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Books > Science & Mathematics > Chemistry > Physical chemistry > Electrochemistry & magnetochemistry
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Redox
(Hardcover)
Rozina Khattak
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R3,481
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Global economic demands and population surges have led to dwindling
resources and problematic environmental issues. As the climate and
its natural resources continue to struggle, it has become necessary
to research and employ new forms of sustainable technology to help
meet the growing demand. Sustainable Nanosystems Development,
Properties, and Applications features emergent research and
theoretical concepts in the areas of nanotechnology, photovoltaics,
electrochemistry, and materials science, as well as within the
physical and environmental sciences. Highlighting progressive
approaches and utilization techniques, this publication is a
critical reference source for researchers, engineers, students,
scientists, and academicians interested in the application of
sustainable nanotechnology.
Providing the reader with an up to date digest of the most
important current research carried out in the field, this volume is
compiled and written by leading experts from across the globe.
Touching on research areas like exploring the application of
electrochemistry in the analysis of chemicals of medical and
environmental interest using new materials such as graphene, the
development of electrochemical energy storage systems showing how
carbon dioxide can be reduced to synthetic fuels, and the
application of electrochemical sensors to sensitive and selective
determination. The reviews of established and current interest in
the field make this book a key reference for researchers in this
exciting and developing area.
The Specialist Periodical Report Electrochemistry presents
comprehensive and critical reviews in all aspects of the field,
with contributions from across the globe, providing the reader with
an informed digest of the most important research currently carried
out in this field. Re-launching in 2015 with a new editorial team,
Volume 13 returns to its roots and provides a wide range of topics
written by leading experts researching at the forefront and heart
of electrochemistry. The book covers topics such as control and
structural analysis, and combines different approaches on utilizing
light as a source for materials science. This volume is a key
reference in the field of electrochemistry, allowing readers to
become easily acquainted with the latest research trends.
"Perovskite-Based Solar Cells: From Fundamentals to Tandem Devices"
gives fundamental understanding of perovskite solar cells from the
chemical composition of each thin layer composing the different
stacks to the whole device. Special attention has been given to the
development of the materials forming the perovskite solar cell and
their effect on the device performance, in addition to the recent
progress of this emerging technology. Moreover, light has been shed
on the perovskite elaboration techniques, in addition to the
several techniques proposed to improve both the efficiency and the
stability of perovskite solar cells. Furthermore, special emphasis
was given to the three types of tandem solar cells and their recent
advances starting from Perovskite/perovskite tandem solar cells to
Perovskite/ CIGS tandem cells to perovskite/ heterojunction silicon
tandem solar cells. The latter constitute a promising solution to
improve photovoltaic solar cells performance.
This book provides the latest information and methodologies of
rotating disk electrode and rotating ring-disk electrode (RDE/RRDE)
and oxygen reduction reaction (ORR). It is an ideal reference for
undergraduate and graduate students, scientists, and engineers who
work in the areas of energy, electrochemistry science and
technology, fuel cells, and other electrochemical systems.
Presents a comprehensive description, from fundamentals to
applications, of catalyzed oxygen reduction reaction and its
mechanismsPortrays a complete description of the RDE (Rotating Disc
Electrode)/RRDE (Rotating Ring-Disc Electrode) techniques and their
use in evaluating ORR (Oxygen Reduction Reaction) catalystsProvides
working examples along with figures, tables, photos and a
comprehensive list of references to help understanding of the
principles involved
This user friendly introduction highlights the importance of
electrochemistry and its applications to the modern world and the
future. In contrast to other texts currently available, it
emphasises understanding and avoids using many pages of complex
equations. It also describes the diverse applications of
electrochemistry rather than focusing on analytical chemistry
alone. Although the book follows a similar structure to the first
edition, the earlier chapters have been extensively up-dated and
the later chapters are entirely new. The text is supported by a
large number of figures which illustrate key points. The book
starts by describing the essential electrochemical techniques
before moving on to cover experimental problems and applications.
To reflect the present interest in fuel cells and the environment,
these have become the focus of the final chapters. A useful
appendix contains problems with fully worked answers to test the
reader's understanding.
