Chemical additives are used to enhance the properties of many industrial products. Since their release into the environment is a potential risk for man and nature, their fate and behavior have been investigated in the framework of the European Union-funded project RISKCYCLE. The results are presented in two volumes, Global Risk-Based Management of Chemical Additives I: Production, Usage and Environmental Occurrence and Global Risk-Based Management of Chemical Additives II: Risk-Based Assessment and Management Strategies. This book is the second of the two volumes and features two main parts. In the first part, experts in the field discuss different models related to the assessment of the potential risks posed by chemical additives and analyze their benefits and drawbacks. In the second part, specific case studies in which the models have been applied are presented and the reliability of the models is evaluated. This volume is an invaluable source of information for scientists and governmental agencies dealing with the risk assessment of chemicals on a global scale.

This book is a collection of all the lectures by the professors attending the 3rd "Interna tional School on Marine Chemistry" held in Ustica (Palermo, Italy, September 2000), under the auspices of the United Nations and the Italian Chemical Society. The School was organized by the University of Palermo in co-operation with the Natural Marine Reserve of Ustica Island. The Organising Committee of the School wishes to thank the University of Messina, the University of Roma "La Sapienza: ' the Italian University Consortium of Environ mental Chemistry, and the Marine Reserve of Ustica Island for their financial support to the School. This book has been printed with the financial support of the Environmental Re search Centre CIRITA of the University of Palermo. thank all the professors whose outstanding scientific contributions have The editors made it possible to publish this book. Professor Antonio Gianguzza Professor Ezio Pelizzetti Professor Silvio Sammartano Contents Part I Biogeochemical Processes at the Air-Water and Water-Sediment Interface .............................................. ."

"Distribution and Transformation of Nutrients and Eutrophication in Large-scale Lakes and Reservoirs: The Three Gorges Reservoir" presents key findings on early eutrophication in large-scale lakes and reservoirs, providing readers with an overview of lake management problems and the tools that can be applied to solve them. The broad spectrum of available tools is presented in detail, including environmental technological methods, ecotechnological methods and the application of models to determine the best management strategy.

The book is intended for environmental engineers and researchers in the fields of environmental science and ecological chemistry.

Professor Zhenyao Shen, Professor Junfeng Niu and Associate Professor Ying Wang work at the School of Environment, Beijing Normal University, China. Dr. Hongyuan Wang works at Chinese Academy of Agricultural Sciences, China. Dr. Xin Zhao works at Changjiang River Scientific Research Institute, China.

Radiography, the use of penetrating radiation to produce shadow images of the internal structure of materials, has been with us since Roentgen made his discovery of x rays in 1895. However, applications of radiography in the earth sciences and in the related field of soils engineering have, until recent ly, been slow to develop. Bruhl reported optimistically on applications in paleontology as early as 1896 and there have been additional reports through the years. However, very few paleontologists adopted the method and the significant literature is relatively restricted. In soil mechanics, Gerber observed the movement oflead pellets in sand during a plate-bearing test as early as 1929. Gradual ly, radiography was applied to other tests including those on footings, compaction of soils, strain in sand, effects of pile penetration, and displace ments under moving wheel loads. Recently, such work has broadened into much varied and sophisticated research. Applications in geology may be dated to Hamblin's work on rocks re ported in 1962. His demonstration that many fine textural and structural details can be observed in slices of rock led to experimentation by others on unconsolidated sediments and soils. Work is now expanding at an un precedented rate. In some operations, such as the logging of oceanographic cores, it is already a routine process. The advantages of radiography lie in its nondestructive nature and its ability to reveal features that sometimes cannot be seen in any other way."

Taphonomic bias is a pervasive feature of the fossil record. A pressing concern, however, is the extent to which taphonomic processes have varied through the ages. It is one thing to work with a biased data set and quite another to work with a bias that has changed with time. This book includes work from both new and established researchers who are using laboratory, field and data-base techniques to characterise and quantify the temporal and spatial variation in taphonomic bias. It may not provide all the answers but it will at least shed light on the right questions.

