Based on a university course, this book provides an exposition of a large spectrum of geological, geochemical and geophysical problems that are amenable to thermodynamic analysis. It also includes selected problems in planetary sciences, relationships between thermodynamics and microscopic properties, particle size effects, methods of approximation of thermodynamic properties of minerals, and some kinetic ramifications of entropy production. The textbook will enable graduate students and researchers alike to develop an appreciation of the fundamental principles of thermodynamics, and their wide ranging applications to natural processes and systems.

The IUTAM Symposium on "Combustion in Supersonic Flows" was held in Poitiers at Ecole Nationale Superieure de Mecanique et d'Aerotechnique (ENSMA) from 2 to 6 october 1995. The Symposium was hosted by the Laboratoire de Combustion et de Detonique (UPR - CNRS 9028) and was attended by 60 delegates from 10 countries. The formal presentations and invited lectures were focused on four main topics, related to combustion in supersonic streams and practical issues relative to the development of new propulsion system: fundamental studies on premixed and unpremixed combustion, fluid dynamic aspects of supersonic combustion, practical system including Scramjet, Ramaccelerators and Pulsed Detonation Engines, application of detonation to propulsion. Invited lectures presenting the state of the art on these topics as well as available data base were delivered by professors Paul A. Libby from University of California at San Diego, Vladimir Sabel'nikov from TsAGI (Russia), Paul Clavin from IRPHE (Marseille, France) and Drs Shmuel Eidelman from SAlC (USA), Gunter Smeets from the French-German Institut of Saint-Louis and Bruno Deshaies from LCD (poi tiers, France).

Volume 41 of the prominent series Modern Aspects of Electrochemistry covers a range of topics in Electrochemistry and Electrochemical Engineering. The topics include the second chapter on the survey of experimental techniques and devices of solid state electrochemistry begun by Professor Joachim Maier in Volume 39. Chapter two contains a review of synthesis and characterization of nanoporous carbons and their electrochemical applications. The next chapter reviews and discusses the use of graphs in the study of chemical reaction network. The book also reviews and discusses mathematical models of three dimensional electrode structures.

This important review series began in 1954 at Academic Press. The latest volume deals with scanning tunneling microscopy, the nickel oxide electrode, radioactive labeling as an in situ method of characterization of solid/liquid interfaces, metallic glasses, reaction kinetics and mechanisms, and DC r

Lithium-Ion Battery Chemistries: A Primer offers a simple description on how different lithium-ion battery chemistries work, along with their differences. It includes a refresher on the basics of electrochemistry and thermodynamics, and an understanding of the fundamental processes that occur in the lithium-ion battery. Furthermore, it reviews each of the major chemistries that are in use today, including Lithium-Iron Phosphate (LFP), Lithium-Cobalt Oxide (LCO), Lithium Manganese Oxide (LMO), Lithium-Nickel Manganese Cobalt (NMC), Lithium-Nickel Cobalt Aluminium (NCA), and Lithium-Titanate Oxide (LTO) and outlines the different types of anodes, including carbon (graphite, hard carbon, soft carbon, graphene), silicon, and tin. In addition, the book offers performance comparisons of different chemistries to help users select the right battery for the right application and provides explanations on why different chemistries have different performances and capabilities. Finally, it offers a brief look at emerging and beyond-lithium chemistries, including lithium-air, zinc-air, aluminum air, solid-state, lithium-sulfur, lithium-glass, and lithium-metal.

This thesis introduces the preparation of a series of Mg-based thin films with different structures using magnetron sputtering, as well as the systematical investigation of their gaseous and electrochemical hydrogen storage properties under mild conditions. It reviews promising applications of Mg-based thin films in smart windows, hydrogen sensors and Ni-MH batteries, while also providing significant insights into research conducted on Mg-based hydrogen storage materials, especially the Mg-based films. Moreover, the unique experimental procedures and methods (including electric resistance, optical transmittance and electrochemical methods) used in this thesis will serve as a valuable reference for researchers in the field of Mg-based hydrogen storage films.

This book presents a collection of chapters on modern bioelectrochemistry, showing different aspects of emerging techniques and materials, biodevice design and reactions. The chapters provide relevant bibliographic information for researchers and students interested in electrochemical impedance spectroscopy applied in biodevices, trends, and validation on impedimetric immunosensors in the application of routine analysis, electrochemical-surface plasmon bioanalytics and carbon nanomaterials in electrochemical biodevices, insights on inorganic complexes and metal based for biomarkers sensors, bioelectrodes and cascade reactions and field effect-based reactions.

