The International Symposium in Brittle Matrix Composites October 13-15, 2003 covers a wide spectrum of topics including cement based composites, ceramic composites and brittle polymer matrix composites. In the papers various topics and issues are considered such as: analytical and numerical studies related to the design of composites, prediction of behaviour and verification of strength and stability, testing methods, manufacturing processes and repair, environmental effects and durability assessment. The present volume of 55 papers proves that there are still many problems in the field of brittle matrix composites deserving theoretical and experimental investigations and that new solutions to these problems are needed for practical application in civil engineering, industrial structures, machinery and other domains.

KEY FEATURES:

A unified, fundamental and quantitative resource. The result of 5 years of investigation from researchers around the world
New data from a range of new techniques, including synchrotron radiation X-ray topography provide safer and surer methods of identifying deformation mechanisms
Informing the future direction of research in intermediate and high temperature processes by providing original treatment of dislocation climb

DESCRIPTION:

"Thermally Activated Mechanisms in Crystal Plasticity is a unified," quantitative and fundamental resource for material scientists investigating the strength of metallic materials of various structures at extreme temperatures. Crystal plasticity is usually controlled by a limited number of elementary dislocation mechanisms, even in complex structures. Those which determine dislocation mobility and how it changes under the influence of stress and temperature are of key importance for understanding and predicting the strength of materials. The authors describe in a consistent way a variety of thermally activated microscopic mechanisms of dislocation mobility in a range of crystals. The principles of the mechanisms and equations of dislocation motion are revisited and new ones are proposed. These describe mostly friction forces on dislocations such as the lattice resistance to glide or those due to sessile cores, as well as dislocation cross-slip and climb. They are critically assessed by comparison with the best available experimental results of microstructural characterization, in situ straining experiments under an electron or a synchrotron beam, as well as accurate transient mechanical tests such as stress relaxation experiments. Some recent attempts at atomistic modeling of dislocation cores under stress and temperature are also considered since they offer a complementary description of core transformations and associated energy barriers.

In addition to offering guidance and assistance for further experimentation, the book indicates new ways to extend the body of data in particular areas such as lattice resistance to glide.

Pumps are commonly encountered in industry and are essential to the smooth running of many industrial complexes. Mechanical engineers entering industry often have little practical experience of pumps and their problems, and need to build up an understanding of the design, operation and appropriate use of pumps, plus how to diagnose faults and put them right. This book tackles all these aspects in a readable manner, drawing on the authors' long experience of lecturing and writing on centrifugal pumps for industrial audiences.

A surge of new molding technologies is transforming plastics processing and material forms to the highly efficient, integrated manufacturing that will set industry standards in the early years of the new century. This book is a survey of these technologies, putting them into context and accentuating opportunities. The relations among these technologies are analyzed in terms of:

Products: auto parts (e.g. bumpers, trim, keyless entry module, blower switch housing), business machines chassis, pallets, furniture, handles, television housings, covers, golf club shafts, connectors, notebook casing, switches, sensors, antennas, sockets, lighting, cellular phone housing, submicron parts, and medical devices.

Materials: composition, resin consideration, blends, structure (skin/core), shrinkage, viscosity, weld line strength, structural properties, morphology, reinforcement, surface roughness.

Processing: macroscopic structure, size and shape, typical problems and their solutions, flow length, injection pressure prediction, process simulation, processing parameters, tooling issues, rheology, rheokinetics, flow equations, flow simulation, no-slip boundary conditions, pressure loss, surface appearance, manufacturing cost, leakage modelling, set-up criteria, optimization of molding parameters non-return valve applications.

Geometry: function (enclosure/support) and complexity (symmetric/three-dimensional), molding window, filling of complex-art, design optimization, x-ray tomography, image reconstruction, acoustic imaging, warpage calculation, simulation and calculation, flow channels, and tight tolerance.

