This is a comprehensive guide to the often confusing subject of thermodynamics, for engineers, physicists, and chemists. The succinct entries are arranged alphabetically, allowing the reader to browse through the subject and to pursue a particular point, skipping or ignoring extraneous points. After twenty years of teaching thermodynamics, Professor Perrot knows exactly which areas students find difficult and has taken particular trouble with these points. The entries explain the words and phrases that crop up in thermodynamics without recourse to pages of mathematics and algebra: the main aim being to explain and clarify the jargon and concepts. Professor Perrot achieves this aim while maintaining a refreshing lightness of prose style, in which spirit he also includes some asides on interesting people and events in the history of thermodynamics.

Most of the things around us are made up of more or less heterogenous mixtures of particles, and the paper, paint, and ink industries also use colloidal systems, either in the final product or at crucial stages in the manufacture. This book provides an introduction to the understanding of the behaviour of such systems.

Expertise in electrolyte systems has become increasingly important in traditional chemical process industry operations, as well as in oil/gas exploration and production. In particular, electrolyte systems come into play in many important applications involving the environment.
Unit recently, engineers faced with the dilemma of predicting the behavior of electrolyte or predicting the behavior of electrolyte systems had to resort to crude predictions largely based on the adaptation of methods applicable to hydrocarbons systems.
The "Handbook of Aqueous Electrolyte Thermodynamics" solves the modern engineer's dilemma by acting as a "do-it yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. Engineers confronting the task of solving industrial problems may now solve them by turning to the "Handbook" and applying the compiled available data and/or the data prediction and analysis techniques presented in this volume to the problem at hand.
Here, the engineer will find a thorough and systematic presentation of electrolyte thermodynamics, beginning with the basic definitions of the equilibrium constants used in formulating electrolyte models and ending with an exposition and comparison of several of the best formulations for the activity coefficients of strong and/or weak electrolytes. In the final chapter there is a general recipe for formulating complete predictive models for electrolytes along with a series of worked illustrative examples.
This unique handbook serves as a useful research and application tool for the practicing process engineer as well as acollege textbook for the chemical engineering student.

This book looks at how molecules react, and how the feasibility and outcome of chemical reactions can be predicted. Beginning with an introduction to the concept of an activity series of metals, Metals and Chemical Change then introduces chemical thermodynamics (enthalpy, entropy and free energy) and applies the concept to both inorganic and organic elements. A Case Study on batteries and fuel cells is also included. The accompanying CD-ROM includes video sequences of the reactions of metals with water, acid and aqueous ions, and gives the reader an opportunity to make experimental observations and predictions about chemical behaviour. A comprehensive Data Book of chemical and physical constants is included, along with a set of interactive self-assessment questions. The Molecular World series provides an integrated introduction to all branches of chemistry for both students wishing to specialise and those wishing to gain a broad understanding of chemistry and its relevance to the everyday world and to other areas of science. The books, with their Case Studies and accompanying multi-media interactive CD-ROMs, will also provide valuable resource material for teachers and lecturers. (The CD-ROMs are designed for use on a PC running Windows 95, 98, ME or 2000.)

This book delves into the rapidly changing area of combustion, in which asymptotic methods and bifurcation theory have made a significant impact as have the constant-density, small-heat-release models and other important contributions.

