Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.

Companion to Chemical Thermodynamics accompanies the newly published Chemical Thermodynamics, 6th Edition, a well-known upper-division undergraduate/graduate text on classical thermodynamics.

The aim of this contemporary textbook is to show students that thermodynamics is a useful tool, not just a series of theoretical exercises. Written in a conversational style, the text presents the second law in a totally new manner----there is no reliance on statistical arguments; instead it is developed as a natural consequence of physical experience. Students are not required to write complex, iterative computer programs to solve phase equilibrium problems----techniques are presented which enable use of readily available math packages. The book also explores electrochemical systems such as batteries and fuel cells. Included in the extensive amount of examples are those which demonstrate the use of thermodynamics in practical design situations.

Reaction Rate Theory and Rare Events bridges the historical gap between these subjects because the increasingly multidisciplinary nature of scientific research often requires an understanding of both reaction rate theory and the theory of other rare events. The book discusses collision theory, transition state theory, RRKM theory, catalysis, diffusion limited kinetics, mean first passage times, Kramers theory, Grote-Hynes theory, transition path theory, non-adiabatic reactions, electron transfer, and topics from reaction network analysis. It is an essential reference for students, professors and scientists who use reaction rate theory or the theory of rare events. In addition, the book discusses transition state search algorithms, tunneling corrections, transmission coefficients, microkinetic models, kinetic Monte Carlo, transition path sampling, and importance sampling methods. The unified treatment in this book explains why chemical reactions and other rare events, while having many common theoretical foundations, often require very different computational modeling strategies.

Introduction to the Technology of Explosives Paul W. Cooper and Stanley R. Kurowski Introduction to the Technology of Explosives is a clear and concise survey of the technologies and physical processes involved in explosive phenomena. The book is intended to provide the worker new to the field with sufficient background to understand problems that may arise and to interact intelligently with specialists in the field. The book covers the fundamentals of the chemistry of explosives; the mechanics of burning; sound, shock, and detonation; initiation and initiators; scaling in design and analysis; and off-the-shelf explosive devices. It provides the basic calculational skills needed to solve simple, first-order engineering design problems, and emphasizes the crucial importance of safety considerations. The book contains a broad range of data on explosive materials, and their properties and behavior, along with extensive lists of useful references. Example problems with solutions are provided in each technical area, as are descriptions and analysis of a wide variety of explosive devices. The book concludes with a thorough and comprehensive description of regulatory requirements for the classification, transportation, and storage of explosives, and an extensive guide to explosives safety in plant and test facilities. This book will be of interest to explosives technicians and engineers, government regulators, crime and accident scene investigators, and instructors in military, police, and FBI bomb schools.

This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Neel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This textbook is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge.

John Wiley & Sons, Inc. is proud to announce an important new series of textbooks -- The Mit Series in Materials Science and Engineering. In response to the growing economic and technological importance of polymers, ceramics, and semi-conductors, many materials science and engineering departments are changing and expanding their curricula. The advent of new courses calls for the development of new textbooks that teach the principles of materials science and engineering as they apply to all the classes of materials. The Mit Series in Materials Science and Engineering is designed to fill the needs of this changing curriculum. Based on the undergraduate curriculum of the MIT Department of Materials Science and Engineering, the series will include textbooks for the core course in the field as well as text for courses in specific material classes. The first three textbooks in the series will be: Thermodynamics of Materials, Vol. I, by David Ragone (0-471-30885-4) Thermodynamics of Materials, Vol. II, by David Ragone (0-471-30886-2) Physical Ceramics: Principles for Ceramics Science and Engineering, by Yet-Ming Chiang, Dunbar Birnie III, and W. David Kingery(0-471-59873-9)

This book provides a sound foundation for understanding abstract concepts of phase and reaction equilibria (e.g. partial molar Gibbs energy, fugacity, and activity), and shows how to apply these concepts to solve practical problems using numerous clear examples. It also presents numerical methods necessary for solving real-world problems as well the basic mathematics needed, facilitating its use as a self-study reference work. In the example problems requiring MATHCAD(r) for the solution, the results of the intermediate steps are given, enabling the reader to easily track mistakes and understand the order of magnitude of the various quantities involved.

