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From Enzyme Models to Model Enzymes (Hardcover, Edition.)
Loot Price: R4,387
Discovery Miles 43 870
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From Enzyme Models to Model Enzymes (Hardcover, Edition.)
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Designing artificial systems with catalytic efficiencies to rival
those of natural enzymes is one of the great challenges facing
science today. Our current level of understanding fails the basic,
practical test - designing and making artificial systems with
catalytic efficiencies to rival those of natural enzymes. Chemists
and bio-scientists are well aware of this problem, and "artificial
enzymes" have been a "hot topic" for many years. However, until
now, there has been no book devoted specifically to this subject.
This is the first book to provide a critical introduction to, and
overview of, this exciting area. It is aimed at students and more
senior researchers with specialist or general interests in the
field. The book starts with a systematic overview of the most
important properties of natural enzymes, with special emphasis on
mechanisms and efficiency of catalysis. This is followed by a
summary of the mechanisms involved in the major classes of reaction
they catalyze, and spells out the logical progression from simple
mechanistic models for particular reactions to the first,
rudimentary artificial enzymes catalyzing them. Catalytic
efficiency is the key criterion for inclusion. An analysis of the
strengths and limitations of the classical design-based approach to
catalysis by enzyme mimics leads on to a discussion of recent
advances which use selection methods coupled with iterative
techniques for creating and improving catalysts by natural methods.
The comparison of natural and artificial catalysts requires a
quantitative understanding based on the interpretation of kinetic
measurements. Key skills in data interpretation are introduced in a
guided approach that connects the formal treatment of kinetic
measurements with their chemical and biological interpretation.
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