This textbook introduces thermodynamics with a modern approach, starting from four fundamental physical facts (the atomic nature of matter, the indistinguishability of atoms and molecules of the same species, the uncertainty principle, and the existence of equilibrium states) and analyzing the behavior of complex systems with the tools of information theory, in particular with Shannon's measure of information (or SMI), which can be defined on any probability distribution. SMI is defined and its properties and time evolution are illustrated, and it is shown that the entropy is a particular type of SMI, i.e. the SMI related to the phase-space distribution for a macroscopic system at equilibrium. The connection to SMI allows the reader to understand what entropy is and why isolated systems follow the Second Law of Thermodynamics. The Second Llaw is also formulated for other systems, not thermally isolated and even open with respect to the transfer of particles. All the fundamental aspects of thermodynamics are derived and illustrated with several examples in the first part of the book. The second part addresses important applications of thermodynamics, covering phase transitions, mixtures and solutions (including the Kirkwood-Buff approach and solvation thermodynamics), chemical equilibrium, and the outstanding properties of water.This textbook is unique in two aspects. First, thermodynamics is introduced with a novel approach, based on information theory applied to macroscopic systems at equilibrium. It is shown that entropy is a particular case of Shannon's measure of information (SMI), and the properties and time evolution of the SMI are used to explain the Second Law of Thermodynamics. This represents a real breakthrough, as classical thermodynamics cannot explain entropy, nor clarify why systems should obey the Second Law. Second, this textbook offers the reader the possibility to get in touch with important and advanced applications of thermodynamics, to address the topics discussed in the second part of the book. Although they may go beyond the content of a typical introductory course on thermodynamics, some of them can be important in the curriculum chosen by the student. At the same time, they are of appealing interest to more advanced scholars.

This book contains the latest information on all aspects of the most important chemical thermodynamic properties of Gibbs energy and Helmholtz energy, as related to fluids. Both the Gibbs energy and Helmholtz energy are very important in the fields of thermodynamics and material properties as many other properties are obtained from the temperature or pressure dependence. Bringing all the information into one authoritative survey, the book is written by acknowledged world experts in their respective fields. Each of the chapters will cover theory, experimental methods and techniques and results for all types of liquids and vapours. This book is the fourth in the series of Thermodynamic Properties related to liquids, solutions and vapours, edited by Emmerich Wilhelm and Trevor Letcher. The previous books were: Heat Capacities (2010), Volume Properties (2015), and Enthalpy (2017). This book fills the gap in fundamental thermodynamic properties and is the last in the series.

Thermodynamics is fundamental to university and college curricula in chemistry, physics, engineering and many life sciences around the world. It is also notoriously difficult for students to understand, learn and apply. What makes this book different, and special, is the clarity of the text. The writing style is fluid, natural and lucid, and everything is explained in a logical and transparent manner. Thermodynamics is a deep, and important, branch of science, and this book does not make it "easy". But it does make it intelligible. This book introduces a new, 'Fourth Law' of Thermodynamics' based on the notion of Gibbs free energy, which underpins almost every application of thermodynamics and which the authors claim is worthy of recognition as a 'law'. The last four chapters bring thermodynamics into the twenty-first century, dealing with bioenergetics (how living systems capture and use free energy), macromolecule assembly (how proteins fold), and macromolecular aggregation (how, for example, virus capsids assemble). This is of great current relevance to students of biochemistry, biochemical engineering and pharmacy, and is covered in very few other texts on thermodynamics. The book also contains many novel and effective examples, such as the explanation of why friction is irreversible, the proof of the depression of the freezing point, and the explanation of the biochemical standard state.

Transport Phenomena Second Edition W. J. Beek K. M. K. Muttzall J. W. van Heuven Momentum, heat and mass transport phenomena can be found everywhere in nature. A solid understanding of the principles of these processes is essential for chemical and process engineers. The second edition of Transport Phenomena builds on the foundation of the first edition which presented fundamental knowledge and practical application of momentum, heat and mass transfer processes in a form useful to engineers. This revised edition includes revisions of the original text in addition to new applications providing a thoroughly updated edition. This updated text includes;
* An introduction to physical transport analysis including units, dimensional analysis and conservation laws.
* A systematic treatment of fluid flow and heat and mass transport, their similarities and dissimilarities.
* Theoretical and semi-empirical equations and a condensed overview of practical data.
* Illustrative problems showing practical applications.
* A problem section at the end of each chapter with answers and explanations.