Clear layout, coherent and logical organization of the content, and presentation suitable for self-studyProvides analytical equations in dimensionless form for the calculation of changes in internal energy, enthalpy, and entropy as well as departure functions and fugacity coefficients Includes up-to-date information, comprehensive in-depth content and current examples in each chapter Includes many well organized problems (with answers), which are extensions of the examples enabling conceptual understanding for quantitative/real problem solving Includes the mathematical background required for solving problems encountered in phase and reaction equilibria Provides an instructor s solutions manual "

Written to introduce readers to molecular descriptions of thermodynamics, chemical systems, and biomolecules, Statistical Thermodynamics discusses the aspects of statistical thermodynamics of most use and interest to chemistry students. Topics include: probability; energy and interactions; statistical mechanics; harmonic oscillators; ideal gas; imperfect gas; heat capacities of gas; rubber elasticity; conformation of polymers; surface adsorption; law of mass action; Ising model; and more. Rich with illustrations and tables to illuminate rather difficult concepts, the text equips students with the ability to apply the method to their own systems.

The first two editions of Concise Chemical Thermodynamics proved to be a very popular introduction to a subject many undergraduate students perceive to be difficult due to the underlying mathematics. With its concise explanations and clear examples, the text has for the past 40 years clarified for countless students one of the most complicated branches of science. Following in the tradition of its predecessors, this Third Edition continues to offer a practical, example-based exploration of a critical topic, maintaining academic rigor but eschewing complicated calculations.

Updated to reflect new concerns in the 21st century, this edition now includes:

• An extensive outlook on the world s current energy consumption and the role of renewable energy in the future
• An example of an exothermic reaction through a discussion of the Mond process for extracting and purifying nickel
• The use of Mathcad(r) to calculate a plot of Gibbs energy for a reaction mixture versus the extent of reaction
• An explanation of the Lambda sensor, which reduces vehicle emissions
• The use of FactSage software to calculate and describe the production of silicon in an arc (oven) furnace

This latest edition re-works problems that have proven to be the most difficult for students and adds several new ones to further amplify complex areas. The book also provides an updated list of suggested readings. Keeping pace with new technology and the shift in emphasis to green chemistry, this volume provides an up-to-date treatment of a foundational topic.

This book offers advanced students, in 7 volumes, successively characterization tools phases, the study of all types of phase, liquid, gas and solid, pure or multi-component, process engineering, chemical and electrochemical equilibria, the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention is given to the rigor of mathematical developments. This book focuses on solid phases.

This textbook introduces thermodynamics with a modern approach, starting from four fundamental physical facts (the atomic nature of matter, the indistinguishability of atoms and molecules of the same species, the uncertainty principle, and the existence of equilibrium states) and analyzing the behavior of complex systems with the tools of information theory, in particular with Shannon's measure of information (or SMI), which can be defined on any probability distribution. SMI is defined and its properties and time evolution are illustrated, and it is shown that the entropy is a particular type of SMI, i.e. the SMI related to the phase-space distribution for a macroscopic system at equilibrium. The connection to SMI allows the reader to understand what entropy is and why isolated systems follow the Second Law of Thermodynamics. The Second Llaw is also formulated for other systems, not thermally isolated and even open with respect to the transfer of particles. All the fundamental aspects of thermodynamics are derived and illustrated with several examples in the first part of the book. The second part addresses important applications of thermodynamics, covering phase transitions, mixtures and solutions (including the Kirkwood-Buff approach and solvation thermodynamics), chemical equilibrium, and the outstanding properties of water.This textbook is unique in two aspects. First, thermodynamics is introduced with a novel approach, based on information theory applied to macroscopic systems at equilibrium. It is shown that entropy is a particular case of Shannon's measure of information (SMI), and the properties and time evolution of the SMI are used to explain the Second Law of Thermodynamics. This represents a real breakthrough, as classical thermodynamics cannot explain entropy, nor clarify why systems should obey the Second Law. Second, this textbook offers the reader the possibility to get in touch with important and advanced applications of thermodynamics, to address the topics discussed in the second part of the book. Although they may go beyond the content of a typical introductory course on thermodynamics, some of them can be important in the curriculum chosen by the student. At the same time, they are of appealing interest to more advanced scholars.

