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Books > Science & Mathematics > Chemistry > Physical chemistry > Thermochemistry & chemical thermodynamics
Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical and Biological Systems, Fourth Edition emphasizes the unifying role of thermodynamics in analyzing natural phenomena. This updated edition expands on the third edition by focusing on the general balance equations for coupled processes of physical, chemical and biological systems. Updates include stochastic approaches, self-organization criticality, ecosystems, mesoscopic thermodynamics, constructual law, quantum thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems. The book also emphasizes nonequilibrium thermodynamics tools, such as fluctuation theories, mesoscopic thermodynamic analysis, information theories, and quantum thermodynamics in describing and designing small scale systems.
"Discusses the most recent advances in the correlations of structure and reactivity relationships of micelles, liposomes, microemulsions, and emulsions by thermal behavior measurements, as well as the options, scope, and limitations of the thermal behavior of dispersed systems. Highlights current studies on heterogeneous colloidal (dispersed) systems."
Handbook of Thermal Analysis and Calorimetry: Recent Advances, Techniques and Applications, Volume Six, Second Edition, presents the latest in a series that has been well received by the thermal analysis and calorimetry community. This volume covers recent advances in techniques and applications that complement the earlier volumes. There has been tremendous progress in the field in recent years, and this book puts together the most high-impact topics selected for their popularity by new editors Sergey Vyazovkin, Nobuyoshi Koga and Christoph Schick-all editors of Thermochimica Acta. Among the important new techniques covered are biomass conversion; sustainable polymers; polymer nanocompsoties; nonmetallic glasses; phase change materials; propellants and explosives; applications to pharmaceuticals; processes in ceramics, metals, and alloys; ionic liquids; fast-scanning calorimetry, and more.
The first edition of this text, entitled Flame and Combustion Phenomena, was published by Professor John Bradley in 1969. Subsequent to John Bradley's untimely death, the second edition, Flame and Combustion, was published in 1985 by Professor John Barnard. The intention of my predecessors was that the book should be suitable for final year under graduates and as an introductory book about combustion phenomena for those involved in research and development in a wide range of disciplines. It is my hope that the same is true of this third edition, with particular attention paid to chemical aspects. The potential market for an introductory text has changed consider ably since the appearance of John Bradley'S monograph. There has been a considerable growth in concern for efficiency, safety and minimisation of the environmental impact of combustion, whereas the development of rocket fuels, explosives and propellants do not command the same intensity of effort as formerly. Thus, it seems prudent to shift the emphasis from some parts of the earlier texts, and to expand others that are more in line with current combustion activities."
Cryogenics is the study of low temperature interactions -
temperatures well below those existing in the natural universe.
- Experiments described in technical detail
Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.
This book provides an accessible yet thorough introduction to thermodynamics, crafted and class-tested over many years of teaching. Suitable for advanced undergraduate and graduate students, this book delivers clear descriptions of how to think about the mathematics and physics involved. The content has been carefully developed in consultation with a large number of instructors, teaching courses worldwide, to ensure wide applicability to modules on thermodynamics. Modern applications of thermodynamics (in physics and related areas) are included throughout-something not offered to the same degree by existing texts in the field. Features: A sophisticated approach to the subject that is suitable for advanced undergraduate students and above Modern applications of thermodynamics included throughout To be followed by volumes on statistical mechanics, which can be used in conjunction with this book on courses which cover both thermodynamics and statistical mechanics
Hydrodynamics, Mass and Heat Transfer in Chemical Engineering contains a concise and systematic exposition of fundamental problems of hydrodynamics, heat and mass transfer, and physicochemical hydrodynamics, which constitute the theoretical basis of chemical engineering in science. Areas covered include: fluid flows; processes of chemical engineering; mass and heat transfer in plane channels, tubes and fluid films; problems of mass and heat transfer; the motion and mass exchange of power-law and viscoplastic fluids through tubes, channels, and films; and the basic concepts and properties of very specific technological media, namely foam systems. Topics are arranged in increasing order of difficulty, with each section beginning with a brief physical and mathematical statement of the problem considered, followed by final results, usually given for the desired variables in the form of final relationships and tables.
Thermodynamics and information touch theory every facet of chemistry. However, the physical chemistry curriculum digested by students worldwide is still heavily skewed toward heat/work principles established more than a century ago. Rectifying this situation, Chemical Thermodynamics and Information Theory with Applications explores applications drawn from the intersection of thermodynamics and information theory-two mature and far-reaching fields. In an approach that intertwines information science and chemistry, this book covers: The informational aspects of thermodynamic state equations The algorithmic aspects of transformations-compression, expansion, cyclic, and more The principles of best-practice programming How molecules transmit and modify information via collisions and chemical reactions Using examples from physical and organic chemistry, this book demonstrates how the disciplines of thermodynamics and information theory are intertwined. Accessible to curiosity-driven chemists with knowledge of basic calculus, probability, and statistics, the book provides a fresh perspective on time-honored subjects such as state transformations, heat and work exchanges, and chemical reactions.