The twelve chapters of this volume aim to provide a complete manual for using noble gases in terrestrial geochemistry, covering applications which range from high temperature processes deep in the Earth's interior to tracing climatic variations using noble gases trapped in ice cores, groundwaters and modern sediments. Other chapters cover noble gases in crustal (aqueous, CO2 and hydrocarbon) fluids and laboratory techniques for determining noble gas solubilities and diffusivities under geologically relevant conditions. Each chapter deals with the fundamentals of the analysis and interpretation of the data, detailing sampling and sampling strategies, techniques for analysis, sources of error and their estimation, including data treatment and data interpretation using recent case studies.

The founders of geology at the beginning of the last century were suspicious oflaboratories. Hutton's well-known dictum illustrates the point: "There are also superficial reasoning men . . . they judge of the great oper ations of the mineral kingdom from having kindled a fire, and looked into the bottom of a little crucible. " The idea was not unreasonable; the earth is so large and its changes are so slow and so complicated that labo ratory tests and experiments were of little help. The earth had to be studied in its own terms and geology grew up as a separate science and not as a branch of physics or chemistry. Its practitioners were, for the most part, experts in structure, stratigraphy, or paleontology, not in silicate chemistry or mechanics. The chemists broke into this closed circle before the physicists did. The problems of the classification of rocks, particularly igneous rocks, and of the nature and genesis of ores are obviously chemical and, by the mid- 19th century, chemistry was in a state where rocks could be effectively analyzed, and a classification built up depending partly on chemistry and partly on the optical study of thin specimens. Gradually the chemical study of rocks became one of the central themes of earth science."

The Thirteenth International Conference on Basement Tectonics was held on the campus of Virginia Polytechnic Institute and State University in Blacksburg, Virginia from June 2 -6, 1997. The oral presentations and discussions over three days covered a wide range of topics, and provided the international audience with a perspective on scientific efforts underway around the world. The conference participants were able to attend two separate field trips: (I) a pre-conference trip guided by Professor Robert Hatcher of the University of Tennessee, Knoxville, examined the Basement rocks in the North Carolina -Tennessee region of the Appalachian Mountains, and (2) a mid-conference field trip guided by A.K. Sinha, convener of the conference, allowed participants to examine the complex rock associations and structures of the> 1000 m.y. old basement rocks in Virginia. Both the field trip guidebooks and abstract volumes were published for the conference. The meeting brought together scientists from more than 14 countries. Their participation, and the fiscal success of the meeting would not have been possible without the support of the Department of Geological Sciences, the College of Arts and Sciences (VPI&SU) and the Basement Tectonics Association. Their support is gratefully acknowledged. As Chairman of the Organizing Committee, I would like to thank Margie Sentelle, Jay Thomas, Peter Welch, and Barry Robinson for the smooth operation of the conference.

Following the long-standing tradition of the Seeheim-Workshops on Mossbauer Spectroscopy, 1978, 1983, 1988, 1994 always held in the same traditional place of the Lufthansa Training Center in Seeheim/Germany, the 5th workshop took place in 2002. The main topics covered are:
-new technical developments such as the techniques of Nuclear Inelastic Scattering (NIS) and Nuclear Forward Scattering (NFS) of Synchrotron Radiation and their applications in studying lattice dynamics, magnetism and surface phenomena;
-investigations of molecular structural and bonding properties in biomolecules and coordination compounds;
-problems related to geochemistry and earth sciences;
-applications of Mossbauer spectroscopy in molecular magnetism and photomagnetism.
The book will serve as a source of great actuality to physicists, chemists and geoscientists employing the Mossbauer effect and other hyperfine interaction techniques to explore solid state properties of bulk materials as well as surface phenomena."

As this is the first general textbook for the field published in over twenty years, the editors have taken great care to make sure coverage is comprehensive. Diagenesis of organic matter, kerogens, exploration for fossil fuels, and many other subjects are discussed in detail to provide faculty and students with a thorough introduction to organic geochemistry.