This book is devoted to CO2 capture and utilization (CCU) from a green, biotechnological and economic perspective, and presents the potential of, and the bottlenecks and breakthroughs in converting a stable molecule such as CO2 into specialty chemicals and materials or energy-rich compounds. The use of renewable energy (solar, wind, geothermal, hydro) and non-fossil hydrogen is a must for converting large volumes of CO2 into energy products, and as such, the authors explore and compare the availability of hydrogen from water using these sources with that using oil or methane. Divided into 13 chapters, the book offers an analysis of the conditions under which CO2 utilization is possible, and discusses CO2 capture from concentrated sources and the atmosphere. It also analyzes the technological (non-chemical) uses of CO2, carbonation of basic minerals and industrial sludge, and the microbial-catalytic-electrochemical-photoelectrochemical-plasma conversion of CO2 into chemicals and energy products. Further, the book provides examples of advanced bioelectrochemical syntheses and RuBisCO engineering, as well as a techno-energetic and economic analysis of CCU. Written by leading international experts, this book offers a unique perspective on the potential of the various technologies discussed, and a vision for a sustainable future. Intended for graduates with a good understanding of chemistry, catalysis, biotechnology, electrochemistry and photochemistry, it particularly appeals to researchers (in academia and industry) and university teachers.

This book combines two areas of intense interest: nanotechnology, and energy conversion and storage devices. In particular, Li-ion batteries have enjoyed conspicuous success in many consumer electronic devices and their projected use in vehicles that will revolutionize the way we travel in the near future. For many applications, Li-ion batteries are the battery of choice. This book consolidates the scattered developments in all areas of research related to nanotechnology and lithium ion batteries.

Tailored Thin Coatings for Corrosion Inhibition Using a Molecular Approach discusses the fundamentals and applications of various thin coatings for the inhibition of fouling and corrosion from a molecular perspective. It provides the reader with a fundamental understanding of why certain coatings perform better than others in a given environment. Surface analytical and electrochemical techniques in understanding the coating performance are emphasized throughout the book, providing readers with a useful reference on how to pursue a systematic corrosion inhibitor R&D program that involves the testing of coating performance using various, currently available, state-of-the-art laboratory techniques. Wherever relevant, environmental considerations of the discussed coatings' technologies are highlighted and discussed, with current and upcoming regulatory trends put forth by different governmental organizations.

This book covers the various advanced manufacturing processes employed by manufacturing industries to improve their productivity in terms of socio-economic development. The authors present automated conventional and non-conventional machining techniques as well as virtual machining principles and techniques. Material removal by mechanical, chemical, thermal and electrochemical processes are described in detail. A glossary of key concepts is attached at end of the book.

Amperometric sensors, biosensors included, particularly rely on suitable electrode materials. Progress in material science has led to a wide variety of options that are available today. For the first time, these novel functional electrode coating materials are reviewed in this monograph, written by and for electroanalytical chemists. This includes intrinsically conducting, redox and ion-exchange polymers, metal and carbon nanostructures, silica based materials. Monolayers and relatively thick films are considered. The authors critically discuss preparation methods, in addition to chemical and physical characteristics of these new materials. They present various examples of emerging applications in electroanalysis. Due to its comprehensive coverage, the book will become an indispensable source for researchers working on the development and even proper use of new amperometric sensor systems.

This book introduces the recent development in Japan of diamond electrodes, which has attracted much attention in the world. For example, electrochemical sensors using diamond electrodes are now being utilized commercially. Newly developing applications such as electrochemical organic synthesis including CO2 reduction are also expected to form an important future technology. Those emerging applications to various fields which are receiving increasing attention are described in detail here. This book is useful not only for students who would like to begin their study of diamond electrodes but also for industries that are exploring novel electrochemical applications.

This thesis outlines the investigation of various electrode materials for Li-ion battery (LIB) applications. Li-ion batteries are widely used in various portable electronic devices owing to their compactness, light weight, longer life, design flexibility and environment friendliness. This work describes the detailed synthesis and structural studies of various novel phosphate based cathode materials and reduced graphene oxide (rGO) composites as anode materials. Their electrochemical characterization as electrode for LIBs has been investigated in detail. The thesis also includes a comprehensive introduction for non-specialists in this field. The research could benefit and will appeal to scientists, especially new researchers working in the field of energy storage.

Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook.

As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.