This ACS Symposium Series is the product of a symposium held at the 241st National Meeting of the American Chemical Society in Anaheim, CA on March 27-31, 2011. It includes chapters on new biobased building blocks such as the furandicarboxylic acid, polyesters and polyamides from adipic, succinic and sebacic acids with aliphatic diols such as 1,3-propylene glycol, 1,4-butanediol, 1,12-dodecylenediol and isosorbide. The conversion of hydroxymethylfurfural, the dehydration product of hexose sugars, to succinic acid and 1,4-butanediol to produce poly(butylene succinate) is described in one chapter. Also the synthesis of new polymers from plant-derived olefinic monomers such as tulipalin A and studies of composites from cotton by-products are featured in other chapters. There is a strong emphasis on biocatalytic synthesis and polymerization within the book. Chapter topics include the synthesis of ?-hydroxyfatty acids and polymers therefrom, an interesting discussion on the structural differences of the products of the biocatalytic and chemical catalytic synthesis of polyesters from oleic diacid and glycerol and the ability to produce polylactic acid (PLA) and PLA-PHA copolyesters within a "microbial cell factory". Other areas of interest explored in other chapters include recent developments of biobased polymer fibers and oleate-based pressure sensitive adhesives and composites. One chapter describes a large increase in cold-drawn fiber tensile strength by the blending of a small amount of ultrahigh molecular weight (MW) poly(3-hydroxybutyrate) with a much lower MW 3-hydroxybutyrate polymer. The addition of a rubber and inorganic fillers to normally brittle PLA was found to dramatically improve its ductility. Finally, there are several chapters on seed oil-based polyurethanes, one on fibers from soy proteins and composites from starch.

This book provides a detailed overview of cancer theranostics applications of magnetic iron oxide nanoparticles. Their synthesis, characterization, multifunctionality, disease targeting, biodistribution, pharmacokinetics and toxicity are highlighted, along with current examples of clinical trials of magnetic nanoparticles in cancer theranostics, and their future scopes and challenges.

Practically every display technology in use today relies on the flat, energy-efficient construction made possible by liquid crystals. These displays provide visually-crisp, vibrantly-colored images that a short time ago were thought only possible in science fiction. Liquid crystals are known mainly for their use in display technologies, but they also provide many diverse and useful applications: adaptive optics, electro-optical devices, films, lasers, photovoltaics, privacy windows, skin cleansers and soaps, and thermometers. The striking images of liquid crystals changing color under polarized lighting conditions are even on display in many museums and art galleries - true examples of science meeting art. Yet, although liquid crystals provide us with visually stunning displays, fascinating applications, and are a rich and fruitful source of interdisciplinary research, their full potential may remain untapped.

The papers published in these peer-reviewed proceedings represent the latest developments in nondestructive characterization of materials and were presented at the Tenth International Symposium on Nondestructive Characterization of Materials held on June 26 - 30, 2000 in Karuizawa, Japan. The symposium was held concurrently with three other symposia and one workshop. This symposium is the tenth in the series that began in 1983 and became an international meeting in 1986.
The symposium started with a Plenary Lecture entitled 'Application of Non-contact Ultrasonics to Nondestrctive Characterization of Materials' by Professor R.E. Green, Jr. Various characterization methods were presented at the symposium, including ultrasonics, X-ray, eddy currents, laser, thermal wave, acoustic emission, optical fibers, optics, magnetics and ultrasonic microscope. Thin films and coatings as well as smart materials were also emphasized in this symposium.

Early Developments of Modern Aerodynamics provides the wider aeronautical community with an insight into the historical development of aerodynamics. There were a number of key developments in the subject by German and Russian scientists and engineers such as Prandtl, Kutta and Zhukovskii at the beginning of the 20th century. All aerodynamics has been based on papers by these people but these fundamental papers are not available in English, indeed some of them have never before been translated. This text presents these papers, in English translation, together with an accompanying commentary putting them into the context of their period and showing their relevance to modern aerodynamics. Aimed at academics and professional engineers this book re-establishes the basis of the science of aerodynamics.