The proposal of the School was made in 1998 to three institutions, which responded enthusiastically: The Abdus Salam International Centre for Theoretical Physics (ICTP), its main co-sponsor, the International Centre for Genetic Engineering and Biotechnology, both in Trieste, Italy, and the Chancellor's Office, Universidad Simon Bolfvar (USB). The secretarial and logistic support was provided in Trieste by the ICTP and in Caracas by USB and the IDEA Convention Center. In addition the event was generously supported by the following institutes, agencies, foundations and academies: NASA Headquarters, European Space Agency, TALVEN Programme, (Delegacion Permanente de Venezuela ante la UNESCO), The SETI Institute, Centro Latinoamericano .de Ffsica, The Third World Academy of Sciences, Academia de Ciencias Ffsicas, Matematicas y Naturales, Red Latinoamericana de Biologfa, The Planetary Society, The Latin American Academy of Sciences (Fondo ACAL), Alberto Vollmer Foundation, Inc, Fundacion J. Oro, Associated to the Catalonian Research Foundation, Red Latinoamericana de Astronomfa and Colegio Emil Friedman. A total of 36 lectures were delivered by 20 lecturers, of which 14 were from the following countries: Argentina, Mexico, Italy, Spain and the USA. Six lecturers were from the host country. In addition there were 5 chairpersons from the host country that were not participants; two participants acted as chairpersons (Pedro Benitez and Tomas Revilla).

Fission track dating is based on the microscopic observation and counting of etchable tracks left by the spontaneous fission of uranium in minerals. Since its development in 1963 the method attracted a steadily growing interest from geologists and geochronologists throughout the world. Apart from its relative experimental ease the success must be mainly ascribed to the specific ability of the method of unravelling the thermal and tectonic history of rocks, a potential which only became fully exploited during the last decade with the systematic introduction of track size analysis. The present work is the first one to deal entirely with fission track dating covering all of its aspects from the origin of the fission tracks, the basis of track etching and fading, the various dating techniques as well as practical procedures and the geologic interpretation to the most recent applications in geology and archaeology.

The future of the Common Fisheries Policy depends on progress in the relevant areas of research. This applies to the whole range of management decisions, where precise, reliable and complete data are essential to inform those who must decide on the pursuit of existing activities, especially in the area of maritime fisheries, and the development of promising new activities such as aquaculture. Every day the Director-General of DG XIV requires more and more information to prepare decisions which will affect the future of all those in the Community who are dependent on fishing and aquaculture. There is thus a high level of direct demand from DG XIV. Over and above this immediate and specific requirement for short- and medium-term applications, research affects the competitivity of the Community. This is one area which favours the collaboration across frontiers of all those who seek to advance knowledge. But although DG XIV is uniquely placed to appreciate the importance of research into fisheries and aquaculture, there is no question of succumbing to the temptation to directly control the scope of research or its conduct. The notion of subsidiarity can best be understood by examining the existing structures in the Member States. The Commission must act first and foremost as a catalyst, by promoting the circulation of information and the coordination of research programmes.

Here is a comprehensive and up-to date compendium of the technology and management of MTBE contamination, exploring the myths which impede successful clean-up techniques, and offering effective solutions. Section I looks at the history, properties, occurrence and assessment of MTBE. Section II discusses applicable remediation technologies. Section III offers remediation case studies.

John E. Mylroie and Ira D. Sasowsky' Caves occupy incongruous positions in both our culture and our science. The oldest records of modem human culture are the vivid cave paintings from southern France and northern Spain, which are in some cases more than 30,000 years old (Chauvet, et ai, 1996). Yet, to call someone a "caveman" is to declare them primitive and ignorant. Caves, being cryptic and mysterious, occupied important roles in many cultures. For example, Greece, a country with abundant karst, had the oracle at Delphi and Hades the god of death working from caves. People are both drawn to and mortified by caves. Written records ofcave exploration exist from as early as 852 BC (Shaw, 1992). In the decade of the 1920's, which was rich in news events, the second biggest story (as measured by column inches of newsprint) was the entrapment of Floyd Collins in Sand Cave, Kentucky, USA. This was surpassed only by Lindbergh's flight across the Atlantic (Murray and Brucker, 1979).