This book systematically describes the design and synthesis of
MOF-related materials and the electrochemical energy
storage-related research in the field of batteries. It starts with
an introduction to the synthesis of MOF-based materials and various
MOF derivatives, such as MOF-derived porous carbon and MOF-derived
metal nanoparticles. This is followed by highlighting the
interesting examples for electrochemical applications, illustrating
recent advances in battery, supercapacitor, and water splitting.
This book is interesting and useful to a wide readership in the
various fields of chemical science, materials science, and
engineering.
The series Topics in Current Chemistry Collections presents
critical reviews from the journal Topics in Current Chemistry
organized in topical volumes. The scope of coverage is all areas of
chemical science including the interfaces with related disciplines
such as biology, medicine and materials science. The goal of each
thematic volume is to give the non-specialist reader, whether in
academia or industry, a comprehensive insight into an area where
new research is emerging which is of interest to a larger
scientific audience.Each review within the volume critically
surveys one aspect of that topic and places it within the context
of the volume as a whole. The most significant developments of the
last 5 to 10 years are presented using selected examples to
illustrate the principles discussed. The coverage is not intended
to be an exhaustive summary of the field or include large
quantities of data, but should rather be conceptual, concentrating
on the methodological thinking that will allow the non-specialist
reader to understand the information presented. Contributions also
offer an outlook on potential future developments in the field.
This book discusses systematically the theoretical research and the
applications of electrochemical oxygen reduction. Oxygen reduction
reaction is a common issue in electrochemistry, but is also an
important process involved in the field of energy, cryogenic fuel
cells, metal-air cells, oxygen sensors and hydrogen peroxide
preparation. This book is divided into 6 chapters; it starts with a
description of dynamic mechanisms, followed by a detailed
introduction on the related experimental methods and related
catalyst preparation technology. By providing the basic methods and
testing techniques, and by demonstrating their applications, it
helps readers gain a better understanding of oxygen reduction
reactions, making it a valuable resource for the industrialization
of scientific research achievements. Accordingly, the book appeals
to a broad readership, particularly graduate students, those
working at universities and research organizations, and industrial
researchers.
Fossil fuels comprise the accumulation of prehistoric biomass that
was energised by sunlight, and formed by earth system dynamics.
Fossil fuels can be conceptualized as stored energy stocks that can
be readily converted to power flows, on demand. A transition from a
reliance on stored energy stocks, to renewable energy flows, will
require a replication of energy storage by technological devices
and energy conversion methods. Most analyses of energy storage
focus solely on the economic-technical properties of storage within
incumbent energy systems. This book broadens the scope of the study
of storage by placing it within a broader, historical, biophysical
framework. The role and value of storage is examined from first
principles, and framed within the contemporary context of
electrical grids and markets. The energy-economic cost of
electrical storage may be critical to the efficacy of high
penetration renewable scenarios, and understanding the costs and
benefits of storage is needed for a proper assessment of storage in
energy transition studies. This book provides a starting point for
engineers, scientists and energy analysts for exploring the role of
storage in energy transition studies, and for gaining an
appreciation of the biophysical constraints of storage.
This is the first machine-generated scientific book in chemistry
published by Springer Nature. Serving as an innovative prototype
defining the current status of the technology, it also provides an
overview about the latest trends of lithium-ion batteries research.
This book explores future ways of informing researchers and
professionals. State-of-the-art computer algorithms were applied
to: select relevant sources from Springer Nature publications,
arrange these in a topical order, and provide succinct summaries of
these articles. The result is a cross-corpora auto-summarization of
current texts, organized by means of a similarity-based clustering
routine in coherent chapters and sections. This book summarizes
more than 150 research articles published from 2016 to 2018 and
provides an informative and concise overview of recent research
into anode and cathode materials as well as further aspects such as
separators, polymer electrolytes, thermal behavior and modelling.
With this prototype, Springer Nature has begun an innovative
journey to explore the field of machine-generated content and to
find answers to the manifold questions on this fascinating topic.
Therefore it was intentionally decided not to manually polish or
copy-edit any of the texts so as to highlight the current status
and remaining boundaries of machine-generated content. Our goal is
to initiate a broad discussion, together with the research
community and domain experts, about the future opportunities,
challenges and limitations of this technology.
