Comprising two volumes this work provides a particularly comprehensive account of the development of kinetic theory and statistical mechanics up to the beginning of the 20th century. The author's historical researches go far beyond any other books on the subject, filling in many more details and putting the history of kinetic theory in the context of 19th century scientific and intellectual history. In the course of detailed examination of the sources, both published and unpublished, the author throws much new light on the dynamics of scientific change, and refutes some generally accepted ideas about historical events. In one section of the work, he demonstrates the use of a kind of historical document which has rarely, if ever, been exploited by historians of science, namely, referees' reports. The work is primarily directed towards physicists, but as it is not only concerned with technical aspects of the history of physics but also deals with cultural and philosophical connections, it will also appeal to historians of science and philosophers. Book 2 is completed by an unusually comprehensive bibliography.

This groundbreaking book contains a broad yet detailed coverage of the major aspects of fire engineering. As would be expected, such matters as fire extinguishers, flame-retardants and fire-fighting feature centrally, with descriptions, from the functional point of view, of fire appliances from selected manufacturers around the world. There is coverage of selected accidental fires, both recent ones and those which have been on record for many years as being amongst the most serious in terms of loss of life. Social and political aspects of fire engineering also feature in the book, for example in accounts of fires in countries where buildings are sub-standard in safety terms and fire services are unreliable. Fire safety products are an integral part of the subject and improvements in fire safety have to a considerable degree been due to development work by manufacturers and trade names therefore feature in the book where applicable. Scientific and engineering details of the products have been obtained and re-expressed in broad terms. The author has paid close attention to the underlying physics and chemistry and some of the topics are complemented by calculations.

Following elucidation of the basics of thermodynamics and detailed explanation of chemical kinetics of reactive mixtures, readers are introduced to unique and effective mathematical tools for the modeling, simulation and analysis of chemical non-equilibrium phenomena in combustion and flows. The reactor approach is presented considering thermochemical reactors as the focal points. Novel equations of chemical kinetics compiling chemical thermodynamic and transport processes make reactor models universal and easily applicable to the simulation of combustion and flow in a variety of propulsion and energy generation units. Readers will find balanced coverage of both fundamental material on chemical kinetics and thermodynamics, and detailed description of mathematical models and algorithms, along with examples of their application. Researchers, practitioners, lecturers, and graduate students will all find this work valuable.

This book offers a comprehensive exploration of geochemical kinetics--the application of chemical kinetics to geological problems, both theoretical and practical. "Geochemical Kinetics" balances the basic theories of chemical kinetics with a thorough examination of advanced theories developed by geochemists, such as nonisothermal kinetics and inverse theories, including geochronology (isotopic dating), thermochronology (temperature-time history), and geospeedometry (cooling rates). The first chapter provides an introduction and overview of the whole field at an elementary level, and the subsequent chapters develop theories and applications for homogeneous reactions, mass and heat transfer, heterogeneous reactions, and inverse problems.

Most of the book's examples are from high-temperature geochemistry, with a few from astronomy and environmental sciences. Appendixes, homework problems for each major section, and a lengthy reference list are also provided. Readers should have knowledge of basic differential equations, some linear algebra, and thermodynamics at the level of an undergraduate physical chemistry course. "Geochemical Kinetics" is a valuable resource for anyone interested in the mathematical treatment of geochemical questions.

Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Huckel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications - natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.

This book concentrates on the topic of physical and chemical equilibrium. Using the simplest mathematics along with numerous numerical examples it accurately and rigorously covers physical and chemical equilibrium in depth and detail. It continues to cover the topics found in the first edition however numerous updates have been made including: Changes in naming and notation (the first edition used the traditional names for the Gibbs Free Energy and for Partial Molal Properties, this edition uses the more popular Gibbs Energy and Partial Molar Properties, ) changes in symbols (the first edition used the Lewis-Randal fugacity rule and the popular symbol for the same quantity, this edition only uses the popular notation, ) and new problems have been added to the text. Finally the second edition includes an appendix about the Bridgman table and its use.