In recent years, the fabrication technologies for the production of advanced polymer composites have been revolutionised by sophisticated manufacturing techniques. These methods have enabled polymer composite materials to produce good quality laminates with minimal voids and accurate fibre alignment.
This book familiarises and provides a background to the understanding and use of advanced polymer composites in the civil infrastructure; numerous examples have been provided to illustrate the use and versatility of the material. Furthermore, the book discusses the current fabrication techniques, design methods and formulae for the design of structural composite systems. In addition it discusses the fundamentals of geosynthetics used in geotechnical engineering. The book introduces the fibres and matrices that are used to manufacture composites, their mechanical and in-service properties and their long term loading characteristics; all these properties are specifically associated with the construction industry. The chapters then discuss the design aspects for 'all composite' units, as well as systems used for the renewal of civil infrastructure. Finally, the book demonstrated the unique possibilities of combining composites with conventional materials to form units in which the various materials making up the unit are loaded in the mode that specifically suits their mechanical characteristics.

The Coming of Materials Science both covers the discipline of materials science, and draws an impressionistic map of the present state of the subject.

The first chapter examines the emergence of the materials science concept, in both academe and industry. The second and third chapters delve back into the prehistory of materials science, examining the growth of such concepts as atoms, crystals and thermodynamics, and also examine the evolution of a number of neighbouring disciplines, to see what helpful parallels might emerge.

The book contains numerous literature references. Many refer to the earliest key papers and books, while others are to sources, often books, offering a view of the present state of a topic. Early references are to the past but as the book continues, it brings the reader up to date with more recent sources.

The author, Professor Robert Cahn FRS, has striven to be critical about the history of the discipline of materials science and to draw general conclusions about scientific practice from what he has discovered about the evolution of materials science. Further issues that the book highlights include: What is a scientific discipline? How do disciplines merge and differentiate? Can a discipline also be interdisciplinary? Is materials science a real discipline? A large range of themes is presented in the book and readers are invited to interact with the author if they reach alternative conclusions. This book is not just for reading and reference, but exists to stimulate thought and provoke discussion as well.

Open microfluidics - the study of microflows having a boundary with surrounding air - encompasses paper- or thread-based microfluidics, droplet microfluidics and open-channel microfluidics. Open-channel microflow is a flow at the micro-scale, guided by solid structures, and having at least a free boundary (with air or vapor) other than the advancing meniscus. This book is devoted to the study of open-channel microfluidics which, contrary to paper or thread or droplet microfluidics, is still very sparsely documented, but bears many new applications in biology, biotechnology, medicine, material and space sciences. Capillarity being the principal force triggering an open microflow, the principles of capillarity are first recalled. The onset of open-channel microflow is next analyzed and the fundamental notion of generalized Cassie angle - the apparent contact angle which accounts for the presence of air - is presented. The theory of the dynamics of open-channel microflows is then developed, using the notion of averaged friction length, which accounts for the presence of air along the boundaries of the flow domain. Different channel morphologies are studied and geometrical features, such as valves and capillary pumps, are examined. An introduction to two-phase open-channel microflows is also presented, showing that immiscible plugs can be transported by an open-channel flow. Finally, a selection of interesting applications in the domains of space, materials, medicine and biology is provided, showing the potentialities of open-channel microfluidics.

Testing of composite materials can present complex problems but is essential in order to ensure the reliable, safe and cost-effective performance of any engineering structure. This essentially practical book, complied from the contributions of leading professionals in the field, describes a wide range of test methods which can be applied to various types of advanced fibre composites. The book focuses on high modulus, high strength fibre/plastic composites and also covers highly anisotrpoic materials such as carbon, aramid and glass.
Engineers and designers specifying the use of materials in structures will find this book an invaluable guide to best practice throughout the range of industrial sectors where FRCs are employed.

Semiconductors and Modern Electronics is a brief introduction to the physics behind semiconductor technologies. Chuck Winrich explores the topic of semiconductors from a qualitative approach to understanding the theories and models used to explain semiconductor devices, which is intended to bring the advanced ideas behind semiconductors to a broader audience of students who will not major in physics. Applications of semiconductors are explored and understood through the models developed in the book. Much of the inspiration for this text comes from Winrich's experience teaching a general electronics course to students majoring in business. The goal of that class, and this work, is to bring forward the science behind semiconductors, and then to look at how that science affects the lives of people.