Transport Phenomena Second Edition W. J. Beek K. M. K. Muttzall J. W. van Heuven Momentum, heat and mass transport phenomena can be found everywhere in nature. A solid understanding of the principles of these processes is essential for chemical and process engineers. The second edition of Transport Phenomena builds on the foundation of the first edition which presented fundamental knowledge and practical application of momentum, heat and mass transfer processes in a form useful to engineers. This revised edition includes revisions of the original text in addition to new applications providing a thoroughly updated edition. This updated text includes;
* An introduction to physical transport analysis including units, dimensional analysis and conservation laws.
* A systematic treatment of fluid flow and heat and mass transport, their similarities and dissimilarities.
* Theoretical and semi-empirical equations and a condensed overview of practical data.
* Illustrative problems showing practical applications.
* A problem section at the end of each chapter with answers and explanations.

Environmental problems are becoming an important aspect of our lives as industries grow apace with populations throughout the world. Thermodynamics, Solubility and Environmental Issues highlights some of the problems and shows how chemistry can help to reduce these them. The unifying theme is Solubility - the most basic and important of thermodynamic properties. This informative book looks at the importance and applications of solubility and thermodynamics, in understanding and in reducing chemical pollution in the environment.
Written by experts in their respective fields and representing the latest findings in this very important and broad area. A collection of twenty-five chapters cover a wide range of topics including; mining, polymer manufacture and applications, radioactive wastes, industries in general, agro-chemicals, soil pollution and biology, together with the basic theory and recent developments in the modelling of environmental pollutants.
* Latest research into solving some of the most important environmental problems
* Covering new technologies, new chemicals and new processes eg, biodegradable polymers, ionic liquids and green chemistry
* Contains the basic theories and underlying importance of solubility

"Thermal Convection - Patterns, Stages of Evolution and Stability Behavior" provides the reader with an ensemble picture of the subject, illustrating the state-of-the-art and providing the researchers from universities and industry with a basis on which they are able to estimate the possible impact of a variety of parameters. Unlike earlier books on the subject, the heavy mathematical background underlying and governing the behaviors illustrated in the text are kept to a minimum.

The text clarifies some still unresolved controversies pertaining to the physical nature of the dominating driving force responsible for asymmetric/oscillatory convection in various natural phenomena and/or technologically important processes and can help researchers in elaborating and validating new, more complex models, in accelerating the current trend towards predictable and reproducible natural phenomena and in establishing an adequate scientific foundation to industrial processes.

"Thermal Convection - Patterns, Stages of Evolution and Stability Behavior" is intended as a useful reference guide for specialists in disciplines such as the metallurgy and foundry field and researchers and scientists who are now coordinating their efforts to improve the quality of semiconductor or macromolecular crystals. The text may also be of use to organic chemists and materials scientists, atmosphere and planetary physicists, as well as an advanced level text for students taking part in courses on the physics of fluids, fluid mechanics, the behavior and evolution of non-linear systems, environmental phenomena and materials engineering.

Application of Thermal Analysis to Kinetic Evaluation of Thermal Decomposition (D. Dollimore & M. Reading).

Thermometric Titrations and Enthalpimetric Analysis (J. Jordan & J. Stahl).

Thermogravimetry (J. Dunn & J. Sharp).

The Application of Thermodilatometry to the Study of Ceramics (M. Ish-Shalom).

Pyrolysis Techniques (W. Irwin).

Application of Thermal Analysis to Problems in Cement Chemistry (J. Bhatty).

Subject Index for Volume 13.

Handbook of Thermal Analysis and Calorimetry, Volume 1: Principles and Practice describes the basic background information common to thermal analysis and calorimetry in general. Thermodynamic and kinetic principles are discussed along with the instrumentation and methodology associated with thermoanalytical and calorimetric techniques. The purpose is to collect the discussion of these general principles and minimize redundancies in the subsequent volumes that are concerned with the applications of these principles and methods. More unique methods, which pertain to specific processes or materials, are covered in later volumes.

• A completely updated, expanded edition of a longstanding and influential text on chemical thermodynamics
  
• Covers the logical foundations and interrelationships of thermodynamics and their application to problems that are commonly encountered by the chemist.
  
• Explanations of abstract concepts in a clear and simple, yet still rigorous fashion
  
• Logical arrangement of the material to facilitate learning, including worked out examples.
  
• Computational techniques, graphical, numerical, and analytical, are described fully and are used frequently, both in illustrative and in assigned problems.

This book provides the first systematic treatment of the thermodynamic theory of site-specific effects in biological macromolecules. It describes the phenomenological and conceptual bases required to allow a mechanistic understanding of these effects from analysis of experimental data. The thermodynamic theory also results in novel experimental strategies that enable the derivation of information on local, site-specific properties of a macromolecular system from analysis of perturbed global properties. The treatment focuses on binding phenomena, but is amenable to extension both conceptually and formally to the analysis of other cooperative processes, such as folding and helix coil transitions. This book will interest any scientist involved in structure function studies of biological macromolecules, or as a text for graduate students in biochemistry and biophysics.

