be described entirely. Based on the present volume further work on the solubili ties of the minerals of marine evaporites may be promoted. The data have been viewed and collected over several years by the first author. The second author entered the preparation of the volume when it was realized that besides graphics and tables a fast access to data was required. Although both authors are responsible for the whole volume, responsibility is weighted somewhat differently for the various parts."