This English translation of a well-known Japanese book covers interfacial physicochemistry in materials science, especially for iron- and steelmaking processes. Interfacial Physical Chemistry of High-Temperature Melts bridges the gap between the basics and applications of physicochemistry. The book begins with an overview of the fundamentals of interfacial physical chemistry and discusses surface tension, describing the derivation of important equations to guide readers to a deep understanding of the phenomenon. The book then goes on to introduce interfacial properties of high-temperature melts, especially the Marangoni effect, and discusses applications to materials processing at high temperature focusing on recent research results by the author and the co-workers. This book is aimed at researchers, graduate students, and professionals in materials processing. Video clips of in-situ observation including experiments under microgravity condition and x-ray observation are available for download on the publisher's website to allow for a deeper understanding.
This long-awaited, revised and updated reference/text combines a thorough description of the origin and application of fundamental chemical kinetics through an assessment of realistic reactor problems with an expanded discussion of kinetics and its relation to chemical thermodynamics. Provides exercises of gradiating difficulty that range from simple applications of equations and concepts developed in the text to open-ended situations drawing on creative thinking Adds a host of worked-out illustrations and a notation list after each chapter, reinforcing important concepts Retaining the careful organization and logical progression of ideas that characterized the first edition, the Second Edition of Reaction Kinetics and Reactor Design clarifies chain and polymerization reactions in greater depth contains new material on microbial and enzyme kinetics and adsorption-desorption theory streamlines the presentation of the derivations arising from the kinetic theory of gases addresses transport effect in catalytic reactions explains gas-solid noncatalytic reactions covers the development of two-phase reactor theory based on plug flow, mixing cell, and dispersion models introduces theory and design of fluid slurry and trickle beds examines catalyst deactivation phenomena, ion exchange, and chromatographic reactors and more Including over 1450 equations for developing rational chemical reactor designs and analysis models, the Second Edition of Reaction Kinetics and Reactor Design is an excellent reference for chemical, mechanical, petroleum, plant, process, civil, and design engineers, and an ideal text for upper-level undergraduate and graduate students in these disciplines.
Laser approaches to combustion diagnostics are of considerable interest due to their remote, non-intrusive and in-situ character, unlimited temperature capability, and potential for simultaneous temporal and spatial resolution. This book aims to make these powerful and important new tools in combustion research understandable. Focuses on spectroscopically-based, spatially-precise, laser techniques for temperature and chemical composition measurements in reacting and non-reacting flows. Following introductory chapters on basic spectroscopy, laser physics, experimental methods and practical considerations, treats each of the major techniques in some detail, replete with measurement examples and references. Concludes with a treatment of field methods which employs the various techniques to perform measurements simultaneously over a two-dimensional slice of the medium being probed.
Engineering Analysis of Fires and Explosions demonstrates how professional forensic engineers apply basic concepts and principles from engineering and scientific disciplines to analyze fires and explosions. It describes how forensic engineers use a "reverse design" process to determine the original cause of a fire or explosion. This guide incorporates practices and lessons learned from the first-hand experiences of the author and his colleagues. It is an exciting introduction to the multidisciplinary subject of fire and explosion analysis and its legal ramifications. The author's straightforward language and style make the concepts easy to understand.
The CRC Handbook of Thermophysical and Thermochemical Data is an interactive software and handbook package that provides an invaluable source of reliable data embracing a wide range of properties of chemical substances, mixtures, and reacting systems. Use the handbook and software together to quickly, and easily generate property values at any desired temperature, pressure, or mixture composition.
Handbook of Thermal Conductivity of Liquids and Gases covers practically all of the data available on the thermalconductivity of pure liquids and gases. Thermal conductivity data included in the book is based on original experimental measurements and correlations recommended or adopted as a standard by the National Standard Reference Data Service of the Russian Federation. New tabulations of thermal conductivity data on high-molecular organic fluids and the alkali metals in both liquid and gaseous states are featured as well. This book will be an important reference for all researchers working in thermodynamics.