This textbook introduces thermodynamics with a modern approach, starting from four fundamental physical facts (the atomic nature of matter, the indistinguishability of atoms and molecules of the same species, the uncertainty principle, and the existence of equilibrium states) and analyzing the behavior of complex systems with the tools of information theory, in particular with Shannon's measure of information (or SMI), which can be defined on any probability distribution. SMI is defined and its properties and time evolution are illustrated, and it is shown that the entropy is a particular type of SMI, i.e. the SMI related to the phase-space distribution for a macroscopic system at equilibrium. The connection to SMI allows the reader to understand what entropy is and why isolated systems follow the Second Law of Thermodynamics. The Second Llaw is also formulated for other systems, not thermally isolated and even open with respect to the transfer of particles. All the fundamental aspects of thermodynamics are derived and illustrated with several examples in the first part of the book. The second part addresses important applications of thermodynamics, covering phase transitions, mixtures and solutions (including the Kirkwood-Buff approach and solvation thermodynamics), chemical equilibrium, and the outstanding properties of water.This textbook is unique in two aspects. First, thermodynamics is introduced with a novel approach, based on information theory applied to macroscopic systems at equilibrium. It is shown that entropy is a particular case of Shannon's measure of information (SMI), and the properties and time evolution of the SMI are used to explain the Second Law of Thermodynamics. This represents a real breakthrough, as classical thermodynamics cannot explain entropy, nor clarify why systems should obey the Second Law. Second, this textbook offers the reader the possibility to get in touch with important and advanced applications of thermodynamics, to address the topics discussed in the second part of the book. Although they may go beyond the content of a typical introductory course on thermodynamics, some of them can be important in the curriculum chosen by the student. At the same time, they are of appealing interest to more advanced scholars.

This widely acclaimed text, now in its sixth edition and translated into many languages, continues to present a clear, simple and concise introduction to chemical thermodynamics. An examination of equilibrium in the everyday world of mechanical objects provides a starting point for an accessible account of the factors that determine equilibrium in chemical systems. This straightforward approach leads students to a thorough understanding of the basic principles of thermodynamics, which are then applied to a wide range of physical chemical systems. The book also discusses the problems of non-ideal solutions and the concept of activity, and provides an introduction to the molecular basis of thermodynamics. Over six editions, the views of teachers of the subject and their students have been incorporated. Reference to the phase rule has been included in this edition and the notation has been revised to conform to current IUPAC recommendations. Students taking courses in thermodynamics will continue to find this popular book an excellent introductory text.

Thermodynamics is fundamental to university and college curricula in chemistry, physics, engineering and many life sciences around the world. It is also notoriously difficult for students to understand, learn and apply. What makes this book different, and special, is the clarity of the text. The writing style is fluid, natural and lucid, and everything is explained in a logical and transparent manner. Thermodynamics is a deep, and important, branch of science, and this book does not make it "easy". But it does make it intelligible. This book introduces a new, 'Fourth Law' of Thermodynamics' based on the notion of Gibbs free energy, which underpins almost every application of thermodynamics and which the authors claim is worthy of recognition as a 'law'. The last four chapters bring thermodynamics into the twenty-first century, dealing with bioenergetics (how living systems capture and use free energy), macromolecule assembly (how proteins fold), and macromolecular aggregation (how, for example, virus capsids assemble). This is of great current relevance to students of biochemistry, biochemical engineering and pharmacy, and is covered in very few other texts on thermodynamics. The book also contains many novel and effective examples, such as the explanation of why friction is irreversible, the proof of the depression of the freezing point, and the explanation of the biochemical standard state.

The renowned Oxford Chemistry Primers series, which provides focused introductions to a range of important topics in chemistry, has been refreshed and updated to suit the needs of today's students, lecturers, and postgraduate researchers. The rigorous, yet accessible, treatment of each subject area is ideal for those wanting a primer in a given topic to prepare them for more advanced study or research. The learning features provided, including end of book problems and online multiple-choice questions, encourage active learning and promote understanding. Furthermore, frequent diagrams and margin notes help to enhance a student's understanding of these essential areas of chemistry. Statistical Thermodynamics gives a concise and accessible account of this fundamental topic by emphasizing the underlying physical chemistry, and using this to introduce the mathematics in an approachable way. The material is presented in short, self-contained sections making it flexible to teach and learn from, and concludes with the application of the theory to real systems. Online Resource Centre: The Online Resource Centre to accompany Statistical Thermodynamics features: For registered adopters of the text: * Figures from the book available to download For students: * Worked solutions to the questions and problems at the end of the book. * Multiple-choice questions for self-directed learning