This book systematically summarizes the advanced development of carbon-based nanomaterials for electrochemical catalysis, and it is comprised of four sections. The first section discusses about the fundamental synthesis, characterization techniques, and catalytic effects on the energy conversion and storage mechanism. The second section elaborately reviews various types of electrocatalytic reactions on carbon-based materials and their performance. The third section focuses on batteries about carbon-based materials with different storage mechanism. And the last one, the following enlightenment in terms of theoretical development and experimental research is provided to the general readers: 1) Precise design and construction of local atomic and electronic structures at the interface of catalysts; 2) Selective activation and directed conversion of carbon-based energy-carrying molecules at the interface; 3) Interaction mechanism and regulation of catalyst solid surface interface properties under environment and external field. This book will be useful for researchers and students who are interested in carbon-based nanomaterials, electrochemical catalysts and energy storage.

This new edition presents principle methods in capillary electrophoresis (CE) separation involving CZE, MEKC, MECC, NACE, and corresponding hyphenated techniques to organic mass spectrometry and ICP-MS. Recent developments in the techniques of single cell analysis, as well as derivation, enantioseparation or the use of ionic liquids, and the use of CZE for the separation of living cells are also highlighted. This book discusses various application methods for the analysis of small ions, organic acids, amino acids, and (poly)saccharides to peptides that are shown with pollutants and biomarkers in food and health. Written in the highly successful Methods in Molecular Biology series format, chapters include introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and tips on troubleshooting and avoiding known pitfalls. Cutting edge and thorough, Capillary Electrophoresis: Methods and Protocols, Second Edition covers a wide field of interests and will be especially great for beginners and students because of its combined focus on mini-reviews and application notes that will help them quickly get an overview of the field.

The present volume presents six chapters, two of them fairly brief, covering both fundamental and applied electrochemistry. The latter aspect has, of course, historical significance in the subject as well as a major technological profile in recent decades, while intimate connections between these complementary facets of the subject have always been a driving force for its earlier and continu ing development. In the Modern Aspects of Electrochemistry series we have periodically included contributions from the several schools of Russi n electrochemistry. This approach is continued in the present volume by inclusion of the chapter by Benderskii, Brodskii, Daikhin, and Velichko from the Frumkin Institute, Moscow, on phase transitions among molecules adsorbed in the double-layer interphase at electrodes. This topic has attracted attention for some years through the works of the Russian school and of Gierst and Buess-Herman. Such behavior is also related to the important phenomenon of self-assembly of molecules in films at interfaces. In Chapter 1, these authors give an account of the factors associated with two-dimensional phase transitions and associated orientation effects with polar adsorbates at electrode interfaces. The theoretical interpretation of these effects are also treated in some detail. Chapter 2, by Rusling, deals with electrochemistry and electro catalysis in microemulsions, thus connecting aspects of electrode kinetics, adsorption at electrode interfaces, and colloid chemistry."

This highly interdisciplinary thesis reports on two innovative photonic biosensors that combine multiple simultaneous measurements to provide unique insights into the activity and structure of surface immobilized biological molecules. In addition, it presents a new silicon photonic biosensor that exploits two cascaded resonant sensors to provide two independent measurements of a biological layer immobilized on the surface. By combining these two measurements, it is possible to unambiguously quantify the density and thickness of the molecular layer; here, the approach's ability to study molecular conformation and conformational changes in real time is demonstrated. The electrophotonic biosensor integrates silicon photonics with electrochemistry into a single technology. This multi-modal biosensor provides a number of unique capabilities that extend the functionality of conventional silicon photonics. For example, by combining the complementary information revealed by simultaneous electrochemical and photonic measurements, it is possible to provide unique insights into on-surface electrochemical processes. Furthermore, the ability to create electrochemical reactions directly on the silicon surface provides a novel approach for engineering the chemical functionality of the photonic sensors. The electrophotonic biosensor thus represents a critical advance towards the development of very high-density photonic sensor arrays for multiplexed diagnostics.

This volume documents the proceedings of the Second Symposium on Metallized Plastics: Fundamental and Applied Aspects held under the aegis of the Dielectric Science and Technology Division of the Electrochemical Society in Montreal, Canada, May 7-10, 1990. The first symposium on this topic was held in Chicago, October 10-12, 1988 and the proceedings of l which have been chronicled in a hard-bound volume l As pointed out in the Preface to the proceedings of the first symposium the metallized plastics find scores of applications ranging from very mundane to very sophisticated. Even a cursory look at the literature will convince that this field has sprouted; and there is every reason to believe that with all the research and development activities taking place, new and exciting applications of metallized plastics will emerge. The program for the second symposium was very comprehensive as it included 46 papers covering many aspects of metallized plastics. This symposium was a testimonial to the brisk research activity and keen interest in the topic of metallized plastics. The success of this symposium reinforced our earlier belief that there was a definite need to hold symposia on this topic on a regular basis. Concomitantly, the third symposium in this vein was held in Phoenix, Arizona, October 13-18, 1991 and the fourth is planned for May 16-21, 1993 in Honolulu, Hawaii. As regards the present volume, it contains a total of 35 papers covering a variety of topics ranging from very fundamental to very applied.