Introducing Biological Energetics is a novel, interdisciplinary text that presents biological understanding in terms of general underlying principles, treating energy as the overarching theme and emphasizing the all-pervading influence of energy transformation in every process, both living and non-living. Key processes and concepts are explained in turn, culminating in a description of the overall functioning and regulation of a living cell. The book rounds off the story of life with a brief account of the endosymbiotic origins of eukaryotic cells, the development of multicellularity, and the emergence of modern plants and animals.
Multidisciplinary research in science is becoming commonplace. However, as traditional boundaries start to break down, researchers are increasingly aware of the deficiencies in their knowledge of related disciplines. Introducing Biological Energetics redresses the reciprocal imbalance in the knowledge levels of physical and biological scientists in particular. Its style of presentation and depth of treatment has been carefully designed to unite these two readerships.

Distillation is a major separation technique practised in the food, chemical, pharmaceutical, petrochemical, petroleum refining, gas and alcohol industries. Because of its low cost and high potential for better thermodynamic efficiency, it is likely to remain the most common method of separation in these industries. This book is a companion volume to Distillation Operation, and it aims to continue the updated account of this evolving separation process. It loooks at process and equipment design procedures, practical limitations and solutions to typical problems. Each chapter ends with sections on nomenclature and references.

This concise text provides an essential treatment of thermodynamics and a discussion of the basic principles built on an intuitive description of the microscopic behavior of matter. Aimed at a range of courses in mechanical and aerospace engineering, the presentation explains the foundations valid at the macroscopic level in relation to what happens at the microscopic level, relying on intuitive and visual explanations which are presented with engaging cases. With ad hoc, real-word examples related also to current and future renewable energy conversion technologies and two well-known programs used for thermodynamic calculations, FluidProp and StanJan, this text provides students with a rich and engaging learning experience.

John Wiley & Sons, Inc. is proud to announce an important new series of textbooks -- The Mit Series in Materials Science and Engineering. In response to the growing economic and technological importance of polymers, ceramics, and semi-conductors, many materials science and engineering departments are changing and expanding their curricula. The advent of new courses calls for the development of new textbooks that teach the principles of materials science and engineering as they apply to all the classes of materials. The Mit Series in Materials Science and Engineering is designed to fill the needs of this changing curriculum. Based on the undergraduate curriculum of the MIT Department of Materials Science and Engineering, the series will include textbooks for the core course in the field as well as text for courses in specific material classes. The first three textbooks in the series will be: Thermodynamics of Materials, Vol. I, by David Ragone (0-471-30885-4) Thermodynamics of Materials, Vol. II, by David Ragone (0-471-30886-2) Physical Ceramics: Principles for Ceramics Science and Engineering, by Yet-Ming Chiang, Dunbar Birnie III, and W. David Kingery(0-471-59873-9)

This book provides the first systematic treatment of the thermodynamic theory of site-specific effects in biological macromolecules. It describes the phenomenological and conceptual bases required to allow a mechanistic understanding of these effects from analysis of experimental data. The thermodynamic theory also results in novel experimental strategies that enable the derivation of information on local, site-specific properties of a macromolecular system from analysis of perturbed global properties. The treatment focuses on binding phenomena, but is amenable to extension both conceptually and formally to the analysis of other cooperative processes, such as folding and helix coil transitions. This book will interest any scientist involved in structure function studies of biological macromolecules, or as a text for graduate students in biochemistry and biophysics.

This is an introduction to statistical mechanics, intended to be used either in an undergraduate physical chemistry course or by beginning graduate students with little undergraduate background in the subject. It assumes familiarity with thermodynamics, chemical kinetics, the kinetic theory of gases, quantum mechanics and spectroscopy, at the level at which these subjects are normally treated in undergraduate physical chemistry. Highly illustrated with numerous exercises and worked solutions, it provides a concise, up-to-date treatise of statistical mechanics and is ideally suited to use in one semester courses.

The renowned Oxford Chemistry Primers series, which provides focused introductions to a range of important topics in chemistry, has been refreshed and updated to suit the needs of today's students, lecturers, and postgraduate researchers. The rigorous, yet accessible, treatment of each subject area is ideal for those wanting a primer in a given topic to prepare them for more advanced study or research. Moreover, cutting-edge examples and applications throughout the texts show the relevance of the chemistry being described to current research and industry. This new edition of Thermodynamics of Chemical Processes is the only self-contained text to cover the thermodynamics of chemical processes at a level appropriate for undergraduates. Describing the basic principles which govern reactivity and phase equilibria in chemical systems, the text is written at the first year undergraduate level and contains a number of worked examples and problems to help students through this introductory material. It shows the application of the theory to disciplines such as biochemistry, materials science, environmental science, forensic and analytical sciences. This new edition places an emphasis on applying the principles and solving problems rather than on formal proof of theorems and detailed mathematical understanding. The ideas of enthalpy, internal energy and entropy are covered to lead into Gibbs free energy and how it can be used to correlate and predict the equilibrium position and properties of chemical reactions and multi-phase systems. Background mathematical ideas are introduced as needed, and the text includes material describing how the physicochemical principles can be applied to related areas such as materials science or biochemistry.