This book deals with the electro-chemo-mechanical properties
characteristic of and unique to solid electrode surfaces, covering
interfacial electrochemistry and surface science. Electrochemical
reactions such as electro-sorption, electro-deposition or film
growth on a solid electrode induce changes in surface stress or
film stress that lead to transformation of the surface phase or
alteration of the surface film. The properties of solid electrode
surfaces associated with the correlation between electrochemical
and mechanical phenomena are named "electro-chemo-mechanical
properties". The book first derives the surface thermodynamics of
solid electrodes as fundamentals for understanding the
electro-chemo-mechanical properties. It also explains the powerful
techniques for investigating the electro-chemo-mechanical
properties, and reviews the arguments for derivation of surface
thermodynamics of solid electrodes. Further, based on current
experimental findings and theories, it discusses the importance of
the contribution of surface stress to the transformation of surface
phases, such as surface reconstruction and underpotential
deposition in addition to the stress evolution during film growth
and film reduction. Moreover, the book describes the
nano-mechanical properties of solid surfaces measured by
nano-indentation in relation to the electro-chemo-mechanical
properties. This book makes a significant contribution to the
further development of numerous fields, including electrocatalysis,
materials science and corrosion science.
In this book, the development of next-generation batteries is
introduced. Included are reports of investigations to realize high
energy density batteries: Li-air, Li-sulfur, and all solid-state
and metal anode (Mg, Al, Zn) batteries. Sulfide and oxide solid
electrolytes are also reviewed.A number of relevant aspects of all
solid-state batteries with a carbon anode or Li-metal anode are
discussed and described: The formation of the cathode; the
interface between the cathode (anode) and electrolyte; the
discharge and charge mechanisms of the Li-air battery; the
electrolyte system for the Li-air battery; and cell construction.
The Li-sulfur battery involves a critical problem, namely, the
dissolution of intermediates of sulfur during the discharge
process. Here, new electrolyte systems for the suppression of
intermediate dissolution are discussed. Li-metal batteries with
liquid electrolytes also present a significant problem: the
dendrite formation of lithium. New separators and electrolytes are
introduced to improve the safety and rechargeability of the
Li-metal anode. Mg, Al, and Zn metal anodes have been also applied
to rechargeable batteries, and in this book, new metal anode
batteries are introduced as the generation-after-next
batteries.This volume is a summary of ALCA-SPRING projects, which
constitute the most extensive research for next-generation
batteries in Japan. The work presented in this book is highly
informative and useful not only for battery researchers but also
for researchers in the fields of electric vehicles and energy
storage.
This book includes selected, peer-reviewed contributions from the
2018 International Conference on "Physics and Mechanics of New
Materials and Their Applications", PHENMA 2018, held in Busan,
South Korea, 9-11 August 2018. Focusing on manufacturing
techniques, physics, mechanics, and applications of modern
materials with special properties, it covers a broad spectrum of
nanomaterials and structures, ferroelectrics and ferromagnetics,
and other advanced materials and composites. The authors discuss
approaches and methods in nanotechnology; newly developed,
environmentally friendly piezoelectric techniques; and physical and
mechanical studies of the microstructural and other properties of
materials. Further, the book presents a range of original
theoretical, experimental and computational methods and their
application in the solution of various technological, mechanical
and physical problems. Moreover, it highlights modern devices
demonstrating high accuracy, longevity and the ability to operate
over wide temperature and pressure ranges or in aggressive media.
The developed devices show improved characteristics due to the use
of advanced materials and composites, opening new horizons in the
investigation of a variety of physical and mechanical processes and
phenomena.
This book presents the design and development of an Internet of
Things (IoT) enabled, smart sensor to detect nitrate contamination
in natural water. It considers three different sensors designed,
fabricated and configured for nitrate detection: a Graphite/PDMS
and Si-based MEMS sensors, and aFR4-based sensor. It also
introduces a selective polymer material developed by means of the
ion imprinting polymerization technique that was used as a coating
on the Si-based MEMS sensor. Further, the book discusses the
development of a smart sensing system that can be used to remotely
monitor the nitrate concentration in any water. Fully explaining
all the techniques used, the book is of interest to engineers,
researchers and scientists working in the field of the
water-quality measurement.
This book provides a brief research source for optical fiber
sensors for energy production and storage systems, discussing
fundamental aspects as well as cutting-edge trends in sensing. This
volume provides industry professionals, researchers and students
with the most updated review on technologies and current trends,
thus helping them identify technology gaps, develop new materials
and novel designs that lead to commercially viable energy storage
systems.