As it results from the very nature of things, the spherical symmetry of the surrounding of a site in a crystal lattice or an atom in a molecule can never occur. Therefore, the eigenfunctions and eigenvalues of any bound ion or atom have to differ from those of spherically symmetric respective free ions. In this way, the most simplified concept of the crystal field effect or ligand field effect in the case of individual molecules can be introduced.
The conventional notion of the crystal field potential is narrowed to its non-spherical part only through ignoring the dominating spherical part which produces only a uniform energy shift of gravity centres of the free ion terms. It is well understood that the non-spherical part of the effective potential "seen" by open-shell electrons localized on a metal ion plays an essential role in most observed properties. Light adsorption, electron paramagnetic resonance, inelastic neutron scattering and basic characteristics derived from magnetic and thermal measurements, are only examples of a much wider class of experimental results dependent on it. The influence is discerned in all kinds of materials containing unpaired localized electrons: ionic crystals, semiconductors and metallic compounds including materials as intriguing as high-"Tc" superconductors, or heavy fermion systems. It is evident from the above that we deal with a widespread effect relative to all free ion terms except those which can stand the lowered symmetry, e.g. "S"-terms.
Despite the universality of the phenomenon, the available handbooks on solid state physics pay only marginal attention to it, merely making mention of its occurrence. Present understanding of the origins of the crystal field potential differs essentially from the pioneering electrostatic picture postulated in the twenties. The considerable development of the theory that has been put forward since then can be traced in many regular articles scattered throughout the literature. The last two decades have left their impression as well but, to the authors' best knowledge, this period has not been closed with a more extended review. This has also motivated us to compile the main achievements in the field in the form of a book.

Rapid evolution is taking place in the water market world wide - driven by increased consumer demand allied to the rarefraction of clean water. The inherent characteristics of composites materials associated with current materials and production technology is allowing the increased use of previously high cost materials and processes at ever decreasing costs.
The Handbook is designed to bring specifiers up to speed with these materials and the new areas of application associated with them, exploring the scope, performance, cost effectiveness and environmental and legislative consequences of their use.

Nanogels are three-dimensional nanosized networks that are formed by physically or chemically cross-linking polymers. They have been explored as a drug-delivery system due to their biocompatibility, high stability, particle-size adjustment, drug-loading capability and modification of the surface for active targeting by cognate receptors on the target cells of tissues. Nanogels can respond to stimuli such as pH, temperature, light and redox, which results in the controlled release of drugs and targeting of site by environmental stimuli and prevents accumulation in non-target tissues, minimizing the side effects of the drug. This book aims to provide a general introduction to nanogels and the design of various stimuli-sensitive nanogels that can control drug release in response to specific stimuli.

This volume examines recent developments in the use of intelligent materials and systems for drug delivery. Controlled release technology is moving from being a simple carrier of active agents to becoming a powerful and flexible method that permits subtle modulation of the delivery profile based on the needs of the biological host. The chapters collected here cover recent advances in materials with responsive properties, novel concepts in controlled release technology, new applications, and microanalytical techniques for rapid and accurate measurements of small samples.

This book contains the fully peer-reviewed papers presented at the Third Engineering Foundation Conference on Small Fatigue Cracks, held under the chairmanship of K.S. Ravichandran and Y. Murakami during December 6-11, 1998, at the Turtle Bay Hilton, Oahu, Hawaii. This book presents a state-of-the-art description of the mechanics, mechanisms and applications of small fatigue cracks by most of the world's leading experts in this field. Topics ranging from the mechanisms of crack initiation, small crack behavior in metallic, intermetallic, ceramic and composite materials, experimental measurement, mechanistic and theoretical models, to the role of small cracks in fretting fatigue and the application of small crack results to the aging aircraft and high-cycle fatigue problems, are covered.

The ESIS-Technical Committee 9 on Concrete was established in 1990 and has met seven times. A proposal was put to European and extra-European laboratories entitled "Scale effects and transitional failure phenomena of reinforced concrete beams in flexure" which lead to several positive responses.