This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been paid to the rigor of mathematical developments. This sixth volume is made up of two parts. The first part focuses on the study of ionic equilibria in water or non-aqueous solvents. The following are then discussed in succession: the dissociation of electrolytes, solvents and solvation, acid-base equilibria, formation of complexes, redox equilibria and the problems of precipitation. Part 2 discusses electrochemical thermodynamics, with the study of two groups: electrodes and electrochemical cells. The book concludes with the study of potential-pH diagrams and their generalization in an aqueous or non-aqueous medium.

In each generation, scientists must redefine their fields: abstracting, simplifying and distilling the previous standard topics to make room for new advances and methods. Sethna's book takes this step for statistical mechanics - a field rooted in physics and chemistry whose ideas and methods are now central to information theory, complexity, and modern biology. Aimed at advanced undergraduates and early graduate students in all of these fields, Sethna limits his main presentation to the topics that future mathematicians and biologists, as well as physicists and chemists, will find fascinating and central to their work. The amazing breadth of the field is reflected in the author's large supply of carefully crafted exercises, each an introduction to a whole field of study: everything from chaos through information theory to life at the end of the universe.

Thermal physics deals with collections of large numbers of particles - typically 10 to the 23rd power or so. Examples include the air in a balloon, the water in a lake, the electrons in a chunk of metal, and the photons given off by the sun. We can't possibly follow every detail of the motions of so many particles. So in thermal physics we assume that these motions are random, and we use the laws of probability to predict how the material as a whole ought to behave. Alternatively, we can measure the bulk properties of a material, and from these infer something about the particles it is made of. This book will give you a working understanding of thermal physics, assuming that you have already studied introductory physics and calculus. You will learn to apply the general laws of energy and entropy to engines, refrigerators, chemical reactions, phase transformations, and mixtures. You will also learn to use basic quantum physics and powerful statistical methods to predict in detail how temperature affects molecular speeds, vibrations of solids, electrical and magnetic behaviors, emission of light, and exotic low-temperature phenomena. The problems and worked examples explore applications not just within physics but also to engineering, chemistry, biology, geology, atmospheric science, astrophysics, cosmology, and everyday life.

Containing the very latest information on all aspects of enthalpy and internal energy as related to fluids, this book brings all the information into one authoritative survey in this well-defined field of chemical thermodynamics. Written by acknowledged experts in their respective fields, each of the 26 chapters covers theory, experimental methods and techniques and results for all types of liquids and vapours. These properties are important in all branches of pure and applied thermodynamics and this vital source is an important contribution to the subject hopefully also providing key pointers for cross-fertilization between sub-areas.

Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs.

"Phase Equilibrium Engineering" presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions.

The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering.

Methodologies are discussed using relevant industrial examples

The molecular nature and composition of the process mixture is given a key role in process decisions

Phase equilibrium diagrams are used as a drawing board for process implementation

In this text the authors present current research in the study of different types of reactions, fundamental processes and advanced technologies of combustion. The topics discussed in this compilation include the Lagrangian formulation to treating the turbulent reacting flows; g-equation in white-noise in time turbulent velocity field; deposition of thin functional coatings at atmospheric pressure using combustion chemical vapour deposition; fundamentals of oxy-fuel carbon capture technology for pulverised fuel boilers; combustion of lignocellulosic biomass and marine biomass by means of thermal analyses; methane combustion by electrochemical promotion of catalysis phenomenon; novel nitrate-free acetate-H2O2 combustion synthesis; and solution combustion method.

This book looks at how molecules react, and how the feasibility and outcome of chemical reactions can be predicted. Beginning with an introduction to the concept of an activity series of metals, Metals and Chemical Change then introduces chemical thermodynamics (enthalpy, entropy and free energy) and applies the concept to both inorganic and organic elements. A Case Study on batteries and fuel cells is also included. The accompanying CD-ROM includes video sequences of the reactions of metals with water, acid and aqueous ions, and gives the reader an opportunity to make experimental observations and predictions about chemical behaviour. A comprehensive Data Book of chemical and physical constants is included, along with a set of interactive self-assessment questions. The Molecular World series provides an integrated introduction to all branches of chemistry for both students wishing to specialise and those wishing to gain a broad understanding of chemistry and its relevance to the everyday world and to other areas of science. The books, with their Case Studies and accompanying multi-media interactive CD-ROMs, will also provide valuable resource material for teachers and lecturers. (The CD-ROMs are designed for use on a PC running Windows 95, 98, ME or 2000.)