Many scientists and engineers do not realize that, under certain conditions, friction can lead to the formation of new structures at the interface, including in situ tribofilms and various patterns. In turn, these structures-usually formed by destabilization of the stationary sliding regime-can lead to the reduction of friction and wear. Friction-Induced Vibrations and Self-Organization: Mechanics and Non-Equilibrium Thermodynamics of Sliding Contact combines the mechanical and thermodynamic methods in tribology, thus extending the field of mechanical friction-induced vibrations to non-mechanical instabilities and self-organization processes at the frictional interface. The book also relates friction-induced self-organization to novel biomimetic materials, such as self-lubricating, self-cleaning, and self-healing materials. Explore Friction from a Different Angle-as a Fundamental Force of Nature The book begins with an exploration of friction as a fundamental force of nature throughout the history of science. It then introduces general concepts related to vibrations, instabilities, and self-organization in the bulk of materials and at the interface. After presenting the principles of non-equilibrium thermodynamics as they apply to the interface, the book formulates the laws of friction and highlights important implications. The authors also analyze wear and lubrication. They then turn their attention to various types of friction-induced vibration, and practical situations and applications where these vibrations are important. The final chapters consider various types of friction-induced self-organization and how these effects can be used for novel self-lubricating, self-cleaning, and self-healing materials. From Frictional Instabilities to Friction-Induced Self-Organization Drawing on the authors' original research, this book presents a new, twenty-first century perspective on friction and tribology. It shows how friction-induced instabilities and vibrations can lead to self-organized structures, and how understanding the structure-property relationships that lead to self-organization is key to designing "smart" biomimetic materials.
Advances in Chemical Engineering, Volume 58 in this long-running serial, highlights new advances in the field with this new volume presenting interesting and timely chapters written by an international board of authors.
This book is a follow-on to the author's bestseller, Principles of Combustion, Second Edition published in 2005. The text covers advanced topics of combustion and flame that are not covered anywhere else. Kuo provides a multiphase systems approach beginning with more common topics and moving to higher level applications such as reacting boundary layer flows, ignition of homogeneous mixtures, flame extinction phenomena, and detonation processes in condensed phase materials. As with Kuo's earlier book, large numbers of examples and problems and a solutions manual are provided.
Thermal Analysis and Thermodynamic Properties of Solids, Second Edition covers foundational principles and recent updates in the field, presenting an authoritative overview of theoretical knowledge and practical applications across several fields. Since the first edition of this book was published, large developments have occurred in the theoretical understanding of-and subsequent ability to assess and apply-principles of thermal analysis. Drawing on the knowledge of its expert author, this second edition provides fascinating insight for both new and experienced students, researchers, and industry professionals whose work is influenced or impacted by thermo analysis principles and tools. Part 1 provides a detailed introduction and guide to theoretical aspects of thermal analysis and the related impact of thermodynamics. Key terminology and concepts, the fundamentals of thermophysical examinations, thermostatics, equilibrium background, thermotics, reaction kinetics and models, thermokinetics and the exploitation of fractals are all discussed. Part 2 then goes on to discuss practical applications of this theoretical information to topics such as crystallization kinetics and glass states, thermodynamics in superconductor models, and climate change.
The Thermodynamics of Phase and Reaction Equilibria, Second Edition, provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g., partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. Available computational software has made it possible for students to tackle realistic and challenging problems from industry. The second edition incorporates phase equilibrium problems dealing with nonideal mixtures containing more than two components and chemical reaction equilibrium problems involving multiple reactions. Computations are carried out with the help of Mathcad (R).
This English translation of a well-known Japanese book covers interfacial physicochemistry in materials science, especially for iron- and steelmaking processes. Interfacial Physical Chemistry of High-Temperature Melts bridges the gap between the basics and applications of physicochemistry. The book begins with an overview of the fundamentals of interfacial physical chemistry and discusses surface tension, describing the derivation of important equations to guide readers to a deep understanding of the phenomenon. The book then goes on to introduce interfacial properties of high-temperature melts, especially the Marangoni effect, and discusses applications to materials processing at high temperature focusing on recent research results by the author and the co-workers. This book is aimed at researchers, graduate students, and professionals in materials processing. Video clips of in-situ observation including experiments under microgravity condition and x-ray observation are available for download on the publisher's website to allow for a deeper understanding.
In handbook form, this reference monograph provides both experimental and theoretical data describing thermodynamic properties of groups of isomers of different classes, particularly for organic compound reactions. Data have been derived through chemical equilibria studies, statistical thermodynamics, and to some degree, calorimetry. Data based on equilibria studies are also valuable as a cross-check to thermodynamic functions derived purely from calorimetric measurements.
Thermodynamics: Principles Characterizing Physical and Chemical Processes, Fifth Edition is an authoritative guide on the physical and chemical processes based on classical thermodynamic principles. Emphasis is placed on fundamental principles, with a combination of theory and practice that demonstrates their applications in a variety of disciplines. Revised and updated to include new material and novel formulations, this edition features a new chapter on algebraic power laws and Fisher information theory, along with detailed updates on irreversible phenomena, Landau theory, self-assembly, Caratheodory's theorem, and the effects of externally applied fields. Drawing on the experience of its expert author, this book is a useful tool for both graduate students, professional chemists, and physicists who wish to acquire a more sophisticated overview of thermodynamics and related subject matter. |
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