Distillation is a major separation technique practised in the food, chemical, pharmaceutical, petrochemical, petroleum refining, gas and alcohol industries. Because of its low cost and high potential for better thermodynamic efficiency, it is likely to remain the most common method of separation in these industries. This book is a companion volume to Distillation Operation, and it aims to continue the updated account of this evolving separation process. It loooks at process and equipment design procedures, practical limitations and solutions to typical problems. Each chapter ends with sections on nomenclature and references.

This book contains the latest information on all aspects of the most important chemical thermodynamic properties of Gibbs energy and Helmholtz energy, as related to fluids. Both the Gibbs energy and Helmholtz energy are very important in the fields of thermodynamics and material properties as many other properties are obtained from the temperature or pressure dependence. Bringing all the information into one authoritative survey, the book is written by acknowledged world experts in their respective fields. Each of the chapters will cover theory, experimental methods and techniques and results for all types of liquids and vapours. This book is the fourth in the series of Thermodynamic Properties related to liquids, solutions and vapours, edited by Emmerich Wilhelm and Trevor Letcher. The previous books were: Heat Capacities (2010), Volume Properties (2015), and Enthalpy (2017). This book fills the gap in fundamental thermodynamic properties and is the last in the series.

This pioneering graduate textbook provides readers with the concepts and practical tools required to understand the maximum entropy principle, and apply it to an understanding of ecological patterns. Rather than building and combining mechanistic models of ecosystems, the approach is grounded in information theory and the logic of inference. Paralleling the derivation of thermodynamics from the maximum entropy principle, the state variable theory of ecology developed in this book predicts realistic forms for all metrics of ecology that describe patterns in the distribution, abundance, and energetics of species over multiple spatial scales, a wide range of habitats, and diverse taxonomic groups.
The first part of the book is foundational, discussing the nature of theory, the relationship of ecology to other sciences, and the concept of the logic of inference. Subsequent sections present the fundamentals of macroecology and of maximum information entropy, starting from first principles. The core of the book integrates these fundamental principles, leading to the derivation and testing of the predictions of the maximum entropy theory of ecology (METE). A final section broadens the book's perspective by showing how METE can help clarify several major issues in conservation biology, placing it in context with other theories and highlighting avenues for future research.

This pioneering graduate textbook provides readers with the concepts and practical tools required to understand the maximum entropy principle, and apply it to an understanding of ecological patterns. Rather than building and combining mechanistic models of ecosystems, the approach is grounded in information theory and the logic of inference. Paralleling the derivation of thermodynamics from the maximum entropy principle, the state variable theory of ecology developed in this book predicts realistic forms for all metrics of ecology that describe patterns in the distribution, abundance, and energetics of species over multiple spatial scales, a wide range of habitats, and diverse taxonomic groups.
The first part of the book is foundational, discussing the nature of theory, the relationship of ecology to other sciences, and the concept of the logic of inference. Subsequent sections present the fundamentals of macroecology and of maximum information entropy, starting from first principles. The core of the book integrates these fundamental principles, leading to the derivation and testing of the predictions of the maximum entropy theory of ecology (METE). A final section broadens the book's perspective by showing how METE can help clarify several major issues in conservation biology, placing it in context with other theories and highlighting avenues for future research.

Introducing Biological Energetics is a novel, interdisciplinary text that presents biological understanding in terms of general underlying principles, treating energy as the overarching theme and emphasizing the all-pervading influence of energy transformation in every process, both living and non-living. Key processes and concepts are explained in turn, culminating in a description of the overall functioning and regulation of a living cell. The book rounds off the story of life with a brief account of the endosymbiotic origins of eukaryotic cells, the development of multicellularity, and the emergence of modern plants and animals.
Multidisciplinary research in science is becoming commonplace. However, as traditional boundaries start to break down, researchers are increasingly aware of the deficiencies in their knowledge of related disciplines. Introducing Biological Energetics redresses the reciprocal imbalance in the knowledge levels of physical and biological scientists in particular. Its style of presentation and depth of treatment has been carefully designed to unite these two readerships.