Lithium Process Chemistry: Resources, Extraction, Batteries and Recycling presents, for the first time, the most recent developments and state-of-the-art of lithium production, lithium-ion batteries, and their recycling. The book provides fundamental and theoretical knowledge on hydrometallurgy and electrochemistry in lithium-ion batteries, including terminology related to these two fields. It is of particular interest to electrochemists who usually have no knowledge in hydrometallurgy and hydrometallurgists not familiar with electrochemistry applied to Li-ion batteries. It is also useful for both teachers and students, presenting an overview on Li production, Li-ion battery technologies, and lithium battery recycling processes that is accompanied by numerous graphical presentations of different battery systems and their electrochemical performances. The book represents the first time that hydrometallurgy and electrochemistry on lithium-ion batteries are assembled in one unique source.

A one-stop resource on all aspects of semiconductor wafer bonding for materials scientists and electrical engineers

Semiconductor Wafer Bonding addresses the entire spectrum of mainstream and likely future applications of wafer bonding. It examines all of the important issues surrounding this technology, including basic interactions between flat surfaces, the influence of particles, surface steps and cavities, surface preparation and room-temperature wafer bonding, thermal treatment of bonded wafer pairs, and much more.

This unique, one-stop resource consolidates information previously available only by time-consuming searches through technical journals, proceedings, and book chapters for more than 1,000 published articles on wafer bonding. It covers all materials used for wafer bonding—including silicon, III-V compounds, fused and crystalline quartz, glass, silicon carbide, sapphire, ferroelectrics, and many others.

For materials scientists and electrical engineers who need to exploit the potential of this flourishing technology, Semiconductor Wafer Bonding is a convenient one-stop resource for answers to many common questions. It is also an excellent text/reference for graduate students eager to learn about this interdisciplinary field, which spans surface chemistry, solid-state physics, materials science, and electrical engineering.

This book provides a comprehensive overview of contemporary basic research, emerging technology, and commercial and industrial applications associated with the electrophoretic deposition of nanomaterials. This presentation of the subject includes an historical survey, the underlying theory of electrophoresis, dielectrophoresis, and the colloidal deposition of materials. This is followed by an assessment of the experimental equipment and procedures for electrophoretic and dielectrophoretic aggregation, manipulation, and deposition of nanoparticles, nanotubes, and other nanomaterials. Additional chapters explore the specific science and technology of electrophoretic film formation, using widely studied and application-driven nanomaterials, such as carbon nanotubes, luminescent nanocrystals, and nano-ceramics. The concluding chapters explore industrial applications and procedures associated with electrophoretic deposition of nanomaterials.

Incorporating the latest theoretical and experimental developments in the field over the past decade, Brainina and Neyman's Electroanalytical Stripping Methods focuses on the theory associated with the most progressive stripping electroanalytical methods (SEAMs) and their application to environmental monitoring and industry. Wherever appropriate, it highlights the main advantages of these methods, including their extremely low detection limit, the low cost of the instruments used, the possibility of speciation analysis, and their use in the investigation of solids as well as solutions. The combined work of two eminent researchers from the former Soviet Union, the book closes the previous information gap that existed between West and East and now makes accessible the most recent developments from Russia, including a different approach to initial electro-crystallization stages, the interconnection between voltammograms of binary metal systems and work functions, and the use of these phenomena in applied stripping voltammetry. Electroanalytical Stripping Methods also provides a critical assessment of current achievements in the field of electrode materials, and in the design of electrodes and electrochemical cells used in stripping methods. Here, the authors provide unique insight into the advantages of graphite electrodes - largely used in the East - over glassy carbon electrodes generally favored by the West. The book presents a number of other modern ideas, including the theory behind and the application of a new internal standard in stripping voltammetry...the catalysis of metals electrodeposition on the foreign substrate with adatoms...and the electrochemical transformation of solidsand adsorbates and their use in phase analysis and the investigation of the defect structure of solids. Electroanalytical Stripping Methods will prove to be an invaluable tool for professionals involved in environmental monitoring, helping them to develop and use trace analysis in evaluating drinking water, food, waste, and other solids and solutions and to apply stripping voltammetry to the analyses of chemicals. Researchers in the food, clinical, and pharmaceutical industries will similarly use the book to develop and apply SEAMs for trace analysis. Practitioners in the microelectronics industry will find useful information on solids that will help them improve the quality of catalyzers, films, special ceramics, and semiconductors. Finally, medical technicians will tap this resource for the insight it can provide in the electroanalysis of blood, urine, and other body fluids.