Complexity and Complex Thermoeconomic Systems describes the properties of complexity and complex thermo-economic systems as the consequence of formulations, definitions, tools, solutions and results consistent with the best performance of a system. Applying to complex systems contemporary advanced techniques, such as static optimization, optimal control, and neural networks, this book treats the systems theory as a science of general laws for functional integrities. It also provides a platform for the discussion of various definitions of complexity, complex hierarchical structures, self-organization examples, special references, and historical issues. This book is a valuable reference for scientists, engineers and graduated students in chemical, mechanical, and environmental engineering, as well as those in physics, ecology and biology, helping them better understand the complex thermodynamic systems and enhance their technical skills in research.

Matter and Molecules: A Broader and Deeper View of Chemical Thermodynamics provides students with an interdisciplinary exploration of physical chemistry. Students learn critical concepts of physical chemistry with special emphasis on application to other areas of science. Instead of presenting a narrow, specialized view of physical and biological phenomena, the text provides a broader, global view, highlighting the problems and scenarios that must be faced and understood by chemists, biochemists, physicists, geologists, pharmacists, engineers, and others. Over the course of 11 chapters, students learn about the fundamentals of thermodynamics; molecules, statistics, and matter; partial molar properties and phase transitions; and gaseous mixtures. They read about mixtures in condensed phases and their equilibrium with vapor, solutions, surface phenomena, and chemical equilibrium. The text closes with chapters dedicated to processes with charge transfer, non-equilibrium processes, and future developments anticipated within the discipline. Worked examples are included throughout to demonstrate the application of the material presented. Matter and Molecules helps students connect the dots between key concepts in physical chemistry and their use in real-world settings. The text is an excellent resource for undergraduate and graduate courses in physical chemistry.

* Presents a solid introduction to thermal analysis, methods, instrumentation, calibration, and application along with the necessary theoretical background.* Useful to chemists, physicists, materials scientists, and engineers who are new to thermal analysis techniques, and to existing users of thermal analysis who wish expand their experience to new techniques and applications* Topics covered include Differential Scanning Calorimetry and Differential Thermal Analysis (DSC/DTA), Thermogravimetry, Thermomechanical Analysis and Dilatometry, Dynamic Mechanical Analysis, Micro-Thermal Analysis, Hot Stage Microscopy, and Instrumentation.* Written by experts in the various areas of thermal analysis* Relevant and detailed experiments and examples follow each chapter.

This book provides an introduction to the essentials of relativistic effects in quantum chemistry, and a reference work that collects all the major developments in this field. It is designed for the graduate student and the computational chemist with a good background in nonrelativistic theory. In addition to explaining the necessary theory in detail, at a level that the non-expert and the student should readily be able to follow, the book discusses the implementation of the theory and practicalities of its use in calculations. After a brief introduction to classical relativity and electromagnetism, the Dirac equation is presented, and its symmetry, atomic solutions, and interpretation are explored. Four-component molecular methods are then developed: self-consistent field theory and the use of basis sets, double-group and time-reversal symmetry, correlation methods, molecular properties, and an overview of relativistic density functional theory. The emphases in this section are on the basics of relativistic theory and how relativistic theory differs from nonrelativistic theory. Approximate methods are treated next, starting with spin separation in the Dirac equation, and proceeding to the Foldy-Wouthuysen, Douglas-Kroll, and related transformations, Breit-Pauli and direct perturbation theory, regular approximations, matrix approximations, and pseudopotential and model potential methods. For each of these approximations, one-electron operators and many-electron methods are developed, spin-free and spin-orbit operators are presented, and the calculation of electric and magnetic properties is discussed. The treatment of spin-orbit effects with correlation rounds off the presentation ofapproximate methods. The book concludes with a discussion of the qualitative changes in the picture of structure and bonding that arise from the inclusion of relativity.