This concise text provides an essential treatment of thermodynamics and a discussion of the basic principles built on an intuitive description of the microscopic behavior of matter. Aimed at a range of courses in mechanical and aerospace engineering, the presentation explains the foundations valid at the macroscopic level in relation to what happens at the microscopic level, relying on intuitive and visual explanations which are presented with engaging cases. With ad hoc, real-word examples related also to current and future renewable energy conversion technologies and two well-known programs used for thermodynamic calculations, FluidProp and StanJan, this text provides students with a rich and engaging learning experience.

A comprehensive introduction, examining both macroscopic and microscopic aspects of the subject, the book applies the theory of thermodynamics to a broad range of materials; from metals, ceramics and other inorganic materials to geological materials. Focusing on materials rather than the underlying mathematical concepts of the subject, this book will be ideal for the non-specialist requiring an introduction to the energetics and stability of materials. Macroscopic thermodynamic properties are linked to the underlying miscroscopic nature of the materials and trends in important properties are discussed. It is a unique approach covering both macroscopic and microscopic aspects of the subject. Authors have worldwide reputations in this area. It fills a gap in the market by featuring a wide range of real up-to-date examples and covering a large amount of materials.

This is an introduction to statistical mechanics, intended to be used either in an undergraduate physical chemistry course or by beginning graduate students with little undergraduate background in the subject. It assumes familiarity with thermodynamics, chemical kinetics, the kinetic theory of gases, quantum mechanics and spectroscopy, at the level at which these subjects are normally treated in undergraduate physical chemistry. Highly illustrated with numerous exercises and worked solutions, it provides a concise, up-to-date treatise of statistical mechanics and is ideally suited to use in one semester courses.

This book looks at how molecules react, and how the feasibility and outcome of chemical reactions can be predicted. Beginning with an introduction to the concept of an activity series of metals, Metals and Chemical Change then introduces chemical thermodynamics (enthalpy, entropy and free energy) and applies the concept to both inorganic and organic elements. A Case Study on batteries and fuel cells is also included. The accompanying CD-ROM includes video sequences of the reactions of metals with water, acid and aqueous ions, and gives the reader an opportunity to make experimental observations and predictions about chemical behaviour. A comprehensive Data Book of chemical and physical constants is included, along with a set of interactive self-assessment questions. The Molecular World series provides an integrated introduction to all branches of chemistry for both students wishing to specialise and those wishing to gain a broad understanding of chemistry and its relevance to the everyday world and to other areas of science. The books, with their Case Studies and accompanying multi-media interactive CD-ROMs, will also provide valuable resource material for teachers and lecturers. (The CD-ROMs are designed for use on a PC running Windows 95, 98, ME or 2000.)

This is a comprehensive and authoritative treatise on all aspects of the theory, instrumentation and practical usefulness of electrothermal atomic absorption spectrometry (ETAAS) and associated techniques. This book reflects the significant changes that have taken place in this popular technique for the accurate determination of metals at ultratrace concentrations in a wide variety of sample types.
This book provides coverage of:
* The evolution of ETAAS
* Heating characteristics of graphite furnace atomizers
* Detailed descriptions of modern instrumentation
* The use of chemical modifiers
* Atomization from solids and slurries
* Other specialized techniques using electrothermal atomizers
* Extensive cross-referencing between chapters
Comprehensive coverage combined with a descriptive style make this a key resource for graduate students in analytical chemistry, researchers in analytical atomic spectrometry and analysts who routinely use ETAAS.

Complexity and Complex Thermoeconomic Systems describes the properties of complexity and complex thermo-economic systems as the consequence of formulations, definitions, tools, solutions and results consistent with the best performance of a system. Applying to complex systems contemporary advanced techniques, such as static optimization, optimal control, and neural networks, this book treats the systems theory as a science of general laws for functional integrities. It also provides a platform for the discussion of various definitions of complexity, complex hierarchical structures, self-organization examples, special references, and historical issues. This book is a valuable reference for scientists, engineers and graduated students in chemical, mechanical, and environmental engineering, as well as those in physics, ecology and biology, helping them better understand the complex thermodynamic systems and enhance their technical skills in research.