An understanding of nonstationary gas flows (and liquids under high pressure) is of critical importance to engineers studying phenomena such as shock waves arising from an explosion of energy in a limited space, the behavior of media through which the shock propagate, and the nonstationary motion of a mixture of gases in energy-producing devices and engines. In this authoritative and well-written book, the reader will find comprehensive treatments of all important aspects of shock-tube and shock-wave research in pure and dusty gases, as well as of dissociated and ionized boundary layers, spherical and cylindrical explosion and implosion phenomena, hypervelocity launchers, and shock-wave reflections, diffractions, and refractions. Unique in its deft combination of analytical, numerical, and experimental work, the book expertly covers 40 years of continuous research in the area. It will be sought after by mechanical engineering students and researchers interested in explosion and blast wave phenomena.

This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been paid to the rigor of mathematical developments. This sixth volume is made up of two parts. The first part focuses on the study of ionic equilibria in water or non-aqueous solvents. The following are then discussed in succession: the dissociation of electrolytes, solvents and solvation, acid-base equilibria, formation of complexes, redox equilibria and the problems of precipitation. Part 2 discusses electrochemical thermodynamics, with the study of two groups: electrodes and electrochemical cells. The book concludes with the study of potential-pH diagrams and their generalization in an aqueous or non-aqueous medium.

The renowned Oxford Chemistry Primers series, which provides focused introductions to a range of important topics in chemistry, has been refreshed and updated to suit the needs of today's students, lecturers, and postgraduate researchers. The rigorous, yet accessible, treatment of each subject area is ideal for those wanting a primer in a given topic to prepare them for more advanced study or research. Moreover, cutting-edge examples and applications throughout the texts show the relevance of the chemistry being described to current research and industry. This new edition of Thermodynamics of Chemical Processes is the only self-contained text to cover the thermodynamics of chemical processes at a level appropriate for undergraduates. Describing the basic principles which govern reactivity and phase equilibria in chemical systems, the text is written at the first year undergraduate level and contains a number of worked examples and problems to help students through this introductory material. It shows the application of the theory to disciplines such as biochemistry, materials science, environmental science, forensic and analytical sciences. This new edition places an emphasis on applying the principles and solving problems rather than on formal proof of theorems and detailed mathematical understanding. The ideas of enthalpy, internal energy and entropy are covered to lead into Gibbs free energy and how it can be used to correlate and predict the equilibrium position and properties of chemical reactions and multi-phase systems. Background mathematical ideas are introduced as needed, and the text includes material describing how the physicochemical principles can be applied to related areas such as materials science or biochemistry.

Containing the very latest information on all aspects of enthalpy and internal energy as related to fluids, this book brings all the information into one authoritative survey in this well-defined field of chemical thermodynamics. Written by acknowledged experts in their respective fields, each of the 26 chapters covers theory, experimental methods and techniques and results for all types of liquids and vapours. These properties are important in all branches of pure and applied thermodynamics and this vital source is an important contribution to the subject hopefully also providing key pointers for cross-fertilization between sub-areas.

In this text the authors present current research in the study of different types of reactions, fundamental processes and advanced technologies of combustion. The topics discussed in this compilation include the Lagrangian formulation to treating the turbulent reacting flows; g-equation in white-noise in time turbulent velocity field; deposition of thin functional coatings at atmospheric pressure using combustion chemical vapour deposition; fundamentals of oxy-fuel carbon capture technology for pulverised fuel boilers; combustion of lignocellulosic biomass and marine biomass by means of thermal analyses; methane combustion by electrochemical promotion of catalysis phenomenon; novel nitrate-free acetate-H2O2 combustion synthesis; and solution combustion method.

Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs.

"Phase Equilibrium Engineering" presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions.

The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering.

Methodologies are discussed using relevant industrial examples

The molecular nature and composition of the process mixture is given a key role in process decisions

Phase equilibrium diagrams are used as a drawing board for process implementation

This book offers a comprehensive exploration of geochemical kinetics--the application of chemical kinetics to geological problems, both theoretical and practical. "Geochemical Kinetics" balances the basic theories of chemical kinetics with a thorough examination of advanced theories developed by geochemists, such as nonisothermal kinetics and inverse theories, including geochronology (isotopic dating), thermochronology (temperature-time history), and geospeedometry (cooling rates). The first chapter provides an introduction and overview of the whole field at an elementary level, and the subsequent chapters develop theories and applications for homogeneous reactions, mass and heat transfer, heterogeneous reactions, and inverse problems.

Most of the book's examples are from high-temperature geochemistry, with a few from astronomy and environmental sciences. Appendixes, homework problems for each major section, and a lengthy reference list are also provided. Readers should have knowledge of basic differential equations, some linear algebra, and thermodynamics at the level of an undergraduate physical chemistry course. "Geochemical Kinetics" is a valuable resource for anyone interested in the mathematical treatment of geochemical questions.

John Wiley & Sons, Inc. is proud to announce an important new series of textbooks -- The MIT Series in Materials Science and Engineering. In response to the growing economic and technological importance of polymers, ceramics, and semi-conductors, many materials science and engineering departments are changing and expanding their curricula. The advent of new courses calls for the development of new textbooks that teach the principles of materials science and engineering as they apply to all the classes of materials. The MIT Series in Materials Science and Engineering is designed to fill the needs of this changing curriculum. Based on the undergraduate curriculum of the MIT Department of Materials Science and Engineering, the series will include textbooks for the core courses in the field as well as texts for courses in specific material classes. The first three textbooks in the series will be: Thermodynamics of Materials, Vol. I, by David Ragone (0-471-30885-4) Thermodynamics of Materials, VoL. II, by David Ragone (0-471-30886-2) Physical Ceramics: Principles for Ceramics Science and Engineering, by Yet-Ming Chiang, Dunbar Birnie III, and W. David Kingery (0-471-59873-9)

The fundamental principles of classic thermodynamics as they apply in science and engineering are illustrated here in numerous, fully worked out examples. Equally valuable at undergraduate and first-year graduate levels, this powerful study tool takes students from fundamental laws to the behavior of PVT systems, to the treatment of flow processes, the basics of chemical thermodynamics and more. Hundreds of review problems with answers speed comprehension and reinforce learning.

Comprising two volumes this work provides a particularly comprehensive account of the development of kinetic theory and statistical mechanics up to the beginning of the 20th century. The author's historical researches go far beyond any other books on the subject, filling in many more details and putting the history of kinetic theory in the context of 19th century scientific and intellectual history. In the course of detailed examination of the sources, both published and unpublished, the author throws much new light on the dynamics of scientific change, and refutes some generally accepted ideas about historical events. In one section of the work, he demonstrates the use of a kind of historical document which has rarely, if ever, been exploited by historians of science, namely, referees' reports. The work is primarily directed towards physicists, but as it is not only concerned with technical aspects of the history of physics but also deals with cultural and philosophical connections, it will also appeal to historians of science and philosophers. Book 2 is completed by an unusually comprehensive bibliography.

An introduction to far-reaching developments in theoretical combustion, with special emphasis on flame stability, a topic that has, to date, benefited most from the application of modern asymptotic methods. The authors provide a modern view of flame theory, and a complete description of the longstanding ignition and explosion problems, including the solutions that were made available independently by Kapila and Kassoy through activation-energy asymptotics, the main theme of this monograph.