This book introduces readers to the fundamental physics and
chemistry of the proton exchange membrane fuel cell (PEMFC),
followed by discussions on recent advances in low platinum
electrocatalysis and related catalyst development for PEMFC (the
book's primary focus), methods of membrane electrode assembly (MEA)
fabrication for low platinum catalysts, and durability issues in
connection with MEA. While energy and environmental issues are
becoming the two main subjects in global sustainable development,
the proton exchange membrane fuel cell (PEMFC), a clean and
efficient new energy technology, has attracted more and more
attention in recent years The major hurdle for more extensive
applications of the PEMFC, especially for the automotive sector, is
the high platinum loading requirement. Readers will gain a
comprehensive understanding of the fundamentals and methods of low
platinum PEMFC. This book is intended for researchers, engineers
and graduate students in the fields of new energy technology, the
fuel cell vehicle industry and fuel cell design.
This book provides a comprehensive review of functional
nanomaterials for electrochemical applications, presenting
interesting examples of nanomaterials with different dimensions and
their applications in electrochemical energy storage. It also
discusses the synthesis of functional nanomaterials, including
quantum dots; one-dimensional, two-dimensional and
three-dimensional nanostructures; and advanced nanocomposites.
Highlighting recent advances in current electrochemical energy
storage hotpots: lithium batteries, lithium-ion batteries,
sodium-ion batteries, other metal-ion batteries, halogen ion
batteries, and metal-gas batteries, this book will appeal to
readers in the various fields of chemistry, material science and
engineering.
This monograph covers the most relevant applications of
chemometrics in electrochemistry with special emphasis on
electroanalytical chemistry. It reviews the use of chemometric
methods for exploratory data analysis, experimental design and
optimization, calibration, model identification, and experts
systems. The book also provides a brief introduction to the
fundamentals of the main chemometric methods and offers examples of
data treatment for calibration and model identification. Due to the
comprehensive coverage, this book offers an invaluable resource for
graduate and postgraduate students, as well as for researchers in
academic and industrial laboratories working in the area of
electroanalysis and electrochemical sensors.
The series Topics in Current Chemistry Collections presents
critical reviews from the journal Topics in Current Chemistry
organized in topical volumes. The scope of coverage is all areas of
chemical science including the interfaces with related disciplines
such as biology, medicine and materials science. The goal of each
thematic volume is to give the non-specialist reader, whether in
academia or industry, a comprehensive insight into an area where
new research is emerging which is of interest to a larger
scientific audience. Each review within the volume critically
surveys one aspect of that topic and places it within the context
of the volume as a whole. The most significant developments of the
last 5 to 10 years are presented using selected examples to
illustrate the principles discussed. The coverage is not intended
to be an exhaustive summary of the field or include large
quantities of data, but should rather be conceptual, concentrating
on the methodological thinking that will allow the non-specialist
reader to understand the information presented. Contributions also
offer an outlook on potential future developments in the field. The
chapters "Assessment of Simple Models for Molecular Simulation of
Ethylene Carbonate and Propylene Carbonate as Solvents for
Electrolyte Solutions" and "Elucidating Solvation Structures for
Rational Design of Multivalent Electrolytes-A Review" are available
open access under a CC BY 4.0 License via link.springer.com.
This book provides detailed information on the electrochemistry of
technetium compounds. After a brief physico-chemical
characterization of this element, it presents the comparative
chemistry of technetium, manganese and rhenium. Particular
attention is paid to the stability, disproportionation,
comproportionation, hydrolysis and polymerization reactions of
technetium ions and their influence on the observed redox systems.
The electrochemical properties of both inorganic as well as organic
technetium species in aqueous and non-aqueous solutions are also
discussed. The respective chapters cover the whole spectrum of
topics related to the application of technetium in nuclear
medicine, electrochemistry of technetium in spent nuclear fuel
(including corrosion properties of technetium alloys), and
detecting trace amounts of technetium with the aid of
electrochemical methods. Providing readers with information not
easily obtained in any other single source, the book will appeal to
researchers working in nuclear chemistry, nuclear medicine or the
nuclear industry.
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