Data on the synthesis and physicochemical studies of salts of mono-
or dibasic unsaturated carboxylic acids and macromolecular metal
carboxylates are generalised and described systematically in this
monograph. The structures and properties of the COO group in
various compounds and characteristic features of the structures of
carboxylate are analysed. The main routes and kinetics of
polymerisation transformations of unsaturated metal carboxylates
are considered. The attention is focused on the effect of the metal
ion on the monomer reactivity and the polymer morphology and
structure. The possibility of stereochemical control of radical
polymerisation of unsaturated metal carboxylates is demonstrated.
The electronic, magnetic, optical, absorption and thermal
properties of metal (co)polymers and nanocomposites and their main
applications are also considered.
General
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