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Smoke Component Yields from Room-scale Fire Tests (Paperback)
Loot Price: R354
Discovery Miles 3 540
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Smoke Component Yields from Room-scale Fire Tests (Paperback)
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Loot Price R354
Discovery Miles 3 540
Expected to ship within 10 - 15 working days
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This report presents the methodology for and results from a series
of room-scale fire tests to produce data on the yields of toxic
products in both pre-flashover and post-flashover fires. The
combustibles examined were: a sofa made of upholstered cushions on
a steel frame, particleboard bookcases with a laminated finish,
polyvinyl chloride sheet, and household electric cable. They were
burned in a room with a long adjacent corridor. The yields of CO2,
CO, HCl, HCN, and carbonaceous soot were determined. Other
toxicants (e.g., NO2, formaldehyde and acrolein) were not found;
concentrations below the detection limits were shown to be of
limited toxicological importance relative to the detected
toxicants. The toxicant yields from sofa cushion fires in a closed
room were similar to those from pre-flashover fires of the same
cushions in a room with the door open. The uncertainties in the
post-flashover data are smaller due to the higher species
concentrations and the more fully established upper layer from
which the fire effluent was sampled. The uncertainty values are
comparable to those estimated for the fractional effective dose
calculations used to determine the time available for escape from a
fire. The uncertainty in the yield data from the sofa, bookcase,
and cable tests is sufficiently small to determine whether a
bench-scale apparatus is producing results that are similar to or
different from the real-scale results here. The use of Fourier
transform infrared (FTIR) spectroscopy was shown to be a useful
tool for obtaining concentration data of toxicants. However, its
operation and interpretation is far from routine. The losses of CO,
HCN, and HCl as they flowed down the corridor were found to be
dependent on the combustible. The downstream to upstream
concentration ratios varied from unity for some fuels to a factor
of five smaller for others. The CO yield from two of the
combustibles was significantly lower than the expected value of
0.2, which should be used in hazard and risk analyses. The accuracy
of the results is verified, and a hypothesis is offered for the
lower CO yield values.
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