The use of thermal and calorimetric methods has shown rapid growth over the last two decades, in an increasingly wide range of applications. In addition, a number of powerful new techniques have been developed. This book supplies a concise and readable account of the principles, experimental apparatus and practical procedures used in thermal analysis and calorimetric methods of analysis. Brief accounts of the basic theory are reinforced with detailed applications of the methods and contemporary developments. Also included is information on standard test methods and manufacturers. Written by acknowledged experts, Principles of Thermal Analysis and Calorimetry is up-to-date, wide-ranging and practical. It will be an important source of information for many levels of readership in a variety of areas, from students and lecturers through to industrial and laboratory staff and consultants.

John Wiley & Sons, Inc. is proud to announce an important new series of textbooks -- The MIT Series in Materials Science and Engineering. In response to the growing economic and technological importance of polymers, ceramics, and semi-conductors, many materials science and engineering departments are changing and expanding their curricula. The advent of new courses calls for the development of new textbooks that teach the principles of materials science and engineering as they apply to all the classes of materials. The MIT Series in Materials Science and Engineering is designed to fill the needs of this changing curriculum. Based on the undergraduate curriculum of the MIT Department of Materials Science and Engineering, the series will include textbooks for the core courses in the field as well as texts for courses in specific material classes. The first three textbooks in the series will be: Thermodynamics of Materials, Vol. I, by David Ragone (0-471-30885-4) Thermodynamics of Materials, VoL. II, by David Ragone (0-471-30886-2) Physical Ceramics: Principles for Ceramics Science and Engineering, by Yet-Ming Chiang, Dunbar Birnie III, and W. David Kingery (0-471-59873-9)

Mass and Density Determinations (R. Davis & W. Koch).

Pressure and Vacuum Measurements (C. Tilford).

Experimental Methods for Studying Diffusion in Gases, Liquids, and Solids (P. Dunlop, et al.).

Determination of Solubility (D. Wyatt & L. Grady).

Viscosity and Its Measurements (J. Greener).

Temperature Measurement with Application to Phase Equilibria Studies (J. Ott & J. Goates).

Calorimetry (J. Oscarson & R. Izatt).

Differential Thermal Methods (J. Boerio-Goates & J. Callanan).

Index.

The fundamental principles of classic thermodynamics as they apply in science and engineering are illustrated here in numerous, fully worked out examples. Equally valuable at undergraduate and first-year graduate levels, this powerful study tool takes students from fundamental laws to the behavior of PVT systems, to the treatment of flow processes, the basics of chemical thermodynamics and more. Hundreds of review problems with answers speed comprehension and reinforce learning.

Comprising two volumes this work provides a particularly comprehensive account of the development of kinetic theory and statistical mechanics up to the beginning of the 20th century. The author's historical researches go far beyond any other books on the subject, filling in many more details and putting the history of kinetic theory in the context of 19th century scientific and intellectual history. In the course of detailed examination of the sources, both published and unpublished, the author throws much new light on the dynamics of scientific change, and refutes some generally accepted ideas about historical events. In one section of the work, he demonstrates the use of a kind of historical document which has rarely, if ever, been exploited by historians of science, namely, referees' reports. The work is primarily directed towards physicists, but as it is not only concerned with technical aspects of the history of physics but also deals with cultural and philosophical connections, it will also appeal to historians of science and philosophers. Book 2 is completed by an unusually comprehensive bibliography.

Hydrocarbon production, gas recovery from shale, CO2 storage and water management have a common scientific underpinning: multiphase flow in porous media. This book provides a fundamental description of multiphase flow through porous rock, with emphasis on the understanding of displacement processes at the pore, or micron, scale. Fundamental equations and principal concepts using energy, momentum, and mass balance are developed, and the latest developments in high-resolution three-dimensional imaging and associated modelling are explored. The treatment is pedagogical, developing sound physical principles to predict flow and recovery through complex rock structures, while providing a review of the recent literature. This systematic approach makes it an excellent reference for those who are new to the field. Inspired by recent research, and based on courses taught to thousands of students and professionals from around the world, it provides the scientific background necessary for a quantitative assessment of multiphase subsurface flow processes, and is ideal for hydrology and environmental engineering students, as well as professionals in the hydrocarbon, water and carbon storage industries.

This book concentrates on the topic of physical and chemical equilibrium. Using the simplest mathematics along with numerous numerical examples it accurately and rigorously covers physical and chemical equilibrium in depth and detail. It continues to cover the topics found in the first edition however numerous updates have been made including: Changes in naming and notation (the first edition used the traditional names for the Gibbs Free Energy and for Partial Molal Properties, this edition uses the more popular Gibbs Energy and Partial Molar Properties, ) changes in symbols (the first edition used the Lewis-Randal fugacity rule and the popular symbol for the same quantity, this edition only uses the popular notation, ) and new problems have been added to the text. Finally the second edition includes an appendix about the Bridgman table and its use.