Acknowledgements Conference Summary R. D. EVANS, A. PROVINI, J. S. MATIICE, B. T. HART and J. WISNIEWSKI/Interactions Between Sediments and Water: Summary of the 7th International Symposium 1-7 Sediment I Water Dynamics D. E. WALLING and W. HE /Investigating Spatial Patterns of Overbank Sedimentation on River Floodplains 9-20 R. JEPSEN, J. ROBERTS and W. LICK / Effects of Bulk Density on Sediment Erosion Rates 21-31 T. G. MILLIGAN and D. H. LORING / The Effect of Flocculation on the Size Distributions of Bottom Sediment in Coastal Inlets: Implications for Contaminant Transport 33-42 loG. DROPPO, G. G. LEPPARD, D. T. FLANNIGAN and S. N. LlSS / The Freshwater Floc: A Functional Relationship of Water and Organic and Inorganic Floc Constituents Affecting Suspended Sediment Properties 43-53 C. H. TSAI and J. Q. HU / Flocculation of Particles by Fluid Shear in Buffered Suspensions 55-62 P. M. STONE and D. E. WALLING / Particle Size Selectivity Considerations in Suspended Sediment Budget Investigations 63-70 Q. HE and D. E. WALLING / Spatial Variability of the Particle Size Composition of Overbank Floodplain Deposits 71-80 C. YEN and Y. LIN KEY / Variations of Bed Surface Sediment Size in a Channel Bend 81-88 M. STONE and B. G. KRISHNAPPAN / Transport Characteristics of Tile-Drain Sediments From an Agricultural Watershed 89-103 U. KERN and B. WESTRICH / Sediment Budget Analysis for River Reservoirs 105-112 A. I. PACKMAN, N. H. BROOKS and J. J.

This is the first book to deal specifically with the procedures used in the analysis of structural relationships and the determination of structural successions in complexly deformed rocks such as migmatites and gneisses. The establishment of structural successions enables: The rigorous control of the dating of specific events in the deformational history by constraining the sites of the dated rocks within the structural succession; The establishment of the time span of orogenic events throughout the structural succession, and the rate of orogenic processes;Their comparison to be used as a basis for correlation between dismembered and separated crustal segments in continental reconstructions;The resolution of the complex relationships between deformed ore bodies and host rocks in high grade terranes, and hence determination of the structural control of ore bodies, an essential part of any successful geological exploration, and a precondition to efficient exploitation. With its new approach, and the use of practical field examples from various parts of the world, this highly illustrated work will form an invaluable reference resource for postgraduates, lecturers and researchers in the structural and isotope geology of high-grade metamorphic terranes, as well as for exploration and survey geologists working in the field. Dr Alaric M. Hopgood who holds an Honorary Readership at the University of St Andrews, Scotland, was a Reader in the Department of Geology there until 1995.

A significant advance in climatological scholarship, Tectonic Uplift and Climate Change is a multidisciplinary effort to summarize the current status of a new theory steadily gaining acceptance in geoscience circles: that long-term cooling and glaciation are controlled by plateau and mountain uplift. Researchers in many diverse fields, from geology to paleobotany, present data that substantiate this hypothesis. The volume covers most of the key, dramatic transformations of the Earth's surface.

Since 1956 the author has been making extensive and detailed investigations of saline lakes on the Qinghai-Tibet plateau. On the basis of large amounts of reliable first-hand data and multidisciplinary analysis, the book deals with the temporal-spatial evolution of the plateau saline lakes and the prospects for inorganic salts and organic resources and their exploitation and protection, as well as the relationships between saline lakes and global changes. This book is the first English monograph on saline lakes on the Qinghai-Tibet Plateau - the Roof of the World'. Compared with books about saline lakes in other areas of the world, this monograph is written in a multidisciplinary, comprehensive and systematic way. It may be used by graduate students, teachers, researchers, field geologists and engineers as a reference book in research, teaching, etc.

