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Books > Science & Mathematics > Chemistry > Physical chemistry > Electrochemistry & magnetochemistry
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Thermodynamics of Molecular Species (Hardcover)
Loot Price: R5,026
Discovery Miles 50 260
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Thermodynamics of Molecular Species (Hardcover)
Expected to ship within 12 - 17 working days
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A much-needed expansion of traditional chemical thermodynamic
concepts--essential reading for today's advanced students and
research professionals
Reflecting the current operational practice of chemistry, this
unique book provides an important update of traditional chemical
thermodynamics, especially the thermodynamics of liquid solutions.
Using a flexible composition model that enumerates both the formal
components of a system and the molecular species derived from them,
Thermodynamics of Molecular Species introduces a set of general
theorems and proofs that address a range of significant phenomena
beyond the reach of traditional chemical thermodynamics, such as
enthalpy-entropy compensation, molar shifts, and thermodynamic
error tolerance. Dr. Grunwald's novel approach creates a natural
framework for mechanistic studies of molecular phenomena, while at
the same time avoiding some of the complexity of statistical
thermodynamics. The book's features include:
* A broad definition of molecular species that includes all
participants in reaction mechanisms: reactants, products,
substrates, catalysts, reactive intermediates, and transition
states
* Solid experimental evidence supported by explicit examples
across a breadth of areas--including solvation, water and aqueous
solutions, environmental isomers, ions, and ion pairs
* Thermodynamic aspects of interionic attraction theory and of
structure-energy correlations
* Almost 100 figures and diagrams that express abstract and
mathematical ideas in clear and concrete terms
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