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Biodegradability of Surfactants (Hardcover, 1995 ed.)
Loot Price: R5,863
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Biodegradability of Surfactants (Hardcover, 1995 ed.)
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The awareness and development of 'biodegradable' surfactants
pre-dates current pressures by the environmental movement by nearly
three decades, wherein a responsible industry mutually agreed to
replace 'hard', non-biodegradable com ponents of household
detergents by 'soft', biodegradable alternatives, without course to
legislation. The only requirement at that time was for surfactants
used in detergents to exhibit a 'primary biodegradability' in
excess of 80%; this referring to the disap pearance or removal from
solution of the intact surface active material as de tected by
specified analytical techniques. This proved useful, as observed
environmental impacts of surfactants, e.g. visible foam on rivers,
are associated with the intact molecule. Test methods for 'primary
biodegradability' were eventually enshrined in EU legislation for
nonionic surfactants (Directive 821242/EEC, amended 73/404IEEC) and
for anionic surfactants (Directive 8212431EEC, amended 73/405IEEC).
No approved test methods and resultant legislation have been
developed for cationic and amphoteric surfactants to date. The
environmental classification of chemical substances, which of
course includes surfactants, and associated risk assessment
utilises a second criterion 'ready biodegradability'. This may be
assessed by a number of methods which monitor oxygen uptake (BOD),
carbon dioxide production or removal of dis solved organic carbon
(DOC). Some surfactants which comply with the above Detergents
Directive are borderline when it comes to 'ready
biodegradability'."
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