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Modern Aspects of Electrochemistry (Hardcover, 1987. Corr. 11t)
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Modern Aspects of Electrochemistry (Hardcover, 1987. Corr. 11t)
Series: Modern Aspects of Electrochemistry, 26
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The present volume presents six chapters, two of them fairly brief,
covering both fundamental and applied electrochemistry. The latter
aspect has, of course, historical significance in the subject as
well as a major technological profile in recent decades, while
intimate connections between these complementary facets of the
subject have always been a driving force for its earlier and
continu ing development. In the Modern Aspects of Electrochemistry
series we have periodically included contributions from the several
schools of Russi n electrochemistry. This approach is continued in
the present volume by inclusion of the chapter by Benderskii,
Brodskii, Daikhin, and Velichko from the Frumkin Institute, Moscow,
on phase transitions among molecules adsorbed in the double-layer
interphase at electrodes. This topic has attracted attention for
some years through the works of the Russian school and of Gierst
and Buess-Herman. Such behavior is also related to the important
phenomenon of self-assembly of molecules in films at interfaces. In
Chapter 1, these authors give an account of the factors associated
with two-dimensional phase transitions and associated orientation
effects with polar adsorbates at electrode interfaces. The
theoretical interpretation of these effects are also treated in
some detail. Chapter 2, by Rusling, deals with electrochemistry and
electro catalysis in microemulsions, thus connecting aspects of
electrode kinetics, adsorption at electrode interfaces, and colloid
chemistry."
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