The chemical interaction of water and rock is one of the most fascinating an d multifaceted process in geology. The composition of surface water and groundwater is largely controlled by the reaction of water with rocks and minerals. At elevated temperature, hydrothermal features, hydrothermal 0 re deposits and geothermal fields are associated with chemical effects of water-rock interaction. Surface outcrops of rocks from deeper levels in the crust, including exposures of lower crustal and mantle rocks, often display structures that formed by interaction of the rocks with a supercritical aqueous fluid at very high pT conditions. Understanding water-rock interaction is also of great importance to applied geology and geochemistry, particularly in areas such as geothermal energy, nuclear waste repositories and applied hydrogeology. The extremely wide-ranging research efforts on the universal water-rock interaction process is reflected in the wide diversity of themes presented at the regular International Symposia on Water-Rock Interaction (WRI). Because of the large and widespread interest in water-rock interaction, the European Union of Geosciences organized a special symposium on "water-rock interaction" at EUGI0, the biannual meeting in Strasbourg 1999 convened by the editors of this volume. In contrast to the regular WRI symposia addressed to the specialists, the EUG 10 "water-rock interaction" symposium brought the subject to a general platform This very successful symposium showed the way to the future of water-rock reaction research.

Carbon dioxide and other `greenhouse' gases are increasing in the atmosphere due to the burning of fossil fuels, the destruction of rain forests, etc., leading to predictions of a gradual global warming which will perturb the global biosphere. An important process which counters this trend toward potential climate change is the removal of carbon dioxide from the surface ocean by photosynthesis. This process packages carbon in phytoplankton which enter the food chain or sink into the deep sea. Their ultimate fate is a `rain' of organic debris out of the surface-mixed layer of the ocean. On a global scale, the mechanisms and overall rate of this process are poorly known. The authors of the 25 papers in this volume present their state-of-the-art approaches to quantifying the mechanisms by which the `rain' of biogenic debris nourishes deep ocean life. Prominent deep sea ecologists, geochemists and modelers address relationships between data and models of carbon fluxes and food chains in the deep ocean. An attempt is made to estimate the fate of carbon in the deep sea on a global scale by summing up the utilization of organic matter among all the populations of the abyssal biosphere. Comparisons are made between these ecological approaches and estimates of geochemical fluxes based on sediment trapping, one-dimensional geochemical models and horizontal (physical) input from continental margins. Planning interdisciplinary enterprises between geochemists and ecologists, including new field programs, are summarized in the final chapter. The summary includes a list of the important gaps in understanding which must be addressed before the role of the deep-sea biota in global-scale processes can be put in perspective.

This volume focuses on isotopic signatures of volatile elements as tracers for evolutionary processes during the formation of the Sun and the planets from an interstellar molecular cloud and, in turn, illuminates how the isotopic compositions of the present-day solar system objects have been established.
The book is an integrated collection of articles by experts in planetary science, solar and plasma physics, astrophysics, mineralogy and chemistry that met for an interdisciplinary workshop at the International Space Science Institute in Bern in January 2002. The authors present analyses of isotope abundance ratios for volatile elements in the sun, planets, satellites, comets, meteorites and interplanetary dust particles, as well as a review of isotopic ratios in star-forming interstellar clouds. This provides insight into the physical and chemical processes in the pre-solar molecular cloud that collapsed to form the Sun and the solar accretion disk. Furthermore, information is presented on dynamical processes and conditions inside this protoplanetary disk, in particular the degree of reprocessing of interstellar solid material, the formation of solids inside the disks, and the formation of terrestrial and giant planets and their satellites. Isotopic fractionation processes discussed in this book include chemical reactions such as ion-molecule and photochemical reactions, nuclear processes inside the sun and in its atmosphere, plasma processes, gravitational escape of gases from planetary atmospheres exposed to the solar wind and solar radiation, thermodynamic processes, a variety of accretion and adsorption processes and mixing of material from the interstellar environment with the material of the evolving solar system.
The volume is intended to provide active researchers in the fields of planetary science and space physics with an up-to-date status report on the topic, and also to serve graduate students with introductory material into the field.

