As pharmaceutical companies look to develop single enantiomers as drug candidates, chemists are increasingly faced with the problems associated with this subclass of organic synthesis. The Handbook of Chiral Chemicals, Second Edition highlights the problems associated with the production of chiral compounds on a commercial scale.

The handbook first elaborates upon starting materials obtained from a "chiral pool," which can be derived from natural products. Then it explains methods and reactions that can introduce or influence stereogenic centers, particularly asymmetric hydrogenations, oxidations, pericyclic reactions, and enzymatic methods. While hydrogenations have been the most widely employed approach for the large-scale synthesis of several commercial compounds, the search for the ideal catalyst has consistently led researchers to enzymes present in biological systems. Several chapters concentrate on understanding how to manipulate enzymes for catalyzing new reactions for taking new substrates. Other significant topics include chiral auxiliaries, chromatographic techniques, enantiomers-specific reactions, and resolution.

This second edition updates all its chapters, illustrating the speed of development in this field, and features new chapters that highlight successful approaches in an industrial setting. The Handbook of Chiral Chemicals, Second Edition is a guide to advances in the field that result in more efficient and cost-effective synthesis of chiral chemicals.

Present the main anthropological and non-anthropological sources of waste generation containing toxic metals. Demonstrate aspects related to the generation, disposal and valuation of solid waste containing toxic metals. Portray techniques for the treatment and reuse of water contaminated with toxic metals.

Direct Natural Gas Conversion to Value-Added Chemicals comprehensively discusses all major aspects of natural gas conversion and introduces a broad spectrum of recent technological developments. Specifically, the book describes heterogeneous and homogeneous catalysis, microwave-assisted conversion, non-thermal plasma conversion, electrochemical conversion, and novel chemical looping conversion approaches. Provides an excellent benchmark resource for the industry and academics Appeals to experienced researchers as well as newcomers to the field, despite the variety of contributing authors and the complexity of the material covered Includes all aspects of direct natural gas conversion: fundamental chemistry, different routes of conversion, catalysts, catalyst deactivation, reaction engineering, novel conversion concepts, thermodynamics, heat and mass transfer issues, system design, and recent research and development Discusses new developments in natural gas conversion and future challenges and opportunities This book is as an excellent resource for advanced students, technology developers, and researchers in chemical engineering, industrial chemistry, and others interested in the conversion of natural gas.

Leveraging Synergies Between Refining and Petrochemical Processes provides a detailed description of the interfaces and connections between crude oil refining and petrochemicals. It offers a view of global and regional markets and economic opportunities for synergies between these sectors. Features: Shows a global and regional market outlook for crude oil refining and petrochemical sectors Explores economic and market opportunities for taking advantage of the synergies between both sectors Analyzes the technical challenges and opportunities that come with these synergies Gives an outlook and prediction of what companies will be able to achieve in the mid-term future Provides introductory and explanatory material as well as in-depth insight into future technology and market developments This book serves as a reference for professionals in chemical engineering, oil and gas engineering, and industrial chemistry. It aims to help engineers and industry professionals understand the challenges and the potential benefits of developing expansion or optimization projects that may bridge the gap between refining and petrochemicals.

Structured Glass-Fiber Catalysts discusses the synthesis of advanced glass-fiber catalysts for various emerging applications, investigation of their properties, and development of the engineering basis required for their wide practical application. This book describes how to create and use such catalysts for different chemical reactions. It discusses how to efficiently arrange them into structured catalytic cartridges and gives examples of their successful application for purification of waste gases from different hazardous contaminants and environmentally safe combustion of fuels. It covers nanosize surface science fundamentals through large-scale commercial catalytic reactors. This book is aimed at researchers and engineers in the fields of chemical engineering, industrial engineering, and materials engineering.

to the Third Edition Following the success of the first two editions of this book in which the core subject matter has been retained, we have taken the opportunity to add substantial new material, including an additional chapter on that most important activity of the chemical industry, research and development. Topical items such as quality, safety and environmental issues also receive enhanced coverage. The team of authors for this edition comprises both those revising and updating their chapters and some new ones. The latter's different approach to the subject matter is reflected in the new titles: Organisational Structures - A Story of Evolution (chapter 5) and Environmental Impact of the Chemical Industry (chapter 9). The chapter on Energy retains its original title but different approach of the new authors is evident. We have updated statistics and tables wherever possible and expanded the index. We hope readers find the brief 'pen pictures' of authors to be interesting. It is worth stressing again that this book is designed to be used with its companion volume - The Chemical Industry, 2nd Edition, ed. Alan Heaton (referred to as Volume 2) - for a complete introduction to the chemical industry. Thanks are due to all contributors and to my wife Joy for typing my contributions.

