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Experimental Functional Map of a Polymer Electrolyte Fuel Cell (Paperback)
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Experimental Functional Map of a Polymer Electrolyte Fuel Cell (Paperback)
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Fuel cell performance is determined by the complex interplay of
mass transport, energy transfer and electrochemical processes. The
convolution of these processes leads to spatial heterogeneity in
the way that fuel cells perform, particularly due to reactant
consumption, water management and the design of fluid-flow plates.
It is therefore unlikely that any bulk measurement made on a fuel
cell will represent performance at all parts of the cell. The
ability to make spatially resolved measurements in a fuel cell
provides one of the most useful ways in which to monitor and
optimise performance. This book reviews the range of in situ
techniques being used to study fuel cells and describes the use of
novel experimental techniques that the authors have used to develop
an experimental functional map of polymer electrolyte fuel cell
(PEFC) performance. These techniques include the mapping of current
density, electrochemical impedance, electrolyte conductivity,
contact resistance and CO poisoning distribution within working
PEFCs, as well as mapping the flow of reactant in gas channels
using laser Doppler anemometry (LDA). The combination of these
techniques, applied across a range of fuel cell operating
conditions allows a unique picture of the internal workings of
PEFCs to be obtained and has been used to validate both numerical
and analytical models.
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