The central topic discussed by the committee was that of the minimum reinforcement in concrete members. The minimum amount of reinforcement is defined as that for which "peak load at first concrete cracking" and "ultimate load after steel yielding" are equal. In this way, any brittle behaviour is avoided as well as any localized failure, if the member is not over-reinforced. In other words, there is a reinforcement percentage range, depending on the size-scale, within which the plastic limit analysis may be applied with its static and kinematic theorems.

Carpinteri, Ferro, Bosco and El-Katieb propose a LEFM model, according to which reinforcement reactions are applied directly on the crack surfaces and a compatibility condition is locally imposed on the crack opening displacement in correspondence with the reinforcement. The theoretical model is found to provide a satisfactory estimate of the minimum percentage of reinforcement that depends on the scale and enables the element in flexure to prevent brittle failure.

The purpose of this wide-ranging introductory text is to provide a basic understanding of the underlying science as well as the engineering applications of composite materials. It explains how composite materials, with their advantages of high strength with stiffness, together with low weight and other desirable properties are formed and discusses the nature of the different types of reinforcement and matrix - and their interaction. Methods of production, examples of typical applications and essential data are all included.
Composite materials: Engineering and science is based on a successful long running course at Imperial College, London, and the numerous worked examples combined with a comprehensive set of problems and self-assessment questions (with answers) provide an excellent text for senio undergraduate and graduate courses in materials science, engineering and physics. It will also be invaluable to any designer or professional engineer new to the composite materials field.
This is a reissue of a successful and well-regarded textbook originally published in 1994 by Chapman & Hall.

Nanomaterials and nanostructures are the original product of nanotechnology, and they are the key building blocks for enabling technologies. In this context, this book presents a concise overview of the synthesis and characterization methods of nanomaterials and nanostructures, while integrating facets of physics, chemistry, and engineering. The book summarizes the fundamentals and technical approaches in synthesis, and processing of nanostructures and nanomaterials, giving the reader a systematic and quick picture of the field. The text focuses on functional aspects of nanomaterials that have a high relevance to immediate applications, such as catalysis, energy harvesting, biosensing, and surface functionalization. There are chapters addressing nanostructured materials and composites, and covering basic properties and requirements of this new class of engineered materials.

These proceedings contain the papers presented at the 4th International Symposium on Engineering Turbulence Modelling and Measurements held at Ajaccio, Corsica, France from 24-26 May 1999. It follows three previous conferences on the topic of engineering turbulence modelling and measurements.
The purpose of this series of symposia is to provide a forum for presenting and discussing new developments in the area of turbulence modelling and measurements, with particular emphasis on engineering-related problems.
Turbulence is still one of the key issues in tackling engineering flow problems. As powerful computers and accurate numerical methods are now available for solving the flow equations, and since engineering applications nearly always involve turbulence effects, the reliability of CFD analysis depends more and more on the performance of the turbulence models. Successful simulation of turbulence requires the understanding of the complex physical phenomena involved and suitable models for describing the turbulent momentum, heat and mass transfer. For the understanding of turbulence phenomena, experiments are indispensable, but they are equally important for providing data for the development and testing of turbulence models and hence for CFD software validation.

This book provides an introduction to topological matter, with a focus on insulating bulk systems. A number of prerequisite concepts and tools are first laid out, including the notion of symmetry transformations, the band theory of semiconductors and aspects of electronic transport. The main part of the book discusses realistic models for both time-reversal-preserving and -violating topological insulators, as well as their characteristic responses to external perturbations. Special emphasis is given to the study of the anomalous electric, thermal and thermoelectric transport properties, the theory of orbital magnetisation, and the polar Kerr effect. The topological models studied throughout this book become unified and generalised by means of the tenfold topological-classification framework and the respective systematic construction of topological invariants. This approach is further extended to topological superconductors and topological semimetals. This book covers a wide range of topics and aims for a transparent presentation of the technical aspects involved. For this purpose, homework problems are also provided in dedicated hands-on sections. Given its structure, and the required background level of the reader, this book is particularly recommended for graduate students or researchers who are new to the field.