Bretherick's Handbook of Reactive Chemical Hazards, Eighth Edition presents the latest updates on the unexpected, but predictable, loss of containment and explosion hazards from chemicals and their admixtures and actual accidents. The extensively cross-referenced book enables readers to avoid explosion and loss of containment of chemicals. Primary and more specialized sources are easily traced, and this new edition includes available record updates, also adding a number of new records. In this newly updated and expanded edition, the content is presented in a clear and user-friendly format.

This is the first book to describe the scientific basis for the action of plant polyphenols in a wide range of technologically important phenomena. The book opens with a general summary of polyphenolic structure and a discussion of the physical and chemical basis of non-covalent molecular interactions (the process of molecular recognition) and the means by which polyphenols initiate the many and varied properties they display. There has been a big increase in interest in our ability to understand the importance of polyphenols in areas as diverse as agriculture, ecology and food selection, foodstuffs and nutrition, beverages (astringency and bitterness), natural medicines (the so-called 'French paradox'), floral pigmentation, natural glues and varnishes and the age-old methods for the manufacture of leather. The role of polyphenols in all of these areas is discussed. This book will be of value to a wide range of researchers with an interest in polyphenolics.

A complete guide to petrochemicals production processes-fully revised to cover the latest advances Get all the information you need on petrochemical processes for major organic chemicals inside this industry-standard one-stop reference. Prepared by leading petrochemical licensing firms, Handbook of Petrochemicals Production Processes, Second Edition clearly explains the powerful techniques used to create the most economically important chemicals in the world. The book offers cutting-edge production methods along with detailed product properties. You will discover how to effectively evaluate licensable processes for new production through the comparison of technologies, environmental factors, and economics. Coverage includes: *General process descriptions, feed definitions, product yields, and simplified flow diagrams *Process chemistries and thermodynamics *Commercial process perspectives, including plant locations and long-term plans *Process details, with flow diagrams and mass and energy balances for major process variations *Feeds and details on unique and key equipment *Brand-new details on gas to petrochemical conversion, biomass to petrochemical conversion, and bisphonal A (BPA)

Modern look at the thermodynamics of hydrocarbon reservoirs

This brilliant, original work offers novel formulations of thermodynamic principles for hydrocarbon reservoirs. The book is packed with valuable step-by-step derivations for retrograde phenomena in capillaries, diffusion and convection, stability and criticality in mixtures, precipitation from complex mixtures, and numerous examples that show in detail how to calculate and apply concepts using the most contemporary techniques.

The book is not only a valuable reference for petroleum and chemical engineers, but can be used by engineers and scientists in different disciplines.

This book provides an overview of the chemical and physical concepts of instability and incompatibility of petroleum and liquid fuels. It helps the petroleum refinery personnel to handle liquid fuels from other sources as feedstocks for the refinery system.

Dr. Smil is the world's authority on nitrogenous fertilizer. The industrial synthesis of ammonia from nitrogen and hydrogen has been of greater fundamental importance to the modern world than the invention of the airplane, nuclear energy, space flight, or television. The expansion of the world's population from 1.6 billion people in 1900 to today's six billion would not have been possible without the synthesis of ammonia. In Enriching the Earth, Vaclav Smil begins with a discussion of nitrogen's unique status in the biosphere, its role in crop production, and traditional means of supplying the nutrient. He then looks at various attempts to expand natural nitrogen flows through mineral and synthetic fertilizers. The core of the book is a detailed narrative of the discovery of ammonia synthesis by Fritz Haber-a discovery scientists had sought for over one hundred years-and its commercialization by Carl Bosch and the chemical company BASF. Smil also examines the emergence of the large-scale nitrogen fertilizer industry and analyzes the extent of global dependence on the Haber-Bosch process and its biospheric consequences. Finally, it looks at the role of nitrogen in civilization and, in a sad coda, describes the lives of Fritz Haber and Carl Bosch after the discovery of ammonia synthesis.