This is a comprehensive guide to the often confusing subject of thermodynamics, for engineers, physicists, and chemists. The succinct entries are arranged alphabetically, allowing the reader to browse through the subject and to pursue a particular point, skipping or ignoring extraneous points. After twenty years of teaching thermodynamics, Professor Perrot knows exactly which areas students find difficult and has taken particular trouble with these points. The entries explain the words and phrases that crop up in thermodynamics without recourse to pages of mathematics and algebra: the main aim being to explain and clarify the jargon and concepts. Professor Perrot achieves this aim while maintaining a refreshing lightness of prose style, in which spirit he also includes some asides on interesting people and events in the history of thermodynamics.

The aim of this contemporary textbook is to show students that thermodynamics is a useful tool, not just a series of theoretical exercises. Written in a conversational style, the text presents the second law in a totally new manner----there is no reliance on statistical arguments; instead it is developed as a natural consequence of physical experience. Students are not required to write complex, iterative computer programs to solve phase equilibrium problems----techniques are presented which enable use of readily available math packages. The book also explores electrochemical systems such as batteries and fuel cells. Included in the extensive amount of examples are those which demonstrate the use of thermodynamics in practical design situations.

Most of the things around us are made up of more or less heterogenous mixtures of particles, and the paper, paint, and ink industries also use colloidal systems, either in the final product or at crucial stages in the manufacture. This book provides an introduction to the understanding of the behaviour of such systems.

The behavior of solid and liquid matter at high pressures and temperatures is best described in a phase diagram, which shows the regions of stability of different phases of the material. Thanks to the diamond-anvil cell, which has made possible much higher pressures, and to new and very accurate theoretical models and methods, Phase Diagrams of the Elements presents the most up-to-date information on the phase behavior of all the chemical elements from hydrogen to fermium. The book summarizes, with the aid of tables and illustrations, the experimental data and the theoretical calculations. Each element is discussed in a separate section. Other chapters deal with methods, the liquid-vapor transition, and an overview of the elements. While comprehensively reviewing all that has been done in this important area, the author also points to questions that need much more experimental and theoretical work.

An introduction to far-reaching developments in theoretical combustion, with special emphasis on flame stability, a topic that has, to date, benefited most from the application of modern asymptotic methods. The authors provide a modern view of flame theory, and a complete description of the longstanding ignition and explosion problems, including the solutions that were made available independently by Kapila and Kassoy through activation-energy asymptotics, the main theme of this monograph.

Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models.

The seventy-five refereed papers in this volume represent the second in a series of biannual benchmarks for technologies that maximize energy conversion while minimizing undesirable emissions. Covering the entire range of industrial and transport combustion as well as strategies for energy R&D, these state-of-the-art contributions will be indispensable to mechanical and chemical engineers in academia and industry, and technical personnel in military, energy, and environmental agencies of government.

Revised and expanded to reflect new developments in the field, this book outlines the basic principles required to understand the chemical processes of explosives. The Chemistry of Explosives provides an overview of the history of explosives, taking the reader to future developments. The text on the classification of explosive materials contains much data on the physical parameters of primary and secondary explosives. The explosive processes of deflagration and detonation, including the theory of 'hotspots' for the detonation process, are introduced and many examples are provided in the detailed description on the thermochemistry of explosives. New material includes coverage of the latest explosive compositions, such as high temperature explosives, nitrocubanes, energetic polymers, plasticizers and insensitive munitions (IM). This concise, readable book is ideal for 'A' level students and new graduates with no previous knowledge of explosive materials. With detailed information on a vast range of explosives in tabular form and an extensive bibliography, this book will also be useful to anyone needing succinct information on the subject.

These two volumes are concerned with current technologically important issues of transition, turbulence and combustion. Topics covered in transition include linear and nonlinear stability, direct and large-eddy simulation and phenomenological modelling of the transition zone. In turbulence, interest was focused on second-order closures and the formulation of near-wall corrections to existing high Reynolds number models, and closure model development based on turbulent flow structures and RNG theory. Topics covered in combustion include counterflow diffusion flames, development of novel mixing enhancement techniques for non-premixed combustion, and methods of modelling the interaction between turbulence and chemical kinetics. This collection of papers from leading researchers represents as yet unpublished state-of-the-art research, resulting in a very valuable tool for scientists and students working in areas of turbulence, transition and combustion.