The analysis of materials containing several elements used to be a difficult problem for analytical chemists, so a well established sequence of wet chemical qualitative tests were performed to ensure each element was detected. Quantitative tests could then be carried out on the sample, according to the range of elements present. Most analytical chemists were very familiar with these techniques, having been taugth them from a very early stage in their education and careers. The analytical chemist can now call on a range of specialist instrumental techniques which can detect the presence of many elements, often simultaneously, and often quantitatively, providing rapid results on samples which, in the past, could take days. The drawback is that the instruments tend to be expensive, suited to particular sample types or matrices and complex in both setting up and in the interpretation of results. Furthermore the general analytical chemist may have access and familiarity with only one or two methods. Written by an international team of contributors, each experts in their particular fields, this book familiarizes analytical chemists with the range of elemental analysis techniquers, to enable them to specify the most appropriate test for any given sample. In addition, it contains important chapters on sample preparation and quality control, essential elements in obtaining accurate and reliable analytical results. As such, this book will be essential reading for all analytical chemists. The techniques of elemental analysis are important in many other disciplines, so the book will be of particular interest to those commissioning a wide range of analytical measurements, such as chemists, geologists, environmental scientists and biologists. The breadth and depth of coverage will also make the book very useful for advanced students.

Oil shales are broadly dermed as petroleum source rocks containing sufficiently high contents of organic matter (above ca 10-15 wt. %) to make utilisation a possibility. Like coal, the world's reserves of oil shales are vast being many times larger than those proven for crude oil. Indeed, some of the largest deposits occur in the USA and Europe where Estonia and Turkey have large reserves. The first recorded interest in oil shale retorting was an English patent in 1694 (Eele, Hancock and Porter, No. 330) which refers to distilling noyle from some kind of stone." The oil shale retorting industry dates back to the middle of the last century, notably Scotland, Estonia, France and Sweden in Europe. Indeed, my own Department at the University of Strathclyde has a historical link with James "Paraffin" Young, the founder of the Scottish oil shale industry who endowed a chair in Applied Chemistry. The growth of the oil industry saw the demise of the oil shale industry in most countries with the notable exception of Estonia, where kukersite has continued to be used for power generation and retorting. However, oil shale utilisation has attracted renewed attention since the early 1970s as a source of transport fuels and chemical feedstocks due to the the long term uncertainties over crude oil supplies.

Dr. Heinonen reviews and critically evaluates the scientific literature on the biological role of inorganic pyrophosphate (PPi ) published from 1940 to the end of 1999. He describes and classifies all known biochemical reactions that produce Ppi; describes and evaluates all published methods used in biological Ppi; and compiles and critically evaluates information on the concentration of PPi (with the conclusion that, contrary to common belief, PPi exists throughout the living world in rather high concentrations). Many reactions in which PPi is used as a biochemical energy source instead of ATP have been described in recent decades, especially in bacteria, protists, and plants. These reactions are evaluated from the bioenergetic and regulatory points of view. Also considered is the possible role of PPi as a source of biochemical energy in the primitive phases of life, before ATP. Data is presented on the regulatory role of PPi in living systems, such as activities of enzymes, fidelity of syntheses of macromolecules, and proliferation of cells. PPi may also regulate the formation and dissolution of bone as well as pathologic calcification of soft tissues and the formation of urinary stones. The formation of calcium pyrophosphate dihydrate crystals in the extracellular fluids of joints cause the disease called pseudogout. Biological Role of Inorganic Pyrophosphate book is a unique and invaluable source of references (about 1120) and summarized data for professionals who study or plan to study the role of PPi in living systems. Many different branches of science (biochemistry, microbiology, bioenergetics, plant physiology, parasitology, evolution, orthopedics, rheumatology) have involvement with PPi. This book sums up available knowledge in one place and will help scientists